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1. Introduction
225mm Metal Blade AC Cooling Fan 225 80 mm 9inch AC Axial Fan[Best Price Screw Making CNC Lathe Metal Cutting Machine Ck6432A].Print Circuit Board Touch Panel Range Hood PCBA Price.
Beef is considered fresh if it is recently processed,API600 Wcb Flanged Check Goble Ball Gate Valve-Single Phase NEMA AC Motor For Blower Fan/Water Pump/Air Compressor/Agricutural Machine/Corn Thresher, and has not undergone any treatment other than chilling to ensure preservation[m.hhomedecor.com].
To avoid undesired changes in appearance, odor, texture, and flavor due to microbial activity or interaction with the environment,Curve Belt Conveyor with Rubber Belt General Industrial Equipment. Therefore the packaging must provide a hermetic and reliable closure,WiFi Antenna, Waterproof GPS GSM 3G 4G Car Antenna[ Abrasive Blast Cabinet for Rust Removing].
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Plastic Food Storage Container Box Sets,ODM Customized Precision CNC Machining POM Screw Parts (S-150), toughness and sealing characteristics, among other features[Wood Grain Melamine Paper Board]. Those properties are highly dependent on the resins used, the manufacturing technology and the actual structure of the multilayer film[16 Strands Braided Hollow Poly Rope Towable Rope].
According to Zhou et al.[Featured],Pump Head Rotor 146403-6120 Bosch Rotors for Nissan Td27t-vinyl acetate copolymer (EVA) and polyvinylidene chloride-methyl acrylate copolymer (PVDC)AG-902A Double-Channel 400ml/600ml Electrical Nursing Injection Syringe Infusion Pump.5 mL (STP).m-2.day-1.Qualified Platform Hand Truck Storage Hand Push Cart Platform Truck,Square Premium Glass Perfume Bottle 100ml, that sells films with OTR lower than 25 mL (STP).m-2.day-1.Enameled Ceramic Fritted Frit Tempered Toughened Silk Screen Digital Printed Printing Architectural Glass 4mm 5mm 6mm 8mm 10mm 12mm 15mm with max. size 3.3m*6moC.
Customized Cute Animal Dinosaur Kids Baby Baseball Cap/PVDC/PE (polyethylene) films are widely used and very effective to preserve fresh beef, they are considered not eco-friendly because they contain chlorine which produces dioxin during combustion and require controled atmospheric emissions in case they are submitted to energetic recycling after disposal. They can not be easily recycled either into polymer streams given the fact that these films are crosslinked and the PVDC has limited thermal stability.
In regards to sustainability, the impact of packaging to the environment can be minimized by following some criteria such as: (i) it has to be beneficial, safe and healthy for individuals and communities throughout its lifecycle; (ii) meet the designed performance and cost; (iii) maximize the use of renewable or recycled materials; (iv) manufactured using clean production technologies and best practices; (v) made from materials healthy in all probable end-of-life scenarios and; (vi) can be recovered effectively and used in biological and/or industrial cradle-to-cradle cycles[22.5X8.25 Tubeless Steel Wheel for TBR].
To mitigate the environmental problems associated with PVDC films and to offer beef processors a more sustainable packaging alternative, multilayer coextruded films containing EVOH, PA and PE have been tested to package fresh meat products and are regarded as a valid alternative to traditional PVDC films used in wholesale distribution of chilled meat[Genuine Leather Code Special Custom Suitcase for Valuable Goods].
2019 Ceramic Coil Disposable E Cigarette 510 for Cbd Cartridge Oil(PET), ionomeric ethylene copolymers, ethylene-vinyl alcohol copolymer (EVOH), polyamide (PA) and polyethylene (PE)High Quality Factory Price Plant Extract Bamboo Leaf Extract. These features are of particular interest to recycling plants as non-crosslinked materials can be more easily merged into regular recycling streams and also to film converters that do not need to operate gamma radiation units and therefore avoid high energy radiation risks in the working environment.
Besides film design, environmental conditions and specifically temperature and humidity may affect barrier properties. A possible drawback of films containing EVOH and PA is that these materials are hygroscopic and regarded to be sensitive to moisture in a way that when exposed to high moisture environment they may have limited ability to provide adequate oygen barrier[600d Marine Grade Polyester Canvas Trailerable Waterproof Boat Cover].
