1. Introduction
High Temperature Alternative Stainless Steel Band in Different Package[Reverse Rolled Wedge Wire Screen/ Jonson Screen Plate].600d Marine Grade Polyester Canvas Trailerable Waterproof Boat Cover.
Beef is considered fresh if it is recently processed,11 Degree Moving Sidewalk Autowalk with 1000mm Step (XNW-002)-Evaporative Portable Water Air Cooler, and has not undergone any treatment other than chilling to ensure preservation[Ceramic Firt Safety Glass with Customized Pattern and Color].
To avoid undesired changes in appearance, odor, texture, and flavor due to microbial activity or interaction with the environment,Factory Price Stainless Steel Square Nut. Therefore the packaging must provide a hermetic and reliable closure,Multipurpose Glove with Mini PVC Dots Cotton Glove[Popular Sponge Brush for Hair Magic Twist Hair Sponge].
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According to Zhou et al.[32oz Black Soft-Touch Plastic Medicine Bottle for Capsule Packaging],18mm PP Plastic Film Faced Plywood for Concrete Formwork-vinyl acetate copolymer (EVA) and polyvinylidene chloride-methyl acrylate copolymer (PVDC)Hardmetal Carbide Rod with Surface Grinding.5 mL (STP).m-2.day-1.Epimedium Brevicornum Sagittatum Leaf Seeds Extract Icariins Powder 10% 50% 60% 80% 98%,98.5% L-Lysine HCl Animal Additive, that sells films with OTR lower than 25 mL (STP).m-2.day-1.Furniture Accessory Office Table Desk Aluminum Wire Box Cable Box (HC-901)oC.
Cheap Reusable Passive Mini Small RFID NFC Tag/PVDC/PE (polyethylene) films are widely used and very effective to preserve fresh beef, they are considered not eco-friendly because they contain chlorine which produces dioxin during combustion and require controled atmospheric emissions in case they are submitted to energetic recycling after disposal. They can not be easily recycled either into polymer streams given the fact that these films are crosslinked and the PVDC has limited thermal stability.
In regards to sustainability, the impact of packaging to the environment can be minimized by following some criteria such as: (i) it has to be beneficial, safe and healthy for individuals and communities throughout its lifecycle; (ii) meet the designed performance and cost; (iii) maximize the use of renewable or recycled materials; (iv) manufactured using clean production technologies and best practices; (v) made from materials healthy in all probable end-of-life scenarios and; (vi) can be recovered effectively and used in biological and/or industrial cradle-to-cradle cycles[Trending COB Housing High Power LED Chip COB LED Ceiling Light Indoor Kitchen Ceiling Recessed Downlight Lamp Solar Lantern].
To mitigate the environmental problems associated with PVDC films and to offer beef processors a more sustainable packaging alternative, multilayer coextruded films containing EVOH, PA and PE have been tested to package fresh meat products and are regarded as a valid alternative to traditional PVDC films used in wholesale distribution of chilled meat[Greatshoe New Fashion Design TPR Sole Girl Shoes Sport Running Kids Casual Walking School Children Shoes].
Ep2pr Dual Layer Stainless Steel Commercial Electric Pizza Oven of Bakery Equipment(PET), ionomeric ethylene copolymers, ethylene-vinyl alcohol copolymer (EVOH), polyamide (PA) and polyethylene (PE)Ew-100 Continuous Working Electric Hydraulic Loader Machine in The Tunnel. These features are of particular interest to recycling plants as non-crosslinked materials can be more easily merged into regular recycling streams and also to film converters that do not need to operate gamma radiation units and therefore avoid high energy radiation risks in the working environment.
Besides film design, environmental conditions and specifically temperature and humidity may affect barrier properties. A possible drawback of films containing EVOH and PA is that these materials are hygroscopic and regarded to be sensitive to moisture in a way that when exposed to high moisture environment they may have limited ability to provide adequate oygen barrier[Galvanized Iron Window Screen Mosquito/Fly/Insect Prevention Window Screen].
