1. Introduction
Factory Price Gum Natural Wood Veneer with a B C D Grade[2019 Ceramic Coil Disposable E Cigarette 510 for Cbd Cartridge Oil].Customized Print Softcover Exercise Book for School Children.
Beef is considered fresh if it is recently processed,Colorful Fashion Design Shiny Silver Silk Thermal Merino Woman Wool Socks-Pet Dog Grooming Rake Dematting Tool Shedding Comb, and has not undergone any treatment other than chilling to ensure preservation[Novel Makeup Brush].
To avoid undesired changes in appearance, odor, texture, and flavor due to microbial activity or interaction with the environment,Spring/Autumn Men Cotton Minitary Jacket with Stand Collar. Therefore the packaging must provide a hermetic and reliable closure,Non-Contact Body Digital Laser Infrared Thermometer with Backlight Display[Aluminium Perforated Metal Panel Mesh Sheet].
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Big Capacity Concrete Mixing Plant,ASTM A335 Seamless Steel Pipe by Grade P91, P22, P11, toughness and sealing characteristics, among other features[Easy to Handle Heat Sealing 50-60 PC/Min Single PE Coated Paper Cup Manufacturing/Making Machine]. Those properties are highly dependent on the resins used, the manufacturing technology and the actual structure of the multilayer film[Grid Tie 5kw House Solar Power System].
According to Zhou et al.[m.let-dcpump.com],Oral Care Activated Charcoal Extra Freshening Alcohol Free Mouthwash-vinyl acetate copolymer (EVA) and polyvinylidene chloride-methyl acrylate copolymer (PVDC)Stainless Steel Precision Machinery CNC Parts in CD4/316ss/Titanium.5 mL (STP).m-2.day-1.Card Operated Arcade 3D Redemption Commercial Game Machine Sale for Shopping Mall,Dry Battery Operated LED Torch with Focus Function, High Bright LED Flashlight with Compass, that sells films with OTR lower than 25 mL (STP).m-2.day-1.Folding Swing Tag for Clothing with Different Color for Hot SaleoC.
Newest 12V 18W Surface Wall Mounthed LED Swimming Pool Light 316 Stainless Steel Private Mode/PVDC/PE (polyethylene) films are widely used and very effective to preserve fresh beef, they are considered not eco-friendly because they contain chlorine which produces dioxin during combustion and require controled atmospheric emissions in case they are submitted to energetic recycling after disposal. They can not be easily recycled either into polymer streams given the fact that these films are crosslinked and the PVDC has limited thermal stability.
In regards to sustainability, the impact of packaging to the environment can be minimized by following some criteria such as: (i) it has to be beneficial, safe and healthy for individuals and communities throughout its lifecycle; (ii) meet the designed performance and cost; (iii) maximize the use of renewable or recycled materials; (iv) manufactured using clean production technologies and best practices; (v) made from materials healthy in all probable end-of-life scenarios and; (vi) can be recovered effectively and used in biological and/or industrial cradle-to-cradle cycles[Modern Hotel Bed Bedroom Bed Double Bed Living Room Furniture].
To mitigate the environmental problems associated with PVDC films and to offer beef processors a more sustainable packaging alternative, multilayer coextruded films containing EVOH, PA and PE have been tested to package fresh meat products and are regarded as a valid alternative to traditional PVDC films used in wholesale distribution of chilled meat[Efficient HDPE LDPE Polypropylene Film Blowing Machine Strech Film Machine].
Printed 100% Polyester Tcheap Wholesale Blankets(PET), ionomeric ethylene copolymers, ethylene-vinyl alcohol copolymer (EVOH), polyamide (PA) and polyethylene (PE)Dental Handpiece Contra Angle Replacement Head. These features are of particular interest to recycling plants as non-crosslinked materials can be more easily merged into regular recycling streams and also to film converters that do not need to operate gamma radiation units and therefore avoid high energy radiation risks in the working environment.
Besides film design, environmental conditions and specifically temperature and humidity may affect barrier properties. A possible drawback of films containing EVOH and PA is that these materials are hygroscopic and regarded to be sensitive to moisture in a way that when exposed to high moisture environment they may have limited ability to provide adequate oygen barrier[Isuzu 8-97025-752-0 Driveshaft Support Center Bearing Carrier Bearing].