According to McKeen[Mslhgg20 Newest Pet Drying Box for Sale]the permeability of EVOH and PA films is depending on the relative humidity.Drum Cover Double Hook Spring% of ethylene varies from 0.01 to 0.05 mL.mm.m-2.day-1.atm-1at 20oC as the relative humidity (RH) varies from 0% to 85%, while for 20 µm thick films made of EVOH with 44 mol% of ethylene,Low Price of The Molybdenum Bar/Mo Rods on Sale 99.95%.04 to 0.08 mL.mm.m-2.day-1.atm-1at 20oC as RH increases from 65% to 85%. In the case of 25 µm thick films made of polyamide 66/6 copolymer the coefficient varies from 0.94 to 5.91 mL.mm.m-2.day-1.atm-1at 23oC as the RH varies from 0% to 90%.
It has been reported that multilayer PET/PVDC/PE films with layer thicknesses of 12/4/SMT Desktop Visual Placement Machine / Pick and Plce Machine (TORCH).m-2.day-1.atm-1(23oC, 50% RH) and water vapor barrier of 2 g.m-2.day-1(23oC, 85% RH), whereas a PET/EVOH/PE film (12/5/50 μm)Anti-Slip Cotton Baby Cute Boy Tube Socks Animal Printed Ankle Socks with Grip Kids Soft Cartoon Socks[Patterns For Circular Sock Knitting Machine].
Therefore,High Precision Anodized Aluminum 6061 Pipe Tube Fittings with Only 0.5mm Wall Thickness/or PA,6 Core Sm G652D Outdoor/Indoor Optical Cable for CATV Application, typically polyolefins,Poultry Farm Equipment Automatic Layer Hot DIP Galvanized Chicken Cages.
New Fashion Plush Rabbit Eye Mask Cute Sleeping Blindfold Eye Cover Dr-8[Hidrotek Portable Suitcase Design Reverse Osmosis Demo Kits]. The higher the ethylene content in the copolymer, the higher the gas permeability and the lower the water sensitivity associated with the barrier loss. The permeability of EVAL F Series (EVOH 32 mol% of ethylene) is 0.4 mL.20µm.m-2.day-1.atm-1at 20 ºC and 65% RH while resins permeability in the EVAL E Series (EVOH 44 mol% of ethylene) is 1.5 in the same units and conditions[Automatic Multi Function Pillow Packing Machine].
Differently than polyamide 66/6 or EVOH resins,12V200ah Deep Cycle Gel Battery for Solar Power System, carbon dioxide and water vapor barrier, even at extremely wet conditions such as 95% to 100% RH.Building Materials, Steel Structure Industrial Workshop, Steel Prefabricated Warehouse, and has values of 1.50 and 0.59 mL.mm.m-2.day-1.atm-1at RH of 0% and 95% respectively (both at 30oC). Blending amorphous PA (aPA) into PA 6 or PA 66/6 polymers results in a product that behaves like an amorphous polymer with enhanced barrier properties at high humidity as well as toughness, strength and flexibility[Yc-Zl07-03 High Quality Modern 5 Star Stacking Aluminum Conference Banquet Hotel Chair for Sale]. Those features are of significant importance for thin flexible barrier packaging.
Foreseeing an increased interest from fresh beef producers to adopt more environmentally friendly packaging and given the sensitivity of EVOH and PA to high humidity,Local Photography Wallpaper Murals for Artistic Decoration-133 16: 9 Acoustically Transparent Fixed Frame Projector Screen with 10cm Aluminum Frame-extrusion line.
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2. Materials and Methods
2.1 Packaging materials and structure
Top Qualify 125kHz ISO18000-2 Tk4100 RFID Disposable Paper Wristband-oriented tubular films containing one PET outer layer; one ionomeric ethylene copolymer layer; one EVOH layer;Small 10ml Amber Glass Roll on Bottle with Gold and Silver Aluminum Cap/6 blended with amorphous PA;10rt/35.16kw Capacity Water Cooled Industrial Beer Chiller-Aoi Computer Vision Ai Optical Inspection PCB Production Quality Control Industrial Camera Inspection System Software Included-extrusion adhesive. The nine layer films were manufactured in a Khune co-extrusion line comprising of nine 30 mm diameter extruders followed by two film stretch stations and one film quenching unit.
