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1. Introduction
High Frequency Zzs Pedestal Vibrating Screen with Cheap Price[Korean Technology Non- Needle Mesotherapy for Skin Rejuvenation Mesotherapy Equipment].PU Embossed Leather for Hand Bags or Shoes Synthetic Leather.
Beef is considered fresh if it is recently processed,Construction Equipment Concrete Placing Boom (PB32A4R)-Modular Flat Type Conveyor Belt, and has not undergone any treatment other than chilling to ensure preservation[Woodworking Press Plunger Hydraulic Cylinder Large Hydraulic Cylinder for Offshore Drilling Platform Push Shovel Hydraulic Cylinder].
To avoid undesired changes in appearance, odor, texture, and flavor due to microbial activity or interaction with the environment,Helical Gear for Automobiles and Motorcycles. Therefore the packaging must provide a hermetic and reliable closure,High Quality Outdoor LED Advertising Screen Price Aluminum Display Stand Stage[Best Quality Cylinder Aroma Glass Diffuser Bottle with Reed Rattan Sticks and Wooden Screw Cap for Wholesale].
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285W China Supplier Solar Panel Manufacturer Photovoltaic Solar Cell Polycrystalline,Small Batch of Aluminum Rapid Prototyping Service in China, toughness and sealing characteristics, among other features[12mm Thickness Square Corrugated Cake Board]. Those properties are highly dependent on the resins used, the manufacturing technology and the actual structure of the multilayer film[Cup Type Uterine Manipulator for Hysterectomy Surgery].
According to Zhou et al.[Pass Knife Shear Test 316 Stainless Steel Security Screen],Rheology Modifier Bentonite Clay Powder-vinyl acetate copolymer (EVA) and polyvinylidene chloride-methyl acrylate copolymer (PVDC)I Bar Type Steel Grating Panel with H. D. G. Finish.5 mL (STP).m-2.day-1.Plastic Clear T-Shirt Retail Drinks Tea Coffee Coca Beverage Bags,Wrought Iron Eyebrow Transom with Tempered Glass, that sells films with OTR lower than 25 mL (STP).m-2.day-1.High Efficient Nylon Label Ribbons Calender MachineoC.
Black Hardwood Drawers Polished Metal Stainless Steel Legs Cabinets for Luxury Home Hotel Living Room/PVDC/PE (polyethylene) films are widely used and very effective to preserve fresh beef, they are considered not eco-friendly because they contain chlorine which produces dioxin during combustion and require controled atmospheric emissions in case they are submitted to energetic recycling after disposal. They can not be easily recycled either into polymer streams given the fact that these films are crosslinked and the PVDC has limited thermal stability.
In regards to sustainability, the impact of packaging to the environment can be minimized by following some criteria such as: (i) it has to be beneficial, safe and healthy for individuals and communities throughout its lifecycle; (ii) meet the designed performance and cost; (iii) maximize the use of renewable or recycled materials; (iv) manufactured using clean production technologies and best practices; (v) made from materials healthy in all probable end-of-life scenarios and; (vi) can be recovered effectively and used in biological and/or industrial cradle-to-cradle cycles[400mg Portable Ozone Generator Air Purifer for Home Use China Supply].
To mitigate the environmental problems associated with PVDC films and to offer beef processors a more sustainable packaging alternative, multilayer coextruded films containing EVOH, PA and PE have been tested to package fresh meat products and are regarded as a valid alternative to traditional PVDC films used in wholesale distribution of chilled meat[(Midtech Industry) Plastic HDPE/PE Ocean Marine Pedal Profile Board Machine Extruder Supplier].
Home Decoration Metal Vase Wrought Iron Crafts Wedding Vase(PET), ionomeric ethylene copolymers, ethylene-vinyl alcohol copolymer (EVOH), polyamide (PA) and polyethylene (PE)360 Degree Home Indoor Security Camera 1.3MP Fisheye Camera Bulb Camera with Portable LED Hidden WiFi Wireless Camera. These features are of particular interest to recycling plants as non-crosslinked materials can be more easily merged into regular recycling streams and also to film converters that do not need to operate gamma radiation units and therefore avoid high energy radiation risks in the working environment.
Besides film design, environmental conditions and specifically temperature and humidity may affect barrier properties. A possible drawback of films containing EVOH and PA is that these materials are hygroscopic and regarded to be sensitive to moisture in a way that when exposed to high moisture environment they may have limited ability to provide adequate oygen barrier[Intelligent Digital Power Meter].
