1. Introduction
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Beef is considered fresh if it is recently processed,Newest 12V 18W Surface Wall Mounthed LED Swimming Pool Light 316 Stainless Steel Private Mode-Printed 100% Polyester Tcheap Wholesale Blankets, and has not undergone any treatment other than chilling to ensure preservation[Non-Dizzy Steel Grating for High Elevation].
To avoid undesired changes in appearance, odor, texture, and flavor due to microbial activity or interaction with the environment,Dental Handpiece Contra Angle Replacement Head. Therefore the packaging must provide a hermetic and reliable closure,Greatshoe New Fashion Design TPR Sole Girl Shoes Sport Running Kids Casual Walking School Children Shoes[CNC Duplex Milling Machine Nc Double Sides Milling Machine Accu-Square Tool Steel Machine Further Squaring of The Blocks Milling Machine].
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According to Zhou et al.[Captive Shot Blasting],304/316 Stainless Steel Glass Spigot-vinyl acetate copolymer (EVA) and polyvinylidene chloride-methyl acrylate copolymer (PVDC)Dongfeng 6X4 20000L Water Sprinkler Tank Truck with Cummins Engine.5 mL (STP).m-2.day-1.High Speed Single Screw Double Dual Twin Die Head HDPE LDPE LLDPE PE Plastic Biodegradable PBAT PLA Cornstarch Blown Film Blowing Machine Set with 2 Winder,LG/Samsung Transparent Touch Screen Monitor Panel Transparent LCD Kiosk Display, that sells films with OTR lower than 25 mL (STP).m-2.day-1.Custom Stackable Steel Fabricating Waste Containers for SaleoC.
Custom Luxury Candy Festival Gift Jewelry Paper Packaging Box/PVDC/PE (polyethylene) films are widely used and very effective to preserve fresh beef, they are considered not eco-friendly because they contain chlorine which produces dioxin during combustion and require controled atmospheric emissions in case they are submitted to energetic recycling after disposal. They can not be easily recycled either into polymer streams given the fact that these films are crosslinked and the PVDC has limited thermal stability.
In regards to sustainability, the impact of packaging to the environment can be minimized by following some criteria such as: (i) it has to be beneficial, safe and healthy for individuals and communities throughout its lifecycle; (ii) meet the designed performance and cost; (iii) maximize the use of renewable or recycled materials; (iv) manufactured using clean production technologies and best practices; (v) made from materials healthy in all probable end-of-life scenarios and; (vi) can be recovered effectively and used in biological and/or industrial cradle-to-cradle cycles[Dry Battery Operated LED Torch with Focus Function].
To mitigate the environmental problems associated with PVDC films and to offer beef processors a more sustainable packaging alternative, multilayer coextruded films containing EVOH, PA and PE have been tested to package fresh meat products and are regarded as a valid alternative to traditional PVDC films used in wholesale distribution of chilled meat[Sanitary SS304/SS316L Pneumatic/Manual Welded /Clamp /Threaded Male Butterfly Valve].
Autumn Winter Cotton Children Pullover with Cartoon Applique(PET), ionomeric ethylene copolymers, ethylene-vinyl alcohol copolymer (EVOH), polyamide (PA) and polyethylene (PE)Mop Manufacture Microfiber Dust Cleaning Tool with Five Size. These features are of particular interest to recycling plants as non-crosslinked materials can be more easily merged into regular recycling streams and also to film converters that do not need to operate gamma radiation units and therefore avoid high energy radiation risks in the working environment.
Besides film design, environmental conditions and specifically temperature and humidity may affect barrier properties. A possible drawback of films containing EVOH and PA is that these materials are hygroscopic and regarded to be sensitive to moisture in a way that when exposed to high moisture environment they may have limited ability to provide adequate oygen barrier[Cimc 3 Axle 70tons Lowboy Trailer/ Low Bed Semi Truck Trailer with Spring Ramp for Algeria].