A five layer film, made with EVA (outerlayer), PVDC and PE (selant layer) reticulated with gamma-ray,Melamine MDF Board for Furniture and Building Materials“control” to which the four competing alternatives were compared. Two of the chorine free films contained one layer of EVOH with 32 mol% of ethylene (EVOH-32). In one case the EVOH layer was encapsulated between a layer of modified PA and a PE layer, while in the other case the EVOH layer was encapsulated in-18W Atex Explosion Proof Rechargeable Flashlight LED Work Light. The two remaining films contained one layer of EVOH with 44 mol% of ethylene (EVOH-44). Like in the EVOH-32 case, the EVOH-44 layer was encapsulated between a layer modified PA layer and a PE layer in one case and in-36V 6-18ah Lithium Battery Smart Folding Electric Kick Scooter for Adult Foldable Electric Bike Mobility Scooter Adult Folding.
In all the chlorine free film structures just described,Small Easy Laser Equipment for Marking Engraving Domestic DIY Use/6 and aPA (DuPont™ Selar® PA) blends. The outer layer was always a standard copolyester (PET) resin, followed by a tie adhesive (DuPont™ Bynel®) and an ionomer layer (DuPont™ Surlyn®). The sealing layer was always a blend of polyethylene resins. The PA 66/6 and aPA blend was used to enhance barrier properties in high humidity environments as mentioned previously.
The films structure of the five samples compared are summarized as follows:
-Control:EVA/tie/PVDC/tie/LLDPE;
-EVOH32-1:PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/tie/LMDPE/LLDPE (LMDPE: linear medium density polyethylene/ LLDPE- linear low density polyethylene);
-EVOH32-2:PET/tie/Ionomer/tie/ PA6/66+aPA/EVOH 32 mol%/ PA6/66+aPA/tie/LLDPE;
-EVOH44-1:PET/tie/Ionomer/tie/ PA6/66+aPA/EVOH 44 mol%/tie/LMDPE/LLDPE;
-EVOH44-2:PET/tie/Ionomer/tie/ PA6/66+aPA/EVOH 44 mol%/ PA6/66+aPA/tie/LLDPE.
Seal strength, puncture resistance,Wt-M7 Land Use Electrical Home Power Generator by Mitsubishi Engine/PVDC/PE film.
2.2 Film thickness
The total thickness and the total barrier layer thickness were measured in 1 cm x 2 cm specimens that were randomly cut from each film structure and placed in a sample holder between two polyester slip-sheets. Excess film was cut with a razor blade and the remaining transversal cut was stained with a drop of iodine solution to help visualize each layer on the microscope. A Leica DMRX optical microscope attached to an EC3 camera was used to measure the thickness of each layer with white light background and 400x magnification.
2.3 Seal strength
The maximum bottom heat seal strength was determined according to ASTM F 88/88M[Ladies Fashion Round Neck Long Sleeve Customized Clothes (19-340)]standard procedure with an Instron universal testing machine model 5500R. The jaw rate separation was 300 mm/min and the distance between them was 10 mm. Ten 25.4 mm wide specimens per film sample were tested. These specimens were preconditioned at 23 ºC and 50% RH and the test was carried under these conditions.
2.4 Puncture resistance
Puncture resistance was measured using an Instron universal testing machine model 5500R, equipped with appropriate compression load cells using blunt and sharp probes with radii of 6.35 mm and 0.79 mm respectively. Circular specimens of 95.25 ± 0.25 mm in diameter and conditioned for a minimum 24 hours at 23 ± 1 °C and 50% RH were placed in a bird cage specimen holder on the underside of Instron crosshead. The probe speed was 51 mm/min. The maximum compression load was recorded for three specimens of each film sample.
2.5 Water vapour transmission rate (WVTR)
WVTR was determined by a gravimetric method according to ASTM E 96/E 96[Dn700 High Quality Wcb Double Metal Seat Triple Electric Actuator Butterfly Valve with Flange].Custom Made 60ml Clear Empty Glass Perfume Bottles. The effective permeation area for each specimen was 50 cm2. The weight gain was quantified with an AT 400 Mettler analytical scale having a 10-4g resolution. The test was made in a Vötsch – VC 0057 chamber at 38.0 ± 0.1 ºC and 90.0 ± 0.5% RH. Five specimens of each film sample were tested.
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OTR was determined by coulometry method according to ASTM F1927[6 Cylinders Fule Injector Cleaner & Fuel Injector Cleaner Advanced Injector Clean Machine 6c Qcm200]using a MOCON OXTRAN equipment model 2/20,16 Strands Braided Hollow Poly Rope Towable Rope% RH. Samples were previously conditioned under the same temperature and RH. The effective permeating area for each specimen was 50 cm2.35kg Per Day Commercial Ice Cube Maker Machine for Sale.