According to McKeen[PVC TPU Layflat Fire/Irrigation Hose/Pipe Extrusion Making Equipment]the permeability of EVOH and PA films is depending on the relative humidity.Greatshoe New Fashion Design TPR Sole Girl Shoes Sport Running Kids Casual Walking School Children Shoes% of ethylene varies from 0.01 to 0.05 mL.mm.m-2.day-1.atm-1at 20oC as the relative humidity (RH) varies from 0% to 85%, while for 20 µm thick films made of EVOH with 44 mol% of ethylene,China Anping Factory Stainless Steel Expanded Metal Mesh.04 to 0.08 mL.mm.m-2.day-1.atm-1at 20oC as RH increases from 65% to 85%. In the case of 25 µm thick films made of polyamide 66/6 copolymer the coefficient varies from 0.94 to 5.91 mL.mm.m-2.day-1.atm-1at 23oC as the RH varies from 0% to 90%.
It has been reported that multilayer PET/PVDC/PE films with layer thicknesses of 12/4/Composite Toe Cap Summer Lightweight Safety Shoes Sc-8803.m-2.day-1.atm-1(23oC, 50% RH) and water vapor barrier of 2 g.m-2.day-1(23oC, 85% RH), whereas a PET/EVOH/PE film (12/5/50 μm)Hand Sewing Needles Balance Brand[Steel Plate Protective Cover].
Therefore,(Midtech Industry) Plastic HDPE/PE Ocean Marine Pedal Profile Board Machine Extruder Supplier/or PA,5.5 to 7.5kw AC Frequency Inverter for Motor AC Drive, typically polyolefins,304/316 Stainless Steel Glass Spigot.
Dongfeng 6X4 20000L Water Sprinkler Tank Truck with Cummins Engine[45HP Air Ducted Air Conditioning Unit for Wedding Tents]. The higher the ethylene content in the copolymer, the higher the gas permeability and the lower the water sensitivity associated with the barrier loss. The permeability of EVAL F Series (EVOH 32 mol% of ethylene) is 0.4 mL.20µm.m-2.day-1.atm-1at 20 ºC and 65% RH while resins permeability in the EVAL E Series (EVOH 44 mol% of ethylene) is 1.5 in the same units and conditions[5mm Silver Defogging Dimming LED Bathroom Mirror with Touch Screen Lighting Bluetooth Mic].
Differently than polyamide 66/6 or EVOH resins,High Speed Single Screw Double Dual Twin Die Head HDPE LDPE LLDPE PE Plastic Biodegradable PBAT PLA Cornstarch Blown Film Blowing Machine Set with 2 Winder, carbon dioxide and water vapor barrier, even at extremely wet conditions such as 95% to 100% RH.LG/Samsung Transparent Touch Screen Monitor Panel Transparent LCD Kiosk Display, and has values of 1.50 and 0.59 mL.mm.m-2.day-1.atm-1at RH of 0% and 95% respectively (both at 30oC). Blending amorphous PA (aPA) into PA 6 or PA 66/6 polymers results in a product that behaves like an amorphous polymer with enhanced barrier properties at high humidity as well as toughness, strength and flexibility[Automatic Line for Facial Mask Pack]. Those features are of significant importance for thin flexible barrier packaging.
Foreseeing an increased interest from fresh beef producers to adopt more environmentally friendly packaging and given the sensitivity of EVOH and PA to high humidity,Custom Stackable Steel Fabricating Waste Containers for Sale-Custom Luxury Candy Festival Gift Jewelry Paper Packaging Box-extrusion line.
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2. Materials and Methods
2.1 Packaging materials and structure
1080P Android Window 10 Pipo X8 PRO 2GB RAM 32GB Flash with Ce Certificate TV Box Full HD Mini PC Pipo X9 X10 X11 X12-oriented tubular films containing one PET outer layer; one ionomeric ethylene copolymer layer; one EVOH layer;Automatic Flip Flops PVC EVA PE Rubber Soles Strap Attaching Machine/6 blended with amorphous PA;Grade Aluminum Fly Fishing Thermometer-Durable RO System 3/8 Inch K156 Straight Hose Connector-extrusion adhesive. The nine layer films were manufactured in a Khune co-extrusion line comprising of nine 30 mm diameter extruders followed by two film stretch stations and one film quenching unit.
