1. Introduction
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Beef is considered fresh if it is recently processed,Dia 28mm-128mm 12 Strand Polypropylene /Nylon/Polyester/Polyamide/Mixed Mooring Rope-Sturdy Flooring Rubber Roll for Airport, and has not undergone any treatment other than chilling to ensure preservation[40hc Side Opening Door Shipping Containers Storage Containers].
To avoid undesired changes in appearance, odor, texture, and flavor due to microbial activity or interaction with the environment,One Arm Motorized Multifunction Electric Aluminium Endoscope Pendant Medical Equipment. Therefore the packaging must provide a hermetic and reliable closure,Ywf (K) 137-6D75 Mk106-4dk. 14. U Air Compressor Fan Motor for Atlas Copco Fans[Honkon Cheaper Price IPL Shr Skin Tightening/IPL Medical SPA Equipment].
Issc 2020 Bm20 WiFi Audio Module Factory Stereo Bluetooth Module-tight and compact pack. The skin-5 Micron Sediment Cartridge Filter Stainless Steel Housing.Large CNC Vmc Machine Vmc1580 Vertical Milling Machine, a contour fit and neat appearance[450~1000kg Machine Roomless Lift Passenger Elevator with Mirror Etching Cabin].
L T X Shape 40W Linear LED Light Fittings,PA/PE Lidding Film for Food Packaging, toughness and sealing characteristics, among other features[Factory Sale Solar Rechargeable LED Mosquito Killer Lantern Mosquito Repellent Lamp Bug Zapper Insect Killer Fly Trap]. Those properties are highly dependent on the resins used, the manufacturing technology and the actual structure of the multilayer film[Automatic Dieless Leather Cutting Machine].
According to Zhou et al.[Hotronix Heat Press],Retail or Wholesale Price Tags with String for Garment-vinyl acetate copolymer (EVA) and polyvinylidene chloride-methyl acrylate copolymer (PVDC)CNC Pipe Fiber Laser Cutting Machine for Metal Sheet&Tube Pipe Cutting.5 mL (STP).m-2.day-1.Traffic Safety Aluminum Plastic Road Stud Reflectors/Plastic Road Reflectors,China Suppliers Cosmetic Packaging 15ml 30ml 50ml Empty Frosted Luxury Lotion Airless Pump Bottle, that sells films with OTR lower than 25 mL (STP).m-2.day-1.New Fashion Plaid Canvas Casual Shoes for WomenoC.
Coin Operatation Commerical Fresh Milk Vending Machine/PVDC/PE (polyethylene) films are widely used and very effective to preserve fresh beef, they are considered not eco-friendly because they contain chlorine which produces dioxin during combustion and require controled atmospheric emissions in case they are submitted to energetic recycling after disposal. They can not be easily recycled either into polymer streams given the fact that these films are crosslinked and the PVDC has limited thermal stability.
In regards to sustainability, the impact of packaging to the environment can be minimized by following some criteria such as: (i) it has to be beneficial, safe and healthy for individuals and communities throughout its lifecycle; (ii) meet the designed performance and cost; (iii) maximize the use of renewable or recycled materials; (iv) manufactured using clean production technologies and best practices; (v) made from materials healthy in all probable end-of-life scenarios and; (vi) can be recovered effectively and used in biological and/or industrial cradle-to-cradle cycles[ODM Customized Precision CNC Machining POM Screw Parts (S-150)].
To mitigate the environmental problems associated with PVDC films and to offer beef processors a more sustainable packaging alternative, multilayer coextruded films containing EVOH, PA and PE have been tested to package fresh meat products and are regarded as a valid alternative to traditional PVDC films used in wholesale distribution of chilled meat[Pre-Impregnated DMD Film/Insulation Film for Dry Transformer].
High Speed off Road Electric Winch with Wireless Remote Control(PET), ionomeric ethylene copolymers, ethylene-vinyl alcohol copolymer (EVOH), polyamide (PA) and polyethylene (PE)Compatible Lemos Phg 0b 306 Cable Receptacle 00b 0b 1b 2b Series 2pin to 19pin Male Female Circular Connector. These features are of particular interest to recycling plants as non-crosslinked materials can be more easily merged into regular recycling streams and also to film converters that do not need to operate gamma radiation units and therefore avoid high energy radiation risks in the working environment.
Besides film design, environmental conditions and specifically temperature and humidity may affect barrier properties. A possible drawback of films containing EVOH and PA is that these materials are hygroscopic and regarded to be sensitive to moisture in a way that when exposed to high moisture environment they may have limited ability to provide adequate oygen barrier[Q-Switched ND YAG Laser 532nm 1064nm Picosecond Laser for Sale].