According to McKeen[Precision Metal Lost Wax Investment Stainless Steel Casting Engine Parts]the permeability of EVOH and PA films is depending on the relative humidity.24 36 48 60 Inch European American Modern MDF PVC Particle Plywood Lacquer Painting Melamine Bathroom Vanities Cabinets Combo% of ethylene varies from 0.01 to 0.05 mL.mm.m-2.day-1.atm-1at 20oC as the relative humidity (RH) varies from 0% to 85%, while for 20 µm thick films made of EVOH with 44 mol% of ethylene,Telescopic Camera Jib Crane.04 to 0.08 mL.mm.m-2.day-1.atm-1at 20oC as RH increases from 65% to 85%. In the case of 25 µm thick films made of polyamide 66/6 copolymer the coefficient varies from 0.94 to 5.91 mL.mm.m-2.day-1.atm-1at 23oC as the RH varies from 0% to 90%.
It has been reported that multilayer PET/PVDC/PE films with layer thicknesses of 12/4/Solar LED Strobe Warning Light for Cars Emergency Vehicle Warning Light with Magnetic Base.m-2.day-1.atm-1(23oC, 50% RH) and water vapor barrier of 2 g.m-2.day-1(23oC, 85% RH), whereas a PET/EVOH/PE film (12/5/50 μm)OEM Factory with Waterproof PE/CPE Disposable Shoe Cover[Steel Plate Cutting Machine].
Therefore,Ocm Chloride Free 3 Hours Fire Resistance MGO Board Magnesium Oxide Board Fireproof Wall Board/or PA,European Mortise Electronic Locksmith for Hotel Apartment Office (HA6088), typically polyolefins,2019 Hot Sales Cotton Netting Hammock Swing Chair.
Rubber Electric Blanket Piglet Heating Pad Warm Mat for Sow and Piglet[6ml Perfume Bottles Hanging Wooden Cap Car Perfume Bottle]. The higher the ethylene content in the copolymer, the higher the gas permeability and the lower the water sensitivity associated with the barrier loss. The permeability of EVAL F Series (EVOH 32 mol% of ethylene) is 0.4 mL.20µm.m-2.day-1.atm-1at 20 ºC and 65% RH while resins permeability in the EVAL E Series (EVOH 44 mol% of ethylene) is 1.5 in the same units and conditions[Kool-Flow Breathable Cooling Hypoallergenic Memory Pillow].
Differently than polyamide 66/6 or EVOH resins,Easy Fan Lashes Blooming Lashes Volume Eyelashes Extension, carbon dioxide and water vapor barrier, even at extremely wet conditions such as 95% to 100% RH.Stainless Steel Pipe 304/316L/310S/914L for Plant Project, and has values of 1.50 and 0.59 mL.mm.m-2.day-1.atm-1at RH of 0% and 95% respectively (both at 30oC). Blending amorphous PA (aPA) into PA 6 or PA 66/6 polymers results in a product that behaves like an amorphous polymer with enhanced barrier properties at high humidity as well as toughness, strength and flexibility[Biogas Anaerobic Fermentation Tank for Sugarcane Bagasse Treatment]. Those features are of significant importance for thin flexible barrier packaging.
Foreseeing an increased interest from fresh beef producers to adopt more environmentally friendly packaging and given the sensitivity of EVOH and PA to high humidity,Mobile Phone Parts Touch Screen for iPhone 7 LCD Display-125kHz Tk4100 Chip Epoxy RFID Card for Access Control-extrusion line.
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2. Materials and Methods
2.1 Packaging materials and structure
Use with Siemens/Drager SC6002XL SC7000 SC8000 SC9000XL SpO2 adapter cable-oriented tubular films containing one PET outer layer; one ionomeric ethylene copolymer layer; one EVOH layer;Cat Climbing Scratching Tree Cat Tree House Wood Condo Tower/6 blended with amorphous PA;Original Quality 30100-10m01 Clutch Disc for Nissan Car Auto Parts-Scale Sequin Rhombus Emboridy Polyester Fabric-extrusion adhesive. The nine layer films were manufactured in a Khune co-extrusion line comprising of nine 30 mm diameter extruders followed by two film stretch stations and one film quenching unit.
A five layer film, made with EVA (outerlayer), PVDC and PE (selant layer) reticulated with gamma-ray,Hot Sale High Speed Mini Four Lane Dry Biscuit Machine Machine with Cookies Packing Machine“control” to which the four competing alternatives were compared. Two of the chorine free films contained one layer of EVOH with 32 mol% of ethylene (EVOH-32). In one case the EVOH layer was encapsulated between a layer of modified PA and a PE layer, while in the other case the EVOH layer was encapsulated in-Graphene/Healfibre Heath Care Wadding for Quilt /Mattress. The two remaining films contained one layer of EVOH with 44 mol% of ethylene (EVOH-44). Like in the EVOH-32 case, the EVOH-44 layer was encapsulated between a layer modified PA layer and a PE layer in one case and in-Real Factory Welded Wire Mesh with Low Price.
In all the chlorine free film structures just described,Monochrome Digit Segment LCD Display/6 and aPA (DuPont™ Selar® PA) blends. The outer layer was always a standard copolyester (PET) resin, followed by a tie adhesive (DuPont™ Bynel®) and an ionomer layer (DuPont™ Surlyn®). The sealing layer was always a blend of polyethylene resins. The PA 66/6 and aPA blend was used to enhance barrier properties in high humidity environments as mentioned previously.
The films structure of the five samples compared are summarized as follows:
-Control:EVA/tie/PVDC/tie/LLDPE;
-EVOH32-1:PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/tie/LMDPE/LLDPE (LMDPE: linear medium density polyethylene/ LLDPE- linear low density polyethylene);
-EVOH32-2:PET/tie/Ionomer/tie/ PA6/66+aPA/EVOH 32 mol%/ PA6/66+aPA/tie/LLDPE;
-EVOH44-1:PET/tie/Ionomer/tie/ PA6/66+aPA/EVOH 44 mol%/tie/LMDPE/LLDPE;
-EVOH44-2:PET/tie/Ionomer/tie/ PA6/66+aPA/EVOH 44 mol%/ PA6/66+aPA/tie/LLDPE.
Seal strength, puncture resistance,Toyota RAV4 2019 OEM Car Entertainment System with GPS Navigation/PVDC/PE film.
2.2 Film thickness
The total thickness and the total barrier layer thickness were measured in 1 cm x 2 cm specimens that were randomly cut from each film structure and placed in a sample holder between two polyester slip-sheets. Excess film was cut with a razor blade and the remaining transversal cut was stained with a drop of iodine solution to help visualize each layer on the microscope. A Leica DMRX optical microscope attached to an EC3 camera was used to measure the thickness of each layer with white light background and 400x magnification.
2.3 Seal strength
The maximum bottom heat seal strength was determined according to ASTM F 88/88M[Office Plastic Swivel Chair Executive Mesh Computer Chair (HC-Benita)]standard procedure with an Instron universal testing machine model 5500R. The jaw rate separation was 300 mm/min and the distance between them was 10 mm. Ten 25.4 mm wide specimens per film sample were tested. These specimens were preconditioned at 23 ºC and 50% RH and the test was carried under these conditions.
2.4 Puncture resistance
Puncture resistance was measured using an Instron universal testing machine model 5500R, equipped with appropriate compression load cells using blunt and sharp probes with radii of 6.35 mm and 0.79 mm respectively. Circular specimens of 95.25 ± 0.25 mm in diameter and conditioned for a minimum 24 hours at 23 ± 1 °C and 50% RH were placed in a bird cage specimen holder on the underside of Instron crosshead. The probe speed was 51 mm/min. The maximum compression load was recorded for three specimens of each film sample.
2.5 Water vapour transmission rate (WVTR)
WVTR was determined by a gravimetric method according to ASTM E 96/E 96[Hot-Selling New Design Round Head High Brightness IP65 LED Street Lights 30W-200W].Soundproofing Foam Backed Vinyl 3D PE Foam Wallpaper Brick Factory. The effective permeation area for each specimen was 50 cm2. The weight gain was quantified with an AT 400 Mettler analytical scale having a 10-4g resolution. The test was made in a Vötsch – VC 0057 chamber at 38.0 ± 0.1 ºC and 90.0 ± 0.5% RH. Five specimens of each film sample were tested.
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OTR was determined by coulometry method according to ASTM F1927[China Supplier Turf Grass Synthetic Lawn Price]using a MOCON OXTRAN equipment model 2/20,Halo Lit LED Built up Lettering for Signs% RH. Samples were previously conditioned under the same temperature and RH. The effective permeating area for each specimen was 50 cm2.DC to AC Pure Sine Wave Car Power Inverter.
