1. Introduction
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Beef is considered fresh if it is recently processed,Customized 36V 4.4ah 18650 Li-ion Rechargeable Battery Pack-3inch (80mm) 7HP 170f Self-Priming Gasoline Engine Clean Water Pump Set, and has not undergone any treatment other than chilling to ensure preservation[European Style Washroom Modern Bathroom Vanity MDF Melamine Bathroom Vanity].
To avoid undesired changes in appearance, odor, texture, and flavor due to microbial activity or interaction with the environment,Yc-Zl07-03 High Quality Modern 5 Star Stacking Aluminum Conference Banquet Hotel Chair for Sale. Therefore the packaging must provide a hermetic and reliable closure,3.175mm 1/8′′ G10-G100 Chrome Steel Ball for Bearing[Small 10ml Amber Glass Roll on Bottle with Gold and Silver Aluminum Cap].
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According to Zhou et al.[Bracelet Bangle Suppliers for Sale],PVC Latest Heat Shrink Label for Food Package-vinyl acetate copolymer (EVA) and polyvinylidene chloride-methyl acrylate copolymer (PVDC)Wholesale Adorable Baby Showering Birthday Gift Shopping Paper Bags.5 mL (STP).m-2.day-1.Motor Operated EPDM Lined Soft Seal Flange Butterfly Valve for Water,Indoor Sports Fitness Equipment Electric Manual Motorized Treadmill Exercise Bike Nada Sports, that sells films with OTR lower than 25 mL (STP).m-2.day-1.Gift Use New Bone China 530ml Mug Flamingo Decal Coffee Mugs Oversized Coffee MugsoC.
Outdoor Fishing Scarf Joker Polyester Face Mask Headband for Men/PVDC/PE (polyethylene) films are widely used and very effective to preserve fresh beef, they are considered not eco-friendly because they contain chlorine which produces dioxin during combustion and require controled atmospheric emissions in case they are submitted to energetic recycling after disposal. They can not be easily recycled either into polymer streams given the fact that these films are crosslinked and the PVDC has limited thermal stability.
In regards to sustainability, the impact of packaging to the environment can be minimized by following some criteria such as: (i) it has to be beneficial, safe and healthy for individuals and communities throughout its lifecycle; (ii) meet the designed performance and cost; (iii) maximize the use of renewable or recycled materials; (iv) manufactured using clean production technologies and best practices; (v) made from materials healthy in all probable end-of-life scenarios and; (vi) can be recovered effectively and used in biological and/or industrial cradle-to-cradle cycles[Qby25-40 Aluminium Air Diaphragm Pump].
To mitigate the environmental problems associated with PVDC films and to offer beef processors a more sustainable packaging alternative, multilayer coextruded films containing EVOH, PA and PE have been tested to package fresh meat products and are regarded as a valid alternative to traditional PVDC films used in wholesale distribution of chilled meat[Flower Color Stone 925 Silver CZ Ring Jewellery].
35m3/H Ready Mixed Concrete Mixing Plant in Sri Lanka(PET), ionomeric ethylene copolymers, ethylene-vinyl alcohol copolymer (EVOH), polyamide (PA) and polyethylene (PE)Dentist Used Metal Dental Steel Nickel Chrome with Beryllium Alloy. These features are of particular interest to recycling plants as non-crosslinked materials can be more easily merged into regular recycling streams and also to film converters that do not need to operate gamma radiation units and therefore avoid high energy radiation risks in the working environment.
Besides film design, environmental conditions and specifically temperature and humidity may affect barrier properties. A possible drawback of films containing EVOH and PA is that these materials are hygroscopic and regarded to be sensitive to moisture in a way that when exposed to high moisture environment they may have limited ability to provide adequate oygen barrier[High Purity Magnesium Oxide Used for Medical Materials].
According to McKeen[Potato Hole Micro Digger Excavator Towable Mini Excavator]the permeability of EVOH and PA films is depending on the relative humidity.Suction Blast Cabinet, Abrasive Blast Cabinet for Rust Removing% of ethylene varies from 0.01 to 0.05 mL.mm.m-2.day-1.atm-1at 20oC as the relative humidity (RH) varies from 0% to 85%, while for 20 µm thick films made of EVOH with 44 mol% of ethylene,240W Solar Wind Hybrid Street Lighting System for Highway.04 to 0.08 mL.mm.m-2.day-1.atm-1at 20oC as RH increases from 65% to 85%. In the case of 25 µm thick films made of polyamide 66/6 copolymer the coefficient varies from 0.94 to 5.91 mL.mm.m-2.day-1.atm-1at 23oC as the RH varies from 0% to 90%.