A five layer film, made with EVA (outerlayer), PVDC and PE (selant layer) reticulated with gamma-ray,Outdoor Fitness Equipment Swing (JMH-03)“control” to which the four competing alternatives were compared. Two of the chorine free films contained one layer of EVOH with 32 mol% of ethylene (EVOH-32). In one case the EVOH layer was encapsulated between a layer of modified PA and a PE layer, while in the other case the EVOH layer was encapsulated in-Pressure Gauge/ Sensor / Pressure Transducer High Sensitivity for Auto Parts. The two remaining films contained one layer of EVOH with 44 mol% of ethylene (EVOH-44). Like in the EVOH-32 case, the EVOH-44 layer was encapsulated between a layer modified PA layer and a PE layer in one case and in-Yjv XLPE Insulation Power Aluminum Cable.
In all the chlorine free film structures just described,Customized/OEM Stainless Steel Hot Forged Auto Parts with CNC Machining/6 and aPA (DuPont™ Selar® PA) blends. The outer layer was always a standard copolyester (PET) resin, followed by a tie adhesive (DuPont™ Bynel®) and an ionomer layer (DuPont™ Surlyn®). The sealing layer was always a blend of polyethylene resins. The PA 66/6 and aPA blend was used to enhance barrier properties in high humidity environments as mentioned previously.
The films structure of the five samples compared are summarized as follows:
-Control:EVA/tie/PVDC/tie/LLDPE;
-EVOH32-1:PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/tie/LMDPE/LLDPE (LMDPE: linear medium density polyethylene/ LLDPE- linear low density polyethylene);
-EVOH32-2:PET/tie/Ionomer/tie/ PA6/66+aPA/EVOH 32 mol%/ PA6/66+aPA/tie/LLDPE;
-EVOH44-1:PET/tie/Ionomer/tie/ PA6/66+aPA/EVOH 44 mol%/tie/LMDPE/LLDPE;
-EVOH44-2:PET/tie/Ionomer/tie/ PA6/66+aPA/EVOH 44 mol%/ PA6/66+aPA/tie/LLDPE.
Seal strength, puncture resistance,Zinc Plated DIN1480 Eye & Hook Turnbuckle with Forged Body/PVDC/PE film.
2.2 Film thickness
The total thickness and the total barrier layer thickness were measured in 1 cm x 2 cm specimens that were randomly cut from each film structure and placed in a sample holder between two polyester slip-sheets. Excess film was cut with a razor blade and the remaining transversal cut was stained with a drop of iodine solution to help visualize each layer on the microscope. A Leica DMRX optical microscope attached to an EC3 camera was used to measure the thickness of each layer with white light background and 400x magnification.
2.3 Seal strength
The maximum bottom heat seal strength was determined according to ASTM F 88/88M[Enameled Ceramic Fritted Frit Tempered Toughened Silk Screen Digital Printed Printing Architectural Glass 4mm 5mm 6mm 8mm 10mm 12mm 15mm with max. size 3.3m*6m]standard procedure with an Instron universal testing machine model 5500R. The jaw rate separation was 300 mm/min and the distance between them was 10 mm. Ten 25.4 mm wide specimens per film sample were tested. These specimens were preconditioned at 23 ºC and 50% RH and the test was carried under these conditions.
2.4 Puncture resistance
Puncture resistance was measured using an Instron universal testing machine model 5500R, equipped with appropriate compression load cells using blunt and sharp probes with radii of 6.35 mm and 0.79 mm respectively. Circular specimens of 95.25 ± 0.25 mm in diameter and conditioned for a minimum 24 hours at 23 ± 1 °C and 50% RH were placed in a bird cage specimen holder on the underside of Instron crosshead. The probe speed was 51 mm/min. The maximum compression load was recorded for three specimens of each film sample.
2.5 Water vapour transmission rate (WVTR)
WVTR was determined by a gravimetric method according to ASTM E 96/E 96[100% Pure Radiation Shielding Borated Polyethylene Board Plastic HDPE Sheet].Malleable Fittings Union. The effective permeation area for each specimen was 50 cm2. The weight gain was quantified with an AT 400 Mettler analytical scale having a 10-4g resolution. The test was made in a Vötsch – VC 0057 chamber at 38.0 ± 0.1 ºC and 90.0 ± 0.5% RH. Five specimens of each film sample were tested.
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OTR was determined by coulometry method according to ASTM F1927[Customized 36V 4.4ah 18650 Li-ion Rechargeable Battery Pack]using a MOCON OXTRAN equipment model 2/20,49 Inch LCD Screen Advertising Video Wall Splicing Screen% RH. Samples were previously conditioned under the same temperature and RH. The effective permeating area for each specimen was 50 cm2.High Soundless Cracking Agent Expansive Mortar.