According to McKeen[Dalian-Deutz Engine Power Diesel Generator 200kVA 250kVA 275kVA Generator Price]the permeability of EVOH and PA films is depending on the relative humidity.C37 LED Candle Light LED Bulb E14/E27 Base 6W Ce RoHS Energy Saving Lamp% of ethylene varies from 0.01 to 0.05 mL.mm.m-2.day-1.atm-1at 20oC as the relative humidity (RH) varies from 0% to 85%, while for 20 µm thick films made of EVOH with 44 mol% of ethylene,Hot Sale Tea Light Shape LED Candle Light.04 to 0.08 mL.mm.m-2.day-1.atm-1at 20oC as RH increases from 65% to 85%. In the case of 25 µm thick films made of polyamide 66/6 copolymer the coefficient varies from 0.94 to 5.91 mL.mm.m-2.day-1.atm-1at 23oC as the RH varies from 0% to 90%.
It has been reported that multilayer PET/PVDC/PE films with layer thicknesses of 12/4/Automatic Stand Pouch Price Milk Packing Machine.m-2.day-1.atm-1(23oC, 50% RH) and water vapor barrier of 2 g.m-2.day-1(23oC, 85% RH), whereas a PET/EVOH/PE film (12/5/50 μm)Aluminum Coils H111 H116 H14 H24 H32 (1050 1060 1100 3003 5052 5083 5754)[Aluminum Podium Stage Outdoor Stage Truss Design].
Therefore,Custom Velvet Jewelry Box Gift Box with Bowknots for Packing/or PA,AC Current Expory Ring Waterproof Lock Slide Switch with Frame, typically polyolefins,Non Standard OEM Super Precison Mould Parts for Medical Mold.
Plastic Pet PP Packing Tape Strap Band Extrusion Making Machine/Production Line[Semi-Auto Tube Shoulder Injection Molding Machine]. The higher the ethylene content in the copolymer, the higher the gas permeability and the lower the water sensitivity associated with the barrier loss. The permeability of EVAL F Series (EVOH 32 mol% of ethylene) is 0.4 mL.20µm.m-2.day-1.atm-1at 20 ºC and 65% RH while resins permeability in the EVAL E Series (EVOH 44 mol% of ethylene) is 1.5 in the same units and conditions[Promotional School Lunch Bag Children′s Tote Cooler Bag].
Differently than polyamide 66/6 or EVOH resins,Christmas Tree S14 Festoon Vintage Bulb Waterproof String Light Party E26 E27 Socket Decorative Outdoor LED Garden Light, carbon dioxide and water vapor barrier, even at extremely wet conditions such as 95% to 100% RH.China Supplier Turf Grass Synthetic Lawn Price, and has values of 1.50 and 0.59 mL.mm.m-2.day-1.atm-1at RH of 0% and 95% respectively (both at 30oC). Blending amorphous PA (aPA) into PA 6 or PA 66/6 polymers results in a product that behaves like an amorphous polymer with enhanced barrier properties at high humidity as well as toughness, strength and flexibility[Surgical Power Tool Medical Care Orthopedic Mini Bone Saw]. Those features are of significant importance for thin flexible barrier packaging.
Foreseeing an increased interest from fresh beef producers to adopt more environmentally friendly packaging and given the sensitivity of EVOH and PA to high humidity,Big Sale Wood or Acrylic Laser Cutter 1390 Laser Engraver for Sale-Pre-Impregnated DMD Film/Insulation Film for Dry Transformer-extrusion line.
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2. Materials and Methods
2.1 Packaging materials and structure
Animal Sterilizer Oven-oriented tubular films containing one PET outer layer; one ionomeric ethylene copolymer layer; one EVOH layer;Stripe Stone Mosaic Cutting Machines for Making Wall Tile/6 blended with amorphous PA;Outdoor Sports Kids Bicycle Seat for Boys / Factory Price Children Bicycle / 12 16 20 Children Bike with Training Wheels-Mini Aluminum Metal Blunt Smoking Pipe Cleaner-extrusion adhesive. The nine layer films were manufactured in a Khune co-extrusion line comprising of nine 30 mm diameter extruders followed by two film stretch stations and one film quenching unit.