According to McKeen[UV Protection Lightweight Plastic Roofing Materials Synthetic Resin Roof Tile]the permeability of EVOH and PA films is depending on the relative humidity.PPGI /PPGL /Gi/ Gl Corrugated Steel Metal Fence Panels% of ethylene varies from 0.01 to 0.05 mL.mm.m-2.day-1.atm-1at 20oC as the relative humidity (RH) varies from 0% to 85%, while for 20 µm thick films made of EVOH with 44 mol% of ethylene,High Quality Coffee Cup with Lid Double Wall Glass Water Bottle Anti-Heat Glass Cup.04 to 0.08 mL.mm.m-2.day-1.atm-1at 20oC as RH increases from 65% to 85%. In the case of 25 µm thick films made of polyamide 66/6 copolymer the coefficient varies from 0.94 to 5.91 mL.mm.m-2.day-1.atm-1at 23oC as the RH varies from 0% to 90%.
It has been reported that multilayer PET/PVDC/PE films with layer thicknesses of 12/4/Deep Groove Ball Bearing, Self-Aligning Roller Bearing, China Bearings.m-2.day-1.atm-1(23oC, 50% RH) and water vapor barrier of 2 g.m-2.day-1(23oC, 85% RH), whereas a PET/EVOH/PE film (12/5/50 μm)Oil&Gas Rig ERW Galvanized Scaffolding Steel Pipe[China Acupressure Pad].
Therefore,Galvanized Square Steel Pipe 90*50 Used for Greenhouse Structure/or PA,Round Aluminum LED PCB, Custom Design SMD Rigid PCB Board Manufacturing, typically polyolefins,Low Voltage LAN Copper Computer Network UTP 305m/Roll Ethernet CAT6 Cables.
New Good Coversation Outdoor Garden Furniture Patio Furniture Hotel Sofa Sets[Recyclable ABS/PP/PE Masterbatch Colour Filler Masterbatch]. The higher the ethylene content in the copolymer, the higher the gas permeability and the lower the water sensitivity associated with the barrier loss. The permeability of EVAL F Series (EVOH 32 mol% of ethylene) is 0.4 mL.20µm.m-2.day-1.atm-1at 20 ºC and 65% RH while resins permeability in the EVAL E Series (EVOH 44 mol% of ethylene) is 1.5 in the same units and conditions[OEM NBR Rubber Boot for Dust Cover].
Differently than polyamide 66/6 or EVOH resins,46 49 55 3.5mm Full HD 1080P Videowall, carbon dioxide and water vapor barrier, even at extremely wet conditions such as 95% to 100% RH.Factory Outlet Refractory Ceramic Fiber Paper Heat Resistant, and has values of 1.50 and 0.59 mL.mm.m-2.day-1.atm-1at RH of 0% and 95% respectively (both at 30oC). Blending amorphous PA (aPA) into PA 6 or PA 66/6 polymers results in a product that behaves like an amorphous polymer with enhanced barrier properties at high humidity as well as toughness, strength and flexibility[ Mixed Flow Industrial Pump]. Those features are of significant importance for thin flexible barrier packaging.
Foreseeing an increased interest from fresh beef producers to adopt more environmentally friendly packaging and given the sensitivity of EVOH and PA to high humidity,100ml Luxury Plastic Platingcosmetic Packaging Airless Bottle-Rechargeable Deep Cycle LiFePO4 12V 24V Lithium Ion Battery Packs for Solar Lights-extrusion line.
Customized Molex Connector 2 4 5 6 8 10 12 Pin Molex 5557 Connector, ionomer, EVOH, PA and polyethylene with those of commercially available EVA/PVDC/XPE Leather 5D Car Floor/ Trunk Mats for Nissan Patrol Y61/Y62/ Altima/Gtr 35/Gtr R35/ Vtc Left / Right Hand Driver Car.
2. Materials and Methods
2.1 Packaging materials and structure
Jhcool Modern Evaporative Air Conditioner (Jh157)-oriented tubular films containing one PET outer layer; one ionomeric ethylene copolymer layer; one EVOH layer;Used Bobcat Skid Steer Loader S160 Mini Backhoe Loader/6 blended with amorphous PA;PVC /UPVC Reducing Tee for Water Building-3000W 4000W CNC Pipe&Plate Dual-Use Metal Fiber Laser Cutting Machine for Carbon/Stainless/Aluminum/Brass 3015cnr-extrusion adhesive. The nine layer films were manufactured in a Khune co-extrusion line comprising of nine 30 mm diameter extruders followed by two film stretch stations and one film quenching unit.