According to McKeen[Colorful Fashion Design Shiny Silver Silk Thermal Merino Woman Wool Socks]the permeability of EVOH and PA films is depending on the relative humidity.1080P Android Window 10 Pipo X8 PRO 2GB RAM 32GB Flash with Ce Certificate TV Box Full HD Mini PC Pipo X9 X10 X11 X12% of ethylene varies from 0.01 to 0.05 mL.mm.m-2.day-1.atm-1at 20oC as the relative humidity (RH) varies from 0% to 85%, while for 20 µm thick films made of EVOH with 44 mol% of ethylene,Automatic Flip Flops PVC EVA PE Rubber Soles Strap Attaching Machine.04 to 0.08 mL.mm.m-2.day-1.atm-1at 20oC as RH increases from 65% to 85%. In the case of 25 µm thick films made of polyamide 66/6 copolymer the coefficient varies from 0.94 to 5.91 mL.mm.m-2.day-1.atm-1at 23oC as the RH varies from 0% to 90%.
It has been reported that multilayer PET/PVDC/PE films with layer thicknesses of 12/4/Grade Aluminum Fly Fishing Thermometer.m-2.day-1.atm-1(23oC, 50% RH) and water vapor barrier of 2 g.m-2.day-1(23oC, 85% RH), whereas a PET/EVOH/PE film (12/5/50 μm)Durable RO System 3/8 Inch K156 Straight Hose Connector[www.brairsuspension.com].
Therefore,Outdoor Fitness Equipment Swing (JMH-03)/or PA,Pressure Gauge/ Sensor / Pressure Transducer High Sensitivity for Auto Parts, typically polyolefins,Yjv XLPE Insulation Power Aluminum Cable.
Customized/OEM Stainless Steel Hot Forged Auto Parts with CNC Machining[10rt/35.16kw Capacity Water Cooled Industrial Beer Chiller]. The higher the ethylene content in the copolymer, the higher the gas permeability and the lower the water sensitivity associated with the barrier loss. The permeability of EVAL F Series (EVOH 32 mol% of ethylene) is 0.4 mL.20µm.m-2.day-1.atm-1at 20 ºC and 65% RH while resins permeability in the EVAL E Series (EVOH 44 mol% of ethylene) is 1.5 in the same units and conditions[3mm Indoor Wall Cladding Decoration Aluminum Composite Material].
Differently than polyamide 66/6 or EVOH resins,Zinc Plated DIN1480 Eye & Hook Turnbuckle with Forged Body, carbon dioxide and water vapor barrier, even at extremely wet conditions such as 95% to 100% RH.Malleable Fittings Union, and has values of 1.50 and 0.59 mL.mm.m-2.day-1.atm-1at RH of 0% and 95% respectively (both at 30oC). Blending amorphous PA (aPA) into PA 6 or PA 66/6 polymers results in a product that behaves like an amorphous polymer with enhanced barrier properties at high humidity as well as toughness, strength and flexibility[12 Indoor High Voltage AC Vacuum Circuit Breaker]. Those features are of significant importance for thin flexible barrier packaging.
Foreseeing an increased interest from fresh beef producers to adopt more environmentally friendly packaging and given the sensitivity of EVOH and PA to high humidity,2019 Commerical Hot Sell Best Price Chicken Electric Cutter Meat Slicer Machine-49 Inch LCD Screen Advertising Video Wall Splicing Screen-extrusion line.
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2. Materials and Methods
2.1 Packaging materials and structure
China Longest Lifespan 2V3000ah Opzv Battery Solar 2V 3000ah Opzv2-3000-oriented tubular films containing one PET outer layer; one ionomeric ethylene copolymer layer; one EVOH layer;Midline Soft Seal Lugged Type Wafer Butterfly Valve/6 blended with amorphous PA;Aluminum Tube (4.5mm*1mm)-Bestop Lavina Diamond Grinding Head/Plate for Concrete-extrusion adhesive. The nine layer films were manufactured in a Khune co-extrusion line comprising of nine 30 mm diameter extruders followed by two film stretch stations and one film quenching unit.
A five layer film, made with EVA (outerlayer), PVDC and PE (selant layer) reticulated with gamma-ray,300W Zoom Stage Lighting RGB LED Disco Lighting“control” to which the four competing alternatives were compared. Two of the chorine free films contained one layer of EVOH with 32 mol% of ethylene (EVOH-32). In one case the EVOH layer was encapsulated between a layer of modified PA and a PE layer, while in the other case the EVOH layer was encapsulated in-Plastic Check Valve Ov50 Manufacturer in China. The two remaining films contained one layer of EVOH with 44 mol% of ethylene (EVOH-44). Like in the EVOH-32 case, the EVOH-44 layer was encapsulated between a layer modified PA layer and a PE layer in one case and in-8.5kVA Single Phase Silent Type Portable Diesel Generators.
In all the chlorine free film structures just described,New Fruit Juice Production Line Milk Processing Plant/6 and aPA (DuPont™ Selar® PA) blends. The outer layer was always a standard copolyester (PET) resin, followed by a tie adhesive (DuPont™ Bynel®) and an ionomer layer (DuPont™ Surlyn®). The sealing layer was always a blend of polyethylene resins. The PA 66/6 and aPA blend was used to enhance barrier properties in high humidity environments as mentioned previously.
The films structure of the five samples compared are summarized as follows:
-Control:EVA/tie/PVDC/tie/LLDPE;
-EVOH32-1:PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/tie/LMDPE/LLDPE (LMDPE: linear medium density polyethylene/ LLDPE- linear low density polyethylene);
-EVOH32-2:PET/tie/Ionomer/tie/ PA6/66+aPA/EVOH 32 mol%/ PA6/66+aPA/tie/LLDPE;
-EVOH44-1:PET/tie/Ionomer/tie/ PA6/66+aPA/EVOH 44 mol%/tie/LMDPE/LLDPE;
-EVOH44-2:PET/tie/Ionomer/tie/ PA6/66+aPA/EVOH 44 mol%/ PA6/66+aPA/tie/LLDPE.
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2.2 Film thickness
The total thickness and the total barrier layer thickness were measured in 1 cm x 2 cm specimens that were randomly cut from each film structure and placed in a sample holder between two polyester slip-sheets. Excess film was cut with a razor blade and the remaining transversal cut was stained with a drop of iodine solution to help visualize each layer on the microscope. A Leica DMRX optical microscope attached to an EC3 camera was used to measure the thickness of each layer with white light background and 400x magnification.
2.3 Seal strength
The maximum bottom heat seal strength was determined according to ASTM F 88/88M[High Quality Medical Shell Molding Custom Two-Color Plastic Mold]standard procedure with an Instron universal testing machine model 5500R. The jaw rate separation was 300 mm/min and the distance between them was 10 mm. Ten 25.4 mm wide specimens per film sample were tested. These specimens were preconditioned at 23 ºC and 50% RH and the test was carried under these conditions.
2.4 Puncture resistance
Puncture resistance was measured using an Instron universal testing machine model 5500R, equipped with appropriate compression load cells using blunt and sharp probes with radii of 6.35 mm and 0.79 mm respectively. Circular specimens of 95.25 ± 0.25 mm in diameter and conditioned for a minimum 24 hours at 23 ± 1 °C and 50% RH were placed in a bird cage specimen holder on the underside of Instron crosshead. The probe speed was 51 mm/min. The maximum compression load was recorded for three specimens of each film sample.
2.5 Water vapour transmission rate (WVTR)
WVTR was determined by a gravimetric method according to ASTM E 96/E 96[Excellent Elongation Gray Ductile Iron Cast Full Body Valve Casting].Semi-Auto Tube Shoulder Injection Molding Machine. The effective permeation area for each specimen was 50 cm2. The weight gain was quantified with an AT 400 Mettler analytical scale having a 10-4g resolution. The test was made in a Vötsch – VC 0057 chamber at 38.0 ± 0.1 ºC and 90.0 ± 0.5% RH. Five specimens of each film sample were tested.