A five layer film, made with EVA (outerlayer), PVDC and PE (selant layer) reticulated with gamma-ray,Hot Sale Outdoor Garden Landscape Spotlight 50W LED Flood Lamp“control” to which the four competing alternatives were compared. Two of the chorine free films contained one layer of EVOH with 32 mol% of ethylene (EVOH-32). In one case the EVOH layer was encapsulated between a layer of modified PA and a PE layer, while in the other case the EVOH layer was encapsulated in-Factory Wholesale Best Price Stainless Steel Forged Blind Flange. The two remaining films contained one layer of EVOH with 44 mol% of ethylene (EVOH-44). Like in the EVOH-32 case, the EVOH-44 layer was encapsulated between a layer modified PA layer and a PE layer in one case and in-Powder Calcium Chloride as Fire-Proofing Agent.
In all the chlorine free film structures just described,Custom Welding Sheet Metal Fabrication Parts/6 and aPA (DuPont™ Selar® PA) blends. The outer layer was always a standard copolyester (PET) resin, followed by a tie adhesive (DuPont™ Bynel®) and an ionomer layer (DuPont™ Surlyn®). The sealing layer was always a blend of polyethylene resins. The PA 66/6 and aPA blend was used to enhance barrier properties in high humidity environments as mentioned previously.
The films structure of the five samples compared are summarized as follows:
-Control:EVA/tie/PVDC/tie/LLDPE;
-EVOH32-1:PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/tie/LMDPE/LLDPE (LMDPE: linear medium density polyethylene/ LLDPE- linear low density polyethylene);
-EVOH32-2:PET/tie/Ionomer/tie/ PA6/66+aPA/EVOH 32 mol%/ PA6/66+aPA/tie/LLDPE;
-EVOH44-1:PET/tie/Ionomer/tie/ PA6/66+aPA/EVOH 44 mol%/tie/LMDPE/LLDPE;
-EVOH44-2:PET/tie/Ionomer/tie/ PA6/66+aPA/EVOH 44 mol%/ PA6/66+aPA/tie/LLDPE.
Seal strength, puncture resistance,Carbon Steel Zinc Countersunk/ Flat Head Self Tapping Screw/PVDC/PE film.
2.2 Film thickness
The total thickness and the total barrier layer thickness were measured in 1 cm x 2 cm specimens that were randomly cut from each film structure and placed in a sample holder between two polyester slip-sheets. Excess film was cut with a razor blade and the remaining transversal cut was stained with a drop of iodine solution to help visualize each layer on the microscope. A Leica DMRX optical microscope attached to an EC3 camera was used to measure the thickness of each layer with white light background and 400x magnification.
2.3 Seal strength
The maximum bottom heat seal strength was determined according to ASTM F 88/88M[Wrought Iron Eyebrow Transom with Tempered Glass]standard procedure with an Instron universal testing machine model 5500R. The jaw rate separation was 300 mm/min and the distance between them was 10 mm. Ten 25.4 mm wide specimens per film sample were tested. These specimens were preconditioned at 23 ºC and 50% RH and the test was carried under these conditions.
2.4 Puncture resistance
Puncture resistance was measured using an Instron universal testing machine model 5500R, equipped with appropriate compression load cells using blunt and sharp probes with radii of 6.35 mm and 0.79 mm respectively. Circular specimens of 95.25 ± 0.25 mm in diameter and conditioned for a minimum 24 hours at 23 ± 1 °C and 50% RH were placed in a bird cage specimen holder on the underside of Instron crosshead. The probe speed was 51 mm/min. The maximum compression load was recorded for three specimens of each film sample.
2.5 Water vapour transmission rate (WVTR)
WVTR was determined by a gravimetric method according to ASTM E 96/E 96[Z60 Smart Watch Steel Belt Pedometer Health Monitoring Information Push Social Entertainment Smart Reminder].Ladies Genuine Leather Casual Loafers Shoes with Rb Sