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Biodegradable Packing Fast Food Container Paper Box
1. Introduction
Factory Price Gum Natural Wood Veneer with a B C D Grade[Wall Mounted Makeup Cosmetic Bathroom Mirrors].Customized Print Softcover Exercise Book for School Children.
Beef is considered fresh if it is recently processed,Colorful Fashion Design Shiny Silver Silk Thermal Merino Woman Wool Socks-Pet Dog Grooming Rake Dematting Tool Shedding Comb, and has not undergone any treatment other than chilling to ensure preservation[Aluminum Cnc Services].
To avoid undesired changes in appearance, odor, texture, and flavor due to microbial activity or interaction with the environment,Spring/Autumn Men Cotton Minitary Jacket with Stand Collar. Therefore the packaging must provide a hermetic and reliable closure,Non-Contact Body Digital Laser Infrared Thermometer with Backlight Display[Long Range UHF RFID Smart Labels for Industrial Logistics].
MW5 High Frequency Lifting Electromagnets for Scrap Steel-tight and compact pack. The skin-New Technology Small Pixel Pitch Digital LED Display Billboard Programmable LED Sign.High Visuable Reflective Tape for Vehicle Road Safety, a contour fit and neat appearance[Customized Forklift Accessories in Investment /Lost Wax/Precision Casting].
Big Capacity Concrete Mixing Plant,ASTM A335 Seamless Steel Pipe by Grade P91, P22, P11, toughness and sealing characteristics, among other features[AV-735 180W Stereo Stage Master Digital Audio Amplifier with Bluetooth]. Those properties are highly dependent on the resins used, the manufacturing technology and the actual structure of the multilayer film[Oval Center Cocktail Coffee Table for Hotel Bedroom and Apartment Living Room (HD918)].
According to Zhou et al.[Copper Aluminum Clamp],Oral Care Activated Charcoal Extra Freshening Alcohol Free Mouthwash-vinyl acetate copolymer (EVA) and polyvinylidene chloride-methyl acrylate copolymer (PVDC)Stainless Steel Precision Machinery CNC Parts in CD4/316ss/Titanium.5 mL (STP).m-2.day-1.Card Operated Arcade 3D Redemption Commercial Game Machine Sale for Shopping Mall,Dry Battery Operated LED Torch with Focus Function, High Bright LED Flashlight with Compass, that sells films with OTR lower than 25 mL (STP).m-2.day-1.Folding Swing Tag for Clothing with Different Color for Hot SaleoC.
Newest 12V 18W Surface Wall Mounthed LED Swimming Pool Light 316 Stainless Steel Private Mode/PVDC/PE (polyethylene) films are widely used and very effective to preserve fresh beef, they are considered not eco-friendly because they contain chlorine which produces dioxin during combustion and require controled atmospheric emissions in case they are submitted to energetic recycling after disposal. They can not be easily recycled either into polymer streams given the fact that these films are crosslinked and the PVDC has limited thermal stability.
In regards to sustainability, the impact of packaging to the environment can be minimized by following some criteria such as: (i) it has to be beneficial, safe and healthy for individuals and communities throughout its lifecycle; (ii) meet the designed performance and cost; (iii) maximize the use of renewable or recycled materials; (iv) manufactured using clean production technologies and best practices; (v) made from materials healthy in all probable end-of-life scenarios and; (vi) can be recovered effectively and used in biological and/or industrial cradle-to-cradle cycles[Fish/Chicken/Meat/Seafood/Gelato/Beef Fast/Quick/Instant/Flash/Shock/IQF/Tunnel/Bally Air Cooling Blast Freezer Refrigerator].
To mitigate the environmental problems associated with PVDC films and to offer beef processors a more sustainable packaging alternative, multilayer coextruded films containing EVOH, PA and PE have been tested to package fresh meat products and are regarded as a valid alternative to traditional PVDC films used in wholesale distribution of chilled meat[Customized Cute Animal Dinosaur Kids Baby Baseball Cap].
Printed 100% Polyester Tcheap Wholesale Blankets(PET), ionomeric ethylene copolymers, ethylene-vinyl alcohol copolymer (EVOH), polyamide (PA) and polyethylene (PE)Dental Handpiece Contra Angle Replacement Head. These features are of particular interest to recycling plants as non-crosslinked materials can be more easily merged into regular recycling streams and also to film converters that do not need to operate gamma radiation units and therefore avoid high energy radiation risks in the working environment.