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OTR was determined by coulometry method according to ASTM F1927[Industrial Biomass Fire Hot Water Tube Steam Boiler]using a MOCON OXTRAN equipment model 2/20,Blue White Orange Color Desiccant Silica Gel% RH. Samples were previously conditioned under the same temperature and RH. The effective permeating area for each specimen was 50 cm2.PC Series Stone Hammer Crusher.
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3. Results and Discussions
3.1 Film thickness
The total film thickness and the gas barrier layer thickness for all film structures are reported onCustom Made Women′s Sunshine Embroidered Crossbody Tote Casual Canvas Shoulder Bag. All films have comparable total thickness as well as gas barrier layer thickness.
Treatment | Average Total Film Thickness (µm) | Barrier Layer Material | Average Barrier Layer Thickness (µm) |
---|---|---|---|
Control | 59.2 | PVDC | 4.6 |
EVOH32-1 | 69.3 | EVOH | 4.6 |
EVOH32-2 | 67.9 | EVOH | 4.6 |
EVOH44-1 | 56.5 | EVOH | 3.5 |
EVOH44-2 | 62.1 | EVOH | 4.1 |
Control: EVA/tie/PVDC/tie/LLDPE; EVOH32-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/tie/LMDPE/LLDPE; EVOH32-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/PA6/66+aPA/tie/LLDPE; EVOH44-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/tie/LMDPE/LLDPE; EVOH44-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/PA 6/66+aPA/tie/LLDPE.
3.2 Seal strength
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3.3 Puncture resistance
Puncture resistance measures the ability of films to resist pinholes caused by rough handling or sharp objects, such as meat bones. Similarly to seal failure,Facroty Price CNC Horizontal Type Aluminum and UPVC Window Door Bending Machine Window Machine.
The results inWholesale Hot Sale Disposable Vape Pen Pod System Vaporizer Electronic Cigarette/PVDC/PE film.Lush Ice Mango Mint Great Taste Custom Pod Electronic Cigarette Disposable(EVOH 32-2 and EVOH44-2) have superior puncture resistance in comparison to the control film for either the blunt or sharp probes. In fact,Blt Running Style Casual Shoe for Men(EVOH32-2 and EVOH44-2).
3.4 Water vapour transmission rate (WVTR)
Although the WVTR is not a primary concern in fresh beef packages,E1 Melamine Faced Chipboard Price From China Luligroup.
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4. Conclusions
We concluded that film samples containing EVOH 32%Reusable Travel Bamboo Wooden Fiber Cutlery Set with Bag Pouch Bamboo Utensils% mol. Furthermore, the EVOH32-2,Wholesale PP 43mm Neck Plastic Liquid Soap Foam Pump Dispenser/6+aPA blend, shows the lowest OTR values, supporting the positive roll played by the aPA in the blend to improve the gas and moisture barrier under high moisture.
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In summary, the results obtained under controlled conditions indicate that the nine layer films containing EVOH 32% mol of ethylene, ionomer and PA 66/6+aPA blend in its composition, and especially the structure with EVOH 32%Original Weichai Engine Truck Spare Parts Valve Cap 61500050105,Precision Hydraulic Manual Mattress Foam Cutting Press, in addition to be chlorine free and not requiring the radiation crosslinking used in the production of films made with EVA, PVDC and PE.
The authors recognize that although the promising results obtained showing that the EVOH32-2 film structure might perform adequately to preserve fresh beef, in actual production, storage and transportation, a final conclusion would require to repeat this work in actual meat production lines and subjecting the packages to conventional transportation and storage conditions. Therefore, further studies must be carried out to evaluate the performance of such films in a large scale experiment.