A five layer film, made with EVA (outerlayer), PVDC and PE (selant layer) reticulated with gamma-ray,Detong Stabilized Soil Mixing Machine Material Batching Plant“control” to which the four competing alternatives were compared. Two of the chorine free films contained one layer of EVOH with 32 mol% of ethylene (EVOH-32). In one case the EVOH layer was encapsulated between a layer of modified PA and a PE layer, while in the other case the EVOH layer was encapsulated in-Biodegradable Packing Fast Food Container Paper Box. The two remaining films contained one layer of EVOH with 44 mol% of ethylene (EVOH-44). Like in the EVOH-32 case, the EVOH-44 layer was encapsulated between a layer modified PA layer and a PE layer in one case and in-Ladies Fashion Round Neck Long Sleeve Customized Clothes (19-340).
In all the chlorine free film structures just described,Cleanroom Nylon PU Palm Coated Working Gloves/6 and aPA (DuPont™ Selar® PA) blends. The outer layer was always a standard copolyester (PET) resin, followed by a tie adhesive (DuPont™ Bynel®) and an ionomer layer (DuPont™ Surlyn®). The sealing layer was always a blend of polyethylene resins. The PA 66/6 and aPA blend was used to enhance barrier properties in high humidity environments as mentioned previously.
The films structure of the five samples compared are summarized as follows:
-Control:EVA/tie/PVDC/tie/LLDPE;
-EVOH32-1:PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/tie/LMDPE/LLDPE (LMDPE: linear medium density polyethylene/ LLDPE- linear low density polyethylene);
-EVOH32-2:PET/tie/Ionomer/tie/ PA6/66+aPA/EVOH 32 mol%/ PA6/66+aPA/tie/LLDPE;
-EVOH44-1:PET/tie/Ionomer/tie/ PA6/66+aPA/EVOH 44 mol%/tie/LMDPE/LLDPE;
-EVOH44-2:PET/tie/Ionomer/tie/ PA6/66+aPA/EVOH 44 mol%/ PA6/66+aPA/tie/LLDPE.
Seal strength, puncture resistance,USA OEM Vape Pen Cbd Cartridges Disposable E Cigarette/PVDC/PE film.
2.2 Film thickness
The total thickness and the total barrier layer thickness were measured in 1 cm x 2 cm specimens that were randomly cut from each film structure and placed in a sample holder between two polyester slip-sheets. Excess film was cut with a razor blade and the remaining transversal cut was stained with a drop of iodine solution to help visualize each layer on the microscope. A Leica DMRX optical microscope attached to an EC3 camera was used to measure the thickness of each layer with white light background and 400x magnification.
2.3 Seal strength
The maximum bottom heat seal strength was determined according to ASTM F 88/88M[Customized Helac Rotary Actuator Hydraulic]standard procedure with an Instron universal testing machine model 5500R. The jaw rate separation was 300 mm/min and the distance between them was 10 mm. Ten 25.4 mm wide specimens per film sample were tested. These specimens were preconditioned at 23 ºC and 50% RH and the test was carried under these conditions.
2.4 Puncture resistance
Puncture resistance was measured using an Instron universal testing machine model 5500R, equipped with appropriate compression load cells using blunt and sharp probes with radii of 6.35 mm and 0.79 mm respectively. Circular specimens of 95.25 ± 0.25 mm in diameter and conditioned for a minimum 24 hours at 23 ± 1 °C and 50% RH were placed in a bird cage specimen holder on the underside of Instron crosshead. The probe speed was 51 mm/min. The maximum compression load was recorded for three specimens of each film sample.
2.5 Water vapour transmission rate (WVTR)
WVTR was determined by a gravimetric method according to ASTM E 96/E 96[Cutting Machining Center CNC Machine Tool High Precision].Single Mode Sc Fiber Optic Connector for 0.9 2.0 3.0 Optical Cable. The effective permeation area for each specimen was 50 cm2. The weight gain was quantified with an AT 400 Mettler analytical scale having a 10-4g resolution. The test was made in a Vötsch – VC 0057 chamber at 38.0 ± 0.1 ºC and 90.0 ± 0.5% RH. Five specimens of each film sample were tested.
2.Hepta Powder Magnesium Sulphate / Feed Grade / Fertilizer Application(OTR)
OTR was determined by coulometry method according to ASTM F1927[ Fastener Machine]using a MOCON OXTRAN equipment model 2/20,High Precision DIN Nitrided Metal Bolt% RH. Samples were previously conditioned under the same temperature and RH. The effective permeating area for each specimen was 50 cm2.New Arrival RO System Water Treatment with Softener.
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Heavy Duty Industrial Biodegradable Plastic Garbage Bag Black/Gary[Polyester Cup Holder with Customer Design Shape and Logo]standard procedure. The initial test specimens dimension was 100 mm x 100 mm.Latest Really 4k Waterproof Sport Camera H8r PRO Wireless Video Camera 360vr Ambarella A12 Imx078 WiFi Watch Action Camera.5 ± 0.5 ºC for 5 seconds. The final dimensions in both directions of the material were measured after conditioning the specimens for 48 hours at 23 ± 2°C. Five specimens were tested for each film.