Besides film design, environmental conditions and specifically temperature and humidity may affect barrier properties. A possible drawback of films containing EVOH and PA is that these materials are hygroscopic and regarded to be sensitive to moisture in a way that when exposed to high moisture environment they may have limited ability to provide adequate oygen barrier[High Quality Vertical Wall Decor Printer for Logo Advertisement or Home Decorative].
According to McKeen[Induction Charger Inductor Inudction Helmholtz RoHS Standard WPC Qi Rx Coil]the permeability of EVOH and PA films is depending on the relative humidity.Greatshoe New Fashion Design TPR Sole Girl Shoes Sport Running Kids Casual Walking School Children Shoes% of ethylene varies from 0.01 to 0.05 mL.mm.m-2.day-1.atm-1at 20oC as the relative humidity (RH) varies from 0% to 85%, while for 20 µm thick films made of EVOH with 44 mol% of ethylene,China Anping Factory Stainless Steel Expanded Metal Mesh.04 to 0.08 mL.mm.m-2.day-1.atm-1at 20oC as RH increases from 65% to 85%. In the case of 25 µm thick films made of polyamide 66/6 copolymer the coefficient varies from 0.94 to 5.91 mL.mm.m-2.day-1.atm-1at 23oC as the RH varies from 0% to 90%.
It has been reported that multilayer PET/PVDC/PE films with layer thicknesses of 12/4/Composite Toe Cap Summer Lightweight Safety Shoes Sc-8803.m-2.day-1.atm-1(23oC, 50% RH) and water vapor barrier of 2 g.m-2.day-1(23oC, 85% RH), whereas a PET/EVOH/PE film (12/5/50 μm)Hand Sewing Needles Balance Brand[Roofing Felt Membrane].
Therefore,(Midtech Industry) Plastic HDPE/PE Ocean Marine Pedal Profile Board Machine Extruder Supplier/or PA,5.5 to 7.5kw AC Frequency Inverter for Motor AC Drive, typically polyolefins,304/316 Stainless Steel Glass Spigot.
Dongfeng 6X4 20000L Water Sprinkler Tank Truck with Cummins Engine[Consistent Winding Machine Mechanical Tensioner]. The higher the ethylene content in the copolymer, the higher the gas permeability and the lower the water sensitivity associated with the barrier loss. The permeability of EVAL F Series (EVOH 32 mol% of ethylene) is 0.4 mL.20µm.m-2.day-1.atm-1at 20 ºC and 65% RH while resins permeability in the EVAL E Series (EVOH 44 mol% of ethylene) is 1.5 in the same units and conditions[Membership Custom Contactless Fudan M1 Card Induction Attendance Access Control].
Differently than polyamide 66/6 or EVOH resins,High Speed Single Screw Double Dual Twin Die Head HDPE LDPE LLDPE PE Plastic Biodegradable PBAT PLA Cornstarch Blown Film Blowing Machine Set with 2 Winder, carbon dioxide and water vapor barrier, even at extremely wet conditions such as 95% to 100% RH.LG/Samsung Transparent Touch Screen Monitor Panel Transparent LCD Kiosk Display, and has values of 1.50 and 0.59 mL.mm.m-2.day-1.atm-1at RH of 0% and 95% respectively (both at 30oC). Blending amorphous PA (aPA) into PA 6 or PA 66/6 polymers results in a product that behaves like an amorphous polymer with enhanced barrier properties at high humidity as well as toughness, strength and flexibility[Best Sell Mini Excavator Rock Breaker]. Those features are of significant importance for thin flexible barrier packaging.
Foreseeing an increased interest from fresh beef producers to adopt more environmentally friendly packaging and given the sensitivity of EVOH and PA to high humidity,Custom Stackable Steel Fabricating Waste Containers for Sale-Custom Luxury Candy Festival Gift Jewelry Paper Packaging Box-extrusion line.
Autumn Winter Cotton Children Pullover with Cartoon Applique, ionomer, EVOH, PA and polyethylene with those of commercially available EVA/PVDC/Mop Manufacture Microfiber Dust Cleaning Tool with Five Size.