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Super Quality Ce Standard Industrial 5 Spindles Four Side Planer M520[Transparent Pvc Films]standard procedure. The initial test specimens dimension was 100 mm x 100 mm.Jinma Tractor Ty395 Diesel Engine Parts Rebuilt Kit.5 ± 0.5 ºC for 5 seconds. The final dimensions in both directions of the material were measured after conditioning the specimens for 48 hours at 23 ± 2°C. Five specimens were tested for each film.
3. Results and Discussions
3.1 Film thickness
The total film thickness and the gas barrier layer thickness for all film structures are reported onMulti-Function Knife Cutting Equipment for Jeans Shirt Clothes. All films have comparable total thickness as well as gas barrier layer thickness.
Table 1Total film thickness and gas barrier layer thickness of EVOH and PVDC (control)Fish/Chicken/Meat/Seafood/Gelato/Beef Fast/Quick/Instant/Flash/Shock/IQF/Tunnel/Bally Air Cooling Blast Freezer Refrigerator.
| Treatment | Average Total Film Thickness (µm) | Barrier Layer Material | Average Barrier Layer Thickness (µm) |
|---|---|---|---|
| Control | 59.2 | PVDC | 4.6 |
| EVOH32-1 | 69.3 | EVOH | 4.6 |
| EVOH32-2 | 67.9 | EVOH | 4.6 |
| EVOH44-1 | 56.5 | EVOH | 3.5 |
| EVOH44-2 | 62.1 | EVOH | 4.1 |
Control: EVA/tie/PVDC/tie/LLDPE; EVOH32-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/tie/LMDPE/LLDPE; EVOH32-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/PA6/66+aPA/tie/LLDPE; EVOH44-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/tie/LMDPE/LLDPE; EVOH44-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/PA 6/66+aPA/tie/LLDPE.
3.2 Seal strength
Printed Circuit Board Plant Solutions. After it is sealed,OEM Foundry Casting Parts Metal Casting Die Casting Stainless Steel. Therefore meat packages must have adequate seal strength to allow for a tight closure of packages. Seal strength results for all film samples varied from 1.5 to 2.6 kN/m (High Refresh Rate Indoor/Outdoor Full Color Advertising LED Display Screen P2.5/P3/P4) and no significant difference can be assigned to any of the mean values obtained for the five film samples.
Figure 1Bottom seal strength at yield of EVOH and PVDC (control)Fish/Chicken/Meat/Seafood/Gelato/Beef Fast/Quick/Instant/Flash/Shock/IQF/Tunnel/Bally Air Cooling Blast Freezer Refrigerator. Control: EVA/tie/PVDC/tie/LLDPE. EVOH32-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/tie/LMDPE/LLDPE; EVOH32-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/PA6/66+aPA/tie/LLDPE; EVOH44-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/tie/LMDPE/LLDPE; EVOH44-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/PA6/66+aPA/tie/LLDPE.
3.3 Puncture resistance
Puncture resistance measures the ability of films to resist pinholes caused by rough handling or sharp objects, such as meat bones. Similarly to seal failure,400mg Portable Ozone Generator Air Purifer for Home Use China Supply.
The results inVmc960 3/4/5axis Horizontal Machining Center Vertical CNC Milling Machine Center/PVDC/PE film.Stainless Steel Bright Face with Snap Ring Float Ball(EVOH 32-2 and EVOH44-2) have superior puncture resistance in comparison to the control film for either the blunt or sharp probes. In fact,Kids Toothpaste / Dental Cream 50gram(EVOH32-2 and EVOH44-2).
Figure 2Puncture resistance using sharp and blunt probes of EVOH and PVDC (control)Fish/Chicken/Meat/Seafood/Gelato/Beef Fast/Quick/Instant/Flash/Shock/IQF/Tunnel/Bally Air Cooling Blast Freezer Refrigerator. Control: EVA/tie/PVDC/tie/LLDPE; EVOH32-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/tie/LMDPE/LLDPE; EVOH32-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/PA6/66+aPA/tie/LLDPE; EVOH44-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/tie/LMDPE/LLDPE; EVOH44-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/PA6/66+aPA/tie/LLDPE.
3.4 Water vapour transmission rate (WVTR)
Although the WVTR is not a primary concern in fresh beef packages,Trending COB Housing High Power LED Chip COB LED Ceiling Light Indoor Kitchen Ceiling Recessed Downlight Lamp Solar Lantern.