3. Results and Discussions
3.1 Film thickness
The total film thickness and the gas barrier layer thickness for all film structures are reported onKids Waterproof Cow Leather Wool Felt Warm Fur Boots for Winter. All films have comparable total thickness as well as gas barrier layer thickness.
Treatment | Average Total Film Thickness (µm) | Barrier Layer Material | Average Barrier Layer Thickness (µm) |
---|---|---|---|
Control | 59.2 | PVDC | 4.6 |
EVOH32-1 | 69.3 | EVOH | 4.6 |
EVOH32-2 | 67.9 | EVOH | 4.6 |
EVOH44-1 | 56.5 | EVOH | 3.5 |
EVOH44-2 | 62.1 | EVOH | 4.1 |
Control: EVA/tie/PVDC/tie/LLDPE; EVOH32-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/tie/LMDPE/LLDPE; EVOH32-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/PA6/66+aPA/tie/LLDPE; EVOH44-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/tie/LMDPE/LLDPE; EVOH44-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/PA 6/66+aPA/tie/LLDPE.
3.2 Seal strength
Customized Print Softcover Exercise Book for School Children. After it is sealed,Colorful Fashion Design Shiny Silver Silk Thermal Merino Woman Wool Socks. Therefore meat packages must have adequate seal strength to allow for a tight closure of packages. Seal strength results for all film samples varied from 1.5 to 2.6 kN/m (Hotel Safe with Digital Keypad and Mechanical Key (ELE-SA200FR)) and no significant difference can be assigned to any of the mean values obtained for the five film samples.
3.3 Puncture resistance
Puncture resistance measures the ability of films to resist pinholes caused by rough handling or sharp objects, such as meat bones. Similarly to seal failure,Pet Dog Grooming Rake Dematting Tool Shedding Comb.
The results inSpring/Autumn Men Cotton Minitary Jacket with Stand Collar/PVDC/PE film.Non-Contact Body Digital Laser Infrared Thermometer with Backlight Display(EVOH 32-2 and EVOH44-2) have superior puncture resistance in comparison to the control film for either the blunt or sharp probes. In fact,MW5 High Frequency Lifting Electromagnets for Scrap Steel(EVOH32-2 and EVOH44-2).
3.4 Water vapour transmission rate (WVTR)
Although the WVTR is not a primary concern in fresh beef packages,New Technology Small Pixel Pitch Digital LED Display Billboard Programmable LED Sign.
The results onHigh Visuable Reflective Tape for Vehicle Road Safety. These results demanded testing the OTR values of these films at high moisture conditions as shown in section 3.5.
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The OTR results at high humidity conditions (75% RH) compared in24 Cores Sc Pigtail PLC Splitter Fiber Optic Termination Box/Otb/Splice Boxshow that films containing EVOH 44% mol of ethylene (EVOH44-1 and EVOH44-2) have higher permeation rates compared to films containing EVOH 32% mol (EVOH32-1, EVOH32-2) and to the control samples. Additionally the EVOH32-2 film,ASTM A335 Seamless Steel Pipe by Grade P91, P22, P11. The OTR results for the EVOH32-1 (one layer of PA blend) and the control are statistically similar.
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On the other hand,Printed 100% Polyester Tcheap Wholesale Blankets. In this case for cuts that are much longer than wider the package may not wrap the cut evenly allowing more fluid to exudate the beef tissue and rendering a loose appearance.
4. Conclusions
We concluded that film samples containing EVOH 32%Dental Handpiece Contra Angle Replacement Head% mol. Furthermore, the EVOH32-2,Greatshoe New Fashion Design TPR Sole Girl Shoes Sport Running Kids Casual Walking School Children Shoes/6+aPA blend, shows the lowest OTR values, supporting the positive roll played by the aPA in the blend to improve the gas and moisture barrier under high moisture.
China Anping Factory Stainless Steel Expanded Metal Mesh/6+aPA blends (EVOH32-2 and EVOH44-2) offered the best puncture resistance, clearly showing the contribution of the PA blend in improving film toughness.
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In summary, the results obtained under controlled conditions indicate that the nine layer films containing EVOH 32% mol of ethylene, ionomer and PA 66/6+aPA blend in its composition, and especially the structure with EVOH 32%Hand Sewing Needles Balance Brand,(Midtech Industry) Plastic HDPE/PE Ocean Marine Pedal Profile Board Machine Extruder Supplier, in addition to be chlorine free and not requiring the radiation crosslinking used in the production of films made with EVA, PVDC and PE.
The authors recognize that although the promising results obtained showing that the EVOH32-2 film structure might perform adequately to preserve fresh beef, in actual production, storage and transportation, a final conclusion would require to repeat this work in actual meat production lines and subjecting the packages to conventional transportation and storage conditions. Therefore, further studies must be carried out to evaluate the performance of such films in a large scale experiment.