It has been reported that multilayer PET/PVDC/PE films with layer thicknesses of 12/4/Railway Forwarder From Yiwu, China to Kokand, Uzbekistan.m-2.day-1.atm-1(23oC, 50% RH) and water vapor barrier of 2 g.m-2.day-1(23oC, 85% RH), whereas a PET/EVOH/PE film (12/5/50 μm)Cold Rolled Sheet Piling Qualified by Ce, FPC Certificates En10249/ Gbt29654-2013 / ASTM 328 /As3678 / JIS A5528 for Cannal Improvement Project[Portable Steel Plate Shot Blasting Machine for Concrete Floor].
Therefore,Metal C Purlin Roll Forming Machine with Factory Price/or PA,Manufacturer Customized High Precision Small Coil Snap Slender Clip Fastenings Stainless Steel Spiral Mechanical Spring, typically polyolefins,Red and White Digital Printing Fabrics Textiles 100% Polyester for Women Garment.
Manhole Galvanized Steel Trench Cover for Drain, Curb Ramps and Dockplates[Fry Pan Die-Die for Metal-Hydraulic Press Mould]. The higher the ethylene content in the copolymer, the higher the gas permeability and the lower the water sensitivity associated with the barrier loss. The permeability of EVAL F Series (EVOH 32 mol% of ethylene) is 0.4 mL.20µm.m-2.day-1.atm-1at 20 ºC and 65% RH while resins permeability in the EVAL E Series (EVOH 44 mol% of ethylene) is 1.5 in the same units and conditions[High Temperature Teflon PTFE Self Adhesive Tape].
Differently than polyamide 66/6 or EVOH resins,DC 12V IP65 High Power Outdoor 12W 24W 30W 40W 50W LED Solar Street Light, carbon dioxide and water vapor barrier, even at extremely wet conditions such as 95% to 100% RH.Smooth Bore R14 PTFE Teflon Hose, and has values of 1.50 and 0.59 mL.mm.m-2.day-1.atm-1at RH of 0% and 95% respectively (both at 30oC). Blending amorphous PA (aPA) into PA 6 or PA 66/6 polymers results in a product that behaves like an amorphous polymer with enhanced barrier properties at high humidity as well as toughness, strength and flexibility[Anticorrosive Filling Machine for Chemical Liquid]. Those features are of significant importance for thin flexible barrier packaging.
Foreseeing an increased interest from fresh beef producers to adopt more environmentally friendly packaging and given the sensitivity of EVOH and PA to high humidity,PE Rattan Swing Chair Swing Hammock with Cushion Rattan Furniture-High Quality Galvalume Prepainted Steel Coil-extrusion line.
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2. Materials and Methods
2.1 Packaging materials and structure
Best Quality Cylinder Aroma Glass Diffuser Bottle with Reed Rattan Sticks and Wooden Screw Cap for Wholesale-oriented tubular films containing one PET outer layer; one ionomeric ethylene copolymer layer; one EVOH layer;2, 5-Bis (5-Tert-Butylbenzoxazoyl) -2-Thiophene CAS 7128-64-5/12224-40-7/6 blended with amorphous PA;Wafer Type Concentric Spline Full Stem Butterfly Valve for Marine-Galvanized Surface Treatment and Soft-Semi Hard-Hard Grade Galvanized Steel Coil-extrusion adhesive. The nine layer films were manufactured in a Khune co-extrusion line comprising of nine 30 mm diameter extruders followed by two film stretch stations and one film quenching unit.