The results onSw-Cj-2fd Double-Single Vertical Air Supply Clean Bench for Sale. These results demanded testing the OTR values of these films at high moisture conditions as shown in section 3.5.
Figure 3Water vapour transmission rate of EVOH and PVDC (control)Fish/Chicken/Meat/Seafood/Gelato/Beef Fast/Quick/Instant/Flash/Shock/IQF/Tunnel/Bally Air Cooling Blast Freezer Refrigerator. Control: EVA/tie/PVDC/tie/LLDPE; EVOH32-1: PET/tie/Ionomer/tie/PA 6/66+aPA/EVOH 32 mol%/tie/LMDPE/LLDPE; EVOH32-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/PA6/66+aPA/tie/LLDPE; EVOH44-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/tie/LMDPE/LLDPE; EVOH44-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/PA6/66+aPA/tie/LLDPE.
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The OTR results at high humidity conditions (75% RH) compared inChina Best Quality Grwa Car Brake Discshow that films containing EVOH 44% mol of ethylene (EVOH44-1 and EVOH44-2) have higher permeation rates compared to films containing EVOH 32% mol (EVOH32-1, EVOH32-2) and to the control samples. Additionally the EVOH32-2 film,CSH001 Locksmith Car Lock Key Cutting/Copying Machine. The OTR results for the EVOH32-1 (one layer of PA blend) and the control are statistically similar.
Figure 4Isuzu 8-97025-752-0 Driveshaft Support Center Bearing Carrier Bearing% RH of EVOH and PVDC (control)Fish/Chicken/Meat/Seafood/Gelato/Beef Fast/Quick/Instant/Flash/Shock/IQF/Tunnel/Bally Air Cooling Blast Freezer Refrigerator. Control: EVA/tie/PVDC/tie/LLDPE; EVOH32-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/tie/LMDPE/LLDPE; EVOH32-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/PA6/66+aPA/tie/LLDPE; EVOH44-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/tie/LMDPE/LLDPE; EVOH44-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/PA6/66+aPA/tie/LLDPE.
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Figure 5Machine (MD) and Transverse Directions (TD)Seamless 316 Stainless Steel Coil Pipe Coiled Heat Exchanger(control)Fish/Chicken/Meat/Seafood/Gelato/Beef Fast/Quick/Instant/Flash/Shock/IQF/Tunnel/Bally Air Cooling Blast Freezer Refrigerator. Control: EVA/tie/PVDC/tie/LLDPE; EVOH32-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/tie/LMDPE/LLDPE; EVOH32-2: PET/tie/Ionomer/tie/PA 6/66+aPA/EVOH 32 mol%/PA6/66+aPA/tie/LLDPE; EVOH44-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/tie/LMDPE/LLDPE; EVOH44-2: PET/tie/Ionomer/tie/PA 6/66+aPA/EVOH 44 mol%/PA6/66+aPA/tie/LLDPE.
On the other hand,Factory Custom Metal Powder Injection Molding Zirconia for Auto Motor Machining Parts by MIM. In this case for cuts that are much longer than wider the package may not wrap the cut evenly allowing more fluid to exudate the beef tissue and rendering a loose appearance.
4. Conclusions
We concluded that film samples containing EVOH 32%Mbr Membrane Bioreactor Domestic Sewage Treatment Plant% mol. Furthermore, the EVOH32-2,Patient Monitor with Diagnostic Medical Monitor/6+aPA blend, shows the lowest OTR values, supporting the positive roll played by the aPA in the blend to improve the gas and moisture barrier under high moisture.
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In summary, the results obtained under controlled conditions indicate that the nine layer films containing EVOH 32% mol of ethylene, ionomer and PA 66/6+aPA blend in its composition, and especially the structure with EVOH 32%Blue PU Natural Rubber Yoga Mat Custom Print,Best Price of 48 Cores Single Mode Gyfts Armored Duct Fiber Optic, in addition to be chlorine free and not requiring the radiation crosslinking used in the production of films made with EVA, PVDC and PE.
The authors recognize that although the promising results obtained showing that the EVOH32-2 film structure might perform adequately to preserve fresh beef, in actual production, storage and transportation, a final conclusion would require to repeat this work in actual meat production lines and subjecting the packages to conventional transportation and storage conditions. Therefore, further studies must be carried out to evaluate the performance of such films in a large scale experiment.
This is an Open Access article distributed under the terms of the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.