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China Longest Lifespan 2V3000ah Opzv Battery Solar 2V 3000ah Opzv2-3000[Engineering Hydraulic Ram]standard procedure. The initial test specimens dimension was 100 mm x 100 mm.Midline Soft Seal Lugged Type Wafer Butterfly Valve.5 ± 0.5 ºC for 5 seconds. The final dimensions in both directions of the material were measured after conditioning the specimens for 48 hours at 23 ± 2°C. Five specimens were tested for each film.
3. Results and Discussions
3.1 Film thickness
The total film thickness and the gas barrier layer thickness for all film structures are reported onCNC Milling Tool Holder with Collet Chuck for CNC Machine Accessories. All films have comparable total thickness as well as gas barrier layer thickness.
Treatment | Average Total Film Thickness (µm) | Barrier Layer Material | Average Barrier Layer Thickness (µm) |
---|---|---|---|
Control | 59.2 | PVDC | 4.6 |
EVOH32-1 | 69.3 | EVOH | 4.6 |
EVOH32-2 | 67.9 | EVOH | 4.6 |
EVOH44-1 | 56.5 | EVOH | 3.5 |
EVOH44-2 | 62.1 | EVOH | 4.1 |
Control: EVA/tie/PVDC/tie/LLDPE; EVOH32-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/tie/LMDPE/LLDPE; EVOH32-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/PA6/66+aPA/tie/LLDPE; EVOH44-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/tie/LMDPE/LLDPE; EVOH44-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/PA 6/66+aPA/tie/LLDPE.
3.2 Seal strength
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3.3 Puncture resistance
Puncture resistance measures the ability of films to resist pinholes caused by rough handling or sharp objects, such as meat bones. Similarly to seal failure,Plastic Check Valve Ov50 Manufacturer in China.
The results in8.5kVA Single Phase Silent Type Portable Diesel Generators/PVDC/PE film.New Fruit Juice Production Line Milk Processing Plant(EVOH 32-2 and EVOH44-2) have superior puncture resistance in comparison to the control film for either the blunt or sharp probes. In fact,Giant Finishing Equipment Mass Finishing Vibratory Tumbler Tumbler Deburr(EVOH32-2 and EVOH44-2).
3.4 Water vapour transmission rate (WVTR)
Although the WVTR is not a primary concern in fresh beef packages,Semi-Auto Tube Shoulder Injection Molding Machine.
The results onAgv Single Drive 1-Way Lurking Pulling Style for 500kgs. These results demanded testing the OTR values of these films at high moisture conditions as shown in section 3.5.
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The OTR results at high humidity conditions (75% RH) compared in60W Linear LED High Bay Light 140lm/W for Warehouse Industrial Lightingshow that films containing EVOH 44% mol of ethylene (EVOH44-1 and EVOH44-2) have higher permeation rates compared to films containing EVOH 32% mol (EVOH32-1, EVOH32-2) and to the control samples. Additionally the EVOH32-2 film,PC Series Stone Hammer Crusher. The OTR results for the EVOH32-1 (one layer of PA blend) and the control are statistically similar.
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On the other hand,Facroty Price CNC Horizontal Type Aluminum and UPVC Window Door Bending Machine Window Machine. In this case for cuts that are much longer than wider the package may not wrap the cut evenly allowing more fluid to exudate the beef tissue and rendering a loose appearance.
4. Conclusions
We concluded that film samples containing EVOH 32%Wholesale Hot Sale Disposable Vape Pen Pod System Vaporizer Electronic Cigarette% mol. Furthermore, the EVOH32-2,Lush Ice Mango Mint Great Taste Custom Pod Electronic Cigarette Disposable/6+aPA blend, shows the lowest OTR values, supporting the positive roll played by the aPA in the blend to improve the gas and moisture barrier under high moisture.
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In summary, the results obtained under controlled conditions indicate that the nine layer films containing EVOH 32% mol of ethylene, ionomer and PA 66/6+aPA blend in its composition, and especially the structure with EVOH 32%Fully Automatic Battery Cage for Layer,Nice Design Wall Plate Furniture Socket Lgt-Ws02, in addition to be chlorine free and not requiring the radiation crosslinking used in the production of films made with EVA, PVDC and PE.
The authors recognize that although the promising results obtained showing that the EVOH32-2 film structure might perform adequately to preserve fresh beef, in actual production, storage and transportation, a final conclusion would require to repeat this work in actual meat production lines and subjecting the packages to conventional transportation and storage conditions. Therefore, further studies must be carried out to evaluate the performance of such films in a large scale experiment.