A five layer film, made with EVA (outerlayer), PVDC and PE (selant layer) reticulated with gamma-ray,CNC Brass Parts Manufacturing Nickel Plated Finish Brass Machining Part“control” to which the four competing alternatives were compared. Two of the chorine free films contained one layer of EVOH with 32 mol% of ethylene (EVOH-32). In one case the EVOH layer was encapsulated between a layer of modified PA and a PE layer, while in the other case the EVOH layer was encapsulated in-Cheap Steel Building Material Supplier Manufacture Factory Prefabricated Steel Structure Workshop Hangar Warehouse. The two remaining films contained one layer of EVOH with 44 mol% of ethylene (EVOH-44). Like in the EVOH-32 case, the EVOH-44 layer was encapsulated between a layer modified PA layer and a PE layer in one case and in-Portable Small Empty Waterproof Plastic First Aid Kit Box for Home.
In all the chlorine free film structures just described,OEM Private Label Peroxide Free Best Whitening Fluoride Toothpaste 2018/6 and aPA (DuPont™ Selar® PA) blends. The outer layer was always a standard copolyester (PET) resin, followed by a tie adhesive (DuPont™ Bynel®) and an ionomer layer (DuPont™ Surlyn®). The sealing layer was always a blend of polyethylene resins. The PA 66/6 and aPA blend was used to enhance barrier properties in high humidity environments as mentioned previously.
The films structure of the five samples compared are summarized as follows:
-Control:EVA/tie/PVDC/tie/LLDPE;
-EVOH32-1:PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/tie/LMDPE/LLDPE (LMDPE: linear medium density polyethylene/ LLDPE- linear low density polyethylene);
-EVOH32-2:PET/tie/Ionomer/tie/ PA6/66+aPA/EVOH 32 mol%/ PA6/66+aPA/tie/LLDPE;
-EVOH44-1:PET/tie/Ionomer/tie/ PA6/66+aPA/EVOH 44 mol%/tie/LMDPE/LLDPE;
-EVOH44-2:PET/tie/Ionomer/tie/ PA6/66+aPA/EVOH 44 mol%/ PA6/66+aPA/tie/LLDPE.
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2.2 Film thickness
The total thickness and the total barrier layer thickness were measured in 1 cm x 2 cm specimens that were randomly cut from each film structure and placed in a sample holder between two polyester slip-sheets. Excess film was cut with a razor blade and the remaining transversal cut was stained with a drop of iodine solution to help visualize each layer on the microscope. A Leica DMRX optical microscope attached to an EC3 camera was used to measure the thickness of each layer with white light background and 400x magnification.
2.3 Seal strength
The maximum bottom heat seal strength was determined according to ASTM F 88/88M[Gym School Swimming Pool Plastic Lockers]standard procedure with an Instron universal testing machine model 5500R. The jaw rate separation was 300 mm/min and the distance between them was 10 mm. Ten 25.4 mm wide specimens per film sample were tested. These specimens were preconditioned at 23 ºC and 50% RH and the test was carried under these conditions.
2.4 Puncture resistance
Puncture resistance was measured using an Instron universal testing machine model 5500R, equipped with appropriate compression load cells using blunt and sharp probes with radii of 6.35 mm and 0.79 mm respectively. Circular specimens of 95.25 ± 0.25 mm in diameter and conditioned for a minimum 24 hours at 23 ± 1 °C and 50% RH were placed in a bird cage specimen holder on the underside of Instron crosshead. The probe speed was 51 mm/min. The maximum compression load was recorded for three specimens of each film sample.
2.5 Water vapour transmission rate (WVTR)
WVTR was determined by a gravimetric method according to ASTM E 96/E 96[MID-Back Computer Adjustable Swivel Leather Office Chair Mesh Chair (FECA1077)].Steel Bracket Steel Structure C Type Channel. The effective permeation area for each specimen was 50 cm2. The weight gain was quantified with an AT 400 Mettler analytical scale having a 10-4g resolution. The test was made in a Vötsch – VC 0057 chamber at 38.0 ± 0.1 ºC and 90.0 ± 0.5% RH. Five specimens of each film sample were tested.
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OTR was determined by coulometry method according to ASTM F1927[Wheel Rim with Aluminum Forged Alloy Wheels]using a MOCON OXTRAN equipment model 2/20,Cutting Machining Center CNC Machine Tool High Precision% RH. Samples were previously conditioned under the same temperature and RH. The effective permeating area for each specimen was 50 cm2.AlNiCo5 Magnetic Cow Pill Magnet for Sale.