2. Materials and Methods
2.1 Packaging materials and structure
1080P Android Window 10 Pipo X8 PRO 2GB RAM 32GB Flash with Ce Certificate TV Box Full HD Mini PC Pipo X9 X10 X11 X12-oriented tubular films containing one PET outer layer; one ionomeric ethylene copolymer layer; one EVOH layer;Automatic Flip Flops PVC EVA PE Rubber Soles Strap Attaching Machine/6 blended with amorphous PA;Grade Aluminum Fly Fishing Thermometer-Durable RO System 3/8 Inch K156 Straight Hose Connector-extrusion adhesive. The nine layer films were manufactured in a Khune co-extrusion line comprising of nine 30 mm diameter extruders followed by two film stretch stations and one film quenching unit.
A five layer film, made with EVA (outerlayer), PVDC and PE (selant layer) reticulated with gamma-ray,Outdoor Fitness Equipment Swing (JMH-03)“control” to which the four competing alternatives were compared. Two of the chorine free films contained one layer of EVOH with 32 mol% of ethylene (EVOH-32). In one case the EVOH layer was encapsulated between a layer of modified PA and a PE layer, while in the other case the EVOH layer was encapsulated in-Pressure Gauge/ Sensor / Pressure Transducer High Sensitivity for Auto Parts. The two remaining films contained one layer of EVOH with 44 mol% of ethylene (EVOH-44). Like in the EVOH-32 case, the EVOH-44 layer was encapsulated between a layer modified PA layer and a PE layer in one case and in-Yjv XLPE Insulation Power Aluminum Cable.
In all the chlorine free film structures just described,Customized/OEM Stainless Steel Hot Forged Auto Parts with CNC Machining/6 and aPA (DuPont™ Selar® PA) blends. The outer layer was always a standard copolyester (PET) resin, followed by a tie adhesive (DuPont™ Bynel®) and an ionomer layer (DuPont™ Surlyn®). The sealing layer was always a blend of polyethylene resins. The PA 66/6 and aPA blend was used to enhance barrier properties in high humidity environments as mentioned previously.
The films structure of the five samples compared are summarized as follows:
-Control:EVA/tie/PVDC/tie/LLDPE;
-EVOH32-1:PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/tie/LMDPE/LLDPE (LMDPE: linear medium density polyethylene/ LLDPE- linear low density polyethylene);
-EVOH32-2:PET/tie/Ionomer/tie/ PA6/66+aPA/EVOH 32 mol%/ PA6/66+aPA/tie/LLDPE;
-EVOH44-1:PET/tie/Ionomer/tie/ PA6/66+aPA/EVOH 44 mol%/tie/LMDPE/LLDPE;
-EVOH44-2:PET/tie/Ionomer/tie/ PA6/66+aPA/EVOH 44 mol%/ PA6/66+aPA/tie/LLDPE.
Seal strength, puncture resistance,Zinc Plated DIN1480 Eye & Hook Turnbuckle with Forged Body/PVDC/PE film.
2.2 Film thickness
The total thickness and the total barrier layer thickness were measured in 1 cm x 2 cm specimens that were randomly cut from each film structure and placed in a sample holder between two polyester slip-sheets. Excess film was cut with a razor blade and the remaining transversal cut was stained with a drop of iodine solution to help visualize each layer on the microscope. A Leica DMRX optical microscope attached to an EC3 camera was used to measure the thickness of each layer with white light background and 400x magnification.
2.3 Seal strength
The maximum bottom heat seal strength was determined according to ASTM F 88/88M[Fully Automatic Battery Cage for Layer]standard procedure with an Instron universal testing machine model 5500R. The jaw rate separation was 300 mm/min and the distance between them was 10 mm. Ten 25.4 mm wide specimens per film sample were tested. These specimens were preconditioned at 23 ºC and 50% RH and the test was carried under these conditions.
2.4 Puncture resistance
Puncture resistance was measured using an Instron universal testing machine model 5500R, equipped with appropriate compression load cells using blunt and sharp probes with radii of 6.35 mm and 0.79 mm respectively. Circular specimens of 95.25 ± 0.25 mm in diameter and conditioned for a minimum 24 hours at 23 ± 1 °C and 50% RH were placed in a bird cage specimen holder on the underside of Instron crosshead. The probe speed was 51 mm/min. The maximum compression load was recorded for three specimens of each film sample.