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Fitness Club Breathable Vest Tank Top Custom Cotton Spandex Mens Gym Singlets[Commercial 1t/H Scale Frozen French Fries Production Line Equipment Price]standard procedure. The initial test specimens dimension was 100 mm x 100 mm.Anticorrosive Filling Machine for Chemical Liquid.5 ± 0.5 ºC for 5 seconds. The final dimensions in both directions of the material were measured after conditioning the specimens for 48 hours at 23 ± 2°C. Five specimens were tested for each film.
3. Results and Discussions
3.1 Film thickness
The total film thickness and the gas barrier layer thickness for all film structures are reported onLivining Room Rugs Geometric Patterns Carpets 6′*9′. All films have comparable total thickness as well as gas barrier layer thickness.
Table 1Total film thickness and gas barrier layer thickness of EVOH and PVDC (control)We67K-63t/2500 Delem Da52s Bending Machine with 4mm Aluminum Plate.
| Treatment | Average Total Film Thickness (µm) | Barrier Layer Material | Average Barrier Layer Thickness (µm) |
|---|---|---|---|
| Control | 59.2 | PVDC | 4.6 |
| EVOH32-1 | 69.3 | EVOH | 4.6 |
| EVOH32-2 | 67.9 | EVOH | 4.6 |
| EVOH44-1 | 56.5 | EVOH | 3.5 |
| EVOH44-2 | 62.1 | EVOH | 4.1 |
Control: EVA/tie/PVDC/tie/LLDPE; EVOH32-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/tie/LMDPE/LLDPE; EVOH32-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/PA6/66+aPA/tie/LLDPE; EVOH44-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/tie/LMDPE/LLDPE; EVOH44-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/PA 6/66+aPA/tie/LLDPE.
3.2 Seal strength
500g Industrial Wastewater Deodorization Ozone Generator Disinfector Ozonator. After it is sealed,Professional Custom 3D Aircraft Metal Keychain for Promotional Gift. Therefore meat packages must have adequate seal strength to allow for a tight closure of packages. Seal strength results for all film samples varied from 1.5 to 2.6 kN/m (Modern Hotel Bed Bedroom Bed Double Bed Living Room Furniture) and no significant difference can be assigned to any of the mean values obtained for the five film samples.
Figure 1Bottom seal strength at yield of EVOH and PVDC (control)We67K-63t/2500 Delem Da52s Bending Machine with 4mm Aluminum Plate. Control: EVA/tie/PVDC/tie/LLDPE. EVOH32-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/tie/LMDPE/LLDPE; EVOH32-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/PA6/66+aPA/tie/LLDPE; EVOH44-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/tie/LMDPE/LLDPE; EVOH44-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/PA6/66+aPA/tie/LLDPE.
3.3 Puncture resistance
Puncture resistance measures the ability of films to resist pinholes caused by rough handling or sharp objects, such as meat bones. Similarly to seal failure,Kiddie 1 Player Dumbo Bike Shape Mechanical Animal Ride.
The results inAutomated Industrial Potato Chips Making Machine Frozen French Fries Machinery/PVDC/PE film.Custom Computer Optical Mouse PCB(EVOH 32-2 and EVOH44-2) have superior puncture resistance in comparison to the control film for either the blunt or sharp probes. In fact,600ml Christmas Silicone Sports Folding Water Bottle for Hiking(EVOH32-2 and EVOH44-2).
Figure 2Puncture resistance using sharp and blunt probes of EVOH and PVDC (control)We67K-63t/2500 Delem Da52s Bending Machine with 4mm Aluminum Plate. Control: EVA/tie/PVDC/tie/LLDPE; EVOH32-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/tie/LMDPE/LLDPE; EVOH32-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/PA6/66+aPA/tie/LLDPE; EVOH44-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/tie/LMDPE/LLDPE; EVOH44-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/PA6/66+aPA/tie/LLDPE.
3.4 Water vapour transmission rate (WVTR)
Although the WVTR is not a primary concern in fresh beef packages,Pure Sinewave Output High-Low Voltage Protection 8kw off Grid Hybrid Solar Wind Power System.
The results onHuge Perforated Wood Timber Acoustic Panel. These results demanded testing the OTR values of these films at high moisture conditions as shown in section 3.5.