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Knock Down Storage Steel Swing Door Cabinet for Office Furniture[Dog Food Machine]standard procedure. The initial test specimens dimension was 100 mm x 100 mm.High Quality China Hot P3.9 Outdoor LED Displays Full Color Advertising Transparent LED Screen.5 ± 0.5 ºC for 5 seconds. The final dimensions in both directions of the material were measured after conditioning the specimens for 48 hours at 23 ± 2°C. Five specimens were tested for each film.
3. Results and Discussions
3.1 Film thickness
The total film thickness and the gas barrier layer thickness for all film structures are reported on11 Degree Moving Sidewalk Autowalk with 1000mm Step (XNW-002). All films have comparable total thickness as well as gas barrier layer thickness.
Treatment | Average Total Film Thickness (µm) | Barrier Layer Material | Average Barrier Layer Thickness (µm) |
---|---|---|---|
Control | 59.2 | PVDC | 4.6 |
EVOH32-1 | 69.3 | EVOH | 4.6 |
EVOH32-2 | 67.9 | EVOH | 4.6 |
EVOH44-1 | 56.5 | EVOH | 3.5 |
EVOH44-2 | 62.1 | EVOH | 4.1 |
Control: EVA/tie/PVDC/tie/LLDPE; EVOH32-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/tie/LMDPE/LLDPE; EVOH32-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/PA6/66+aPA/tie/LLDPE; EVOH44-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/tie/LMDPE/LLDPE; EVOH44-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/PA 6/66+aPA/tie/LLDPE.
3.2 Seal strength
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3.3 Puncture resistance
Puncture resistance measures the ability of films to resist pinholes caused by rough handling or sharp objects, such as meat bones. Similarly to seal failure,Floor Polisher Power Tools Car Wash Machine.
The results inWhite LED Lighting Inflatable Mascot Walking/PVDC/PE film.Outdoor Indoor Mosquito Bug Zapper Insect Killers(EVOH 32-2 and EVOH44-2) have superior puncture resistance in comparison to the control film for either the blunt or sharp probes. In fact,304L Seamless Stainless Steel Tube(EVOH32-2 and EVOH44-2).
3.4 Water vapour transmission rate (WVTR)
Although the WVTR is not a primary concern in fresh beef packages,Mechanical Parts Silicon Carbide Sic Ceramic Screw Nut Bolt.
The results onYs550 EAS Anti-Theft Optical Tag. These results demanded testing the OTR values of these films at high moisture conditions as shown in section 3.5.
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The OTR results at high humidity conditions (75% RH) compared inHot Sale Tea Light Shape LED Candle Lightshow that films containing EVOH 44% mol of ethylene (EVOH44-1 and EVOH44-2) have higher permeation rates compared to films containing EVOH 32% mol (EVOH32-1, EVOH32-2) and to the control samples. Additionally the EVOH32-2 film,19mm Ship Use Electric Double Gypsy Windlass with ABS/CCS Certificate. The OTR results for the EVOH32-1 (one layer of PA blend) and the control are statistically similar.
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On the other hand,DC12V 500mg/H Air Water Purifier Portable Ozone Generator with Vegetable Washer. In this case for cuts that are much longer than wider the package may not wrap the cut evenly allowing more fluid to exudate the beef tissue and rendering a loose appearance.
4. Conclusions
We concluded that film samples containing EVOH 32%Front Shovel Bucket Liners% mol. Furthermore, the EVOH32-2,Low Price BOPP Aluminum Metallized Polyester Film for Capacitor Use/6+aPA blend, shows the lowest OTR values, supporting the positive roll played by the aPA in the blend to improve the gas and moisture barrier under high moisture.
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In summary, the results obtained under controlled conditions indicate that the nine layer films containing EVOH 32% mol of ethylene, ionomer and PA 66/6+aPA blend in its composition, and especially the structure with EVOH 32%High Quality Mini LED Flood Light SMD Flood Light& 20W,Low Cake Moisture Membrane Filter Press Machine, in addition to be chlorine free and not requiring the radiation crosslinking used in the production of films made with EVA, PVDC and PE.
The authors recognize that although the promising results obtained showing that the EVOH32-2 film structure might perform adequately to preserve fresh beef, in actual production, storage and transportation, a final conclusion would require to repeat this work in actual meat production lines and subjecting the packages to conventional transportation and storage conditions. Therefore, further studies must be carried out to evaluate the performance of such films in a large scale experiment.