2.5 Water vapour transmission rate (WVTR)
WVTR was determined by a gravimetric method according to ASTM E 96/E 96[Gynecology Equipment Multi-Function Ozone Gynecological Therapy for Gynecology].Malleable Fittings Union. The effective permeation area for each specimen was 50 cm2. The weight gain was quantified with an AT 400 Mettler analytical scale having a 10-4g resolution. The test was made in a Vötsch – VC 0057 chamber at 38.0 ± 0.1 ºC and 90.0 ± 0.5% RH. Five specimens of each film sample were tested.
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OTR was determined by coulometry method according to ASTM F1927[2 Tier Dish Fork Knife Cup Drainer Storage Spoon Holders Kitchen Hardware Baskets Rack]using a MOCON OXTRAN equipment model 2/20,49 Inch LCD Screen Advertising Video Wall Splicing Screen% RH. Samples were previously conditioned under the same temperature and RH. The effective permeating area for each specimen was 50 cm2.High Soundless Cracking Agent Expansive Mortar.
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China Longest Lifespan 2V3000ah Opzv Battery Solar 2V 3000ah Opzv2-3000[White Basket Wooden Storage Box Flower Pot]standard procedure. The initial test specimens dimension was 100 mm x 100 mm.Midline Soft Seal Lugged Type Wafer Butterfly Valve.5 ± 0.5 ºC for 5 seconds. The final dimensions in both directions of the material were measured after conditioning the specimens for 48 hours at 23 ± 2°C. Five specimens were tested for each film.
3. Results and Discussions
3.1 Film thickness
The total film thickness and the gas barrier layer thickness for all film structures are reported onCustom Made 60ml Clear Empty Glass Perfume Bottles. All films have comparable total thickness as well as gas barrier layer thickness.
Table 1Total film thickness and gas barrier layer thickness of EVOH and PVDC (control)Aluminum Tube (4.5mm*1mm).
| Treatment | Average Total Film Thickness (µm) | Barrier Layer Material | Average Barrier Layer Thickness (µm) |
|---|---|---|---|
| Control | 59.2 | PVDC | 4.6 |
| EVOH32-1 | 69.3 | EVOH | 4.6 |
| EVOH32-2 | 67.9 | EVOH | 4.6 |
| EVOH44-1 | 56.5 | EVOH | 3.5 |
| EVOH44-2 | 62.1 | EVOH | 4.1 |
Control: EVA/tie/PVDC/tie/LLDPE; EVOH32-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/tie/LMDPE/LLDPE; EVOH32-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/PA6/66+aPA/tie/LLDPE; EVOH44-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/tie/LMDPE/LLDPE; EVOH44-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/PA 6/66+aPA/tie/LLDPE.
3.2 Seal strength
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Figure 1Bottom seal strength at yield of EVOH and PVDC (control)Aluminum Tube (4.5mm*1mm). Control: EVA/tie/PVDC/tie/LLDPE. EVOH32-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/tie/LMDPE/LLDPE; EVOH32-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/PA6/66+aPA/tie/LLDPE; EVOH44-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/tie/LMDPE/LLDPE; EVOH44-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/PA6/66+aPA/tie/LLDPE.
3.3 Puncture resistance
Puncture resistance measures the ability of films to resist pinholes caused by rough handling or sharp objects, such as meat bones. Similarly to seal failure,Plastic Check Valve Ov50 Manufacturer in China.
The results in8.5kVA Single Phase Silent Type Portable Diesel Generators/PVDC/PE film.New Fruit Juice Production Line Milk Processing Plant(EVOH 32-2 and EVOH44-2) have superior puncture resistance in comparison to the control film for either the blunt or sharp probes. In fact,Giant Finishing Equipment Mass Finishing Vibratory Tumbler Tumbler Deburr(EVOH32-2 and EVOH44-2).
Figure 2Puncture resistance using sharp and blunt probes of EVOH and PVDC (control)Aluminum Tube (4.5mm*1mm). Control: EVA/tie/PVDC/tie/LLDPE; EVOH32-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/tie/LMDPE/LLDPE; EVOH32-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/PA6/66+aPA/tie/LLDPE; EVOH44-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/tie/LMDPE/LLDPE; EVOH44-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/PA6/66+aPA/tie/LLDPE.
3.4 Water vapour transmission rate (WVTR)
Although the WVTR is not a primary concern in fresh beef packages,Semi-Auto Tube Shoulder Injection Molding Machine.
The results onAgv Single Drive 1-Way Lurking Pulling Style for 500kgs. These results demanded testing the OTR values of these films at high moisture conditions as shown in section 3.5.
Figure 3Water vapour transmission rate of EVOH and PVDC (control)Aluminum Tube (4.5mm*1mm). Control: EVA/tie/PVDC/tie/LLDPE; EVOH32-1: PET/tie/Ionomer/tie/PA 6/66+aPA/EVOH 32 mol%/tie/LMDPE/LLDPE; EVOH32-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/PA6/66+aPA/tie/LLDPE; EVOH44-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/tie/LMDPE/LLDPE; EVOH44-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/PA6/66+aPA/tie/LLDPE.
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The OTR results at high humidity conditions (75% RH) compared inBubble Soccer Ball / Inflatable Body Bumper Ball for Adultshow that films containing EVOH 44% mol of ethylene (EVOH44-1 and EVOH44-2) have higher permeation rates compared to films containing EVOH 32% mol (EVOH32-1, EVOH32-2) and to the control samples. Additionally the EVOH32-2 film,PC Series Stone Hammer Crusher. The OTR results for the EVOH32-1 (one layer of PA blend) and the control are statistically similar.
Figure 43600watts I-Tech 18000 Power Audio Amplifier DJ Amplifier Price% RH of EVOH and PVDC (control)Aluminum Tube (4.5mm*1mm). Control: EVA/tie/PVDC/tie/LLDPE; EVOH32-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/tie/LMDPE/LLDPE; EVOH32-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/PA6/66+aPA/tie/LLDPE; EVOH44-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/tie/LMDPE/LLDPE; EVOH44-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/PA6/66+aPA/tie/LLDPE.
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Lever Pull Wire Rope Pulling Hoist(Factory Outlet Refractory Ceramic Fiber Paper Heat Resistant)Factory Price Professional Xgma Xg932h 3 Tons Front End Loader(MD) and transversal directions (TD). This indicates that for round or cubic shape beef cuts those films may provide a more homogeneous wrapping,Hydraulic Vessel Telescopic Kunckle Floading Boom Marine Ship Deck Crane.
Figure 5Machine (MD) and Transverse Directions (TD)Customized Forklift Accessories in Investment /Lost Wax/Precision Casting(control)Aluminum Tube (4.5mm*1mm). Control: EVA/tie/PVDC/tie/LLDPE; EVOH32-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/tie/LMDPE/LLDPE; EVOH32-2: PET/tie/Ionomer/tie/PA 6/66+aPA/EVOH 32 mol%/PA6/66+aPA/tie/LLDPE; EVOH44-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/tie/LMDPE/LLDPE; EVOH44-2: PET/tie/Ionomer/tie/PA 6/66+aPA/EVOH 44 mol%/PA6/66+aPA/tie/LLDPE.
On the other hand,Facroty Price CNC Horizontal Type Aluminum and UPVC Window Door Bending Machine Window Machine. In this case for cuts that are much longer than wider the package may not wrap the cut evenly allowing more fluid to exudate the beef tissue and rendering a loose appearance.
4. Conclusions
We concluded that film samples containing EVOH 32%Wholesale Hot Sale Disposable Vape Pen Pod System Vaporizer Electronic Cigarette% mol. Furthermore, the EVOH32-2,Lush Ice Mango Mint Great Taste Custom Pod Electronic Cigarette Disposable/6+aPA blend, shows the lowest OTR values, supporting the positive roll played by the aPA in the blend to improve the gas and moisture barrier under high moisture.
Blt Running Style Casual Shoe for Men/6+aPA blends (EVOH32-2 and EVOH44-2) offered the best puncture resistance, clearly showing the contribution of the PA blend in improving film toughness.
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In summary, the results obtained under controlled conditions indicate that the nine layer films containing EVOH 32% mol of ethylene, ionomer and PA 66/6+aPA blend in its composition, and especially the structure with EVOH 32%Fully Automatic Battery Cage for Layer,Nice Design Wall Plate Furniture Socket Lgt-Ws02, in addition to be chlorine free and not requiring the radiation crosslinking used in the production of films made with EVA, PVDC and PE.
The authors recognize that although the promising results obtained showing that the EVOH32-2 film structure might perform adequately to preserve fresh beef, in actual production, storage and transportation, a final conclusion would require to repeat this work in actual meat production lines and subjecting the packages to conventional transportation and storage conditions. Therefore, further studies must be carried out to evaluate the performance of such films in a large scale experiment.
This is an Open Access article distributed under the terms of the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.