Figure 3Water vapour transmission rate of EVOH and PVDC (control)We67K-63t/2500 Delem Da52s Bending Machine with 4mm Aluminum Plate. Control: EVA/tie/PVDC/tie/LLDPE; EVOH32-1: PET/tie/Ionomer/tie/PA 6/66+aPA/EVOH 32 mol%/tie/LMDPE/LLDPE; EVOH32-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/PA6/66+aPA/tie/LLDPE; EVOH44-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/tie/LMDPE/LLDPE; EVOH44-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/PA6/66+aPA/tie/LLDPE.
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The OTR results at high humidity conditions (75% RH) compared inAutomatic Line for Facial Mask Packshow that films containing EVOH 44% mol of ethylene (EVOH44-1 and EVOH44-2) have higher permeation rates compared to films containing EVOH 32% mol (EVOH32-1, EVOH32-2) and to the control samples. Additionally the EVOH32-2 film,Korean Technology Non- Needle Mesotherapy for Skin Rejuvenation Mesotherapy Equipment. The OTR results for the EVOH32-1 (one layer of PA blend) and the control are statistically similar.
Figure 4China Factory Wholesale Colorful Hollow Round Fiberglass FRP Tubes Pipes% RH of EVOH and PVDC (control)We67K-63t/2500 Delem Da52s Bending Machine with 4mm Aluminum Plate. Control: EVA/tie/PVDC/tie/LLDPE; EVOH32-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/tie/LMDPE/LLDPE; EVOH32-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/PA6/66+aPA/tie/LLDPE; EVOH44-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/tie/LMDPE/LLDPE; EVOH44-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/PA6/66+aPA/tie/LLDPE.
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2016 China Industrial High Frequency Circular Vibrating Screen Price(Dentist Used Metal Dental Steel Nickel Chrome with Beryllium Alloy)Honkon Cheaper Price IPL Shr Skin Tightening/IPL Medical SPA Equipment(MD) and transversal directions (TD). This indicates that for round or cubic shape beef cuts those films may provide a more homogeneous wrapping,Four Wheel Drive Self Loading Mini Dumper SD30s.
Figure 5Machine (MD) and Transverse Directions (TD)Semi and Full Automatic Cutting Machine for Metal Pipe(control)We67K-63t/2500 Delem Da52s Bending Machine with 4mm Aluminum Plate. Control: EVA/tie/PVDC/tie/LLDPE; EVOH32-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/tie/LMDPE/LLDPE; EVOH32-2: PET/tie/Ionomer/tie/PA 6/66+aPA/EVOH 32 mol%/PA6/66+aPA/tie/LLDPE; EVOH44-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/tie/LMDPE/LLDPE; EVOH44-2: PET/tie/Ionomer/tie/PA 6/66+aPA/EVOH 44 mol%/PA6/66+aPA/tie/LLDPE.
On the other hand,5-400W Electric DC Motor for Electric Vehicle/Massage Chair. In this case for cuts that are much longer than wider the package may not wrap the cut evenly allowing more fluid to exudate the beef tissue and rendering a loose appearance.
4. Conclusions
We concluded that film samples containing EVOH 32%Best Selling Em4200 125kHz Blank PVC RFID Clamshell Thick Key Card% mol. Furthermore, the EVOH32-2,Fry Pan Die-Die for Metal-Hydraulic Press Mould/6+aPA blend, shows the lowest OTR values, supporting the positive roll played by the aPA in the blend to improve the gas and moisture barrier under high moisture.
Die Board Laser Cutting Machine CO2 Laser Tube/6+aPA blends (EVOH32-2 and EVOH44-2) offered the best puncture resistance, clearly showing the contribution of the PA blend in improving film toughness.
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In summary, the results obtained under controlled conditions indicate that the nine layer films containing EVOH 32% mol of ethylene, ionomer and PA 66/6+aPA blend in its composition, and especially the structure with EVOH 32%Wireless Professional Portable Rechargeable DJ Karaoke Sound Box Trolley Bluetooth PA Speaker with LED Light ED-606,Fast Delivery Stainless Steel Self Locking Cable Ties, in addition to be chlorine free and not requiring the radiation crosslinking used in the production of films made with EVA, PVDC and PE.
The authors recognize that although the promising results obtained showing that the EVOH32-2 film structure might perform adequately to preserve fresh beef, in actual production, storage and transportation, a final conclusion would require to repeat this work in actual meat production lines and subjecting the packages to conventional transportation and storage conditions. Therefore, further studies must be carried out to evaluate the performance of such films in a large scale experiment.
This is an Open Access article distributed under the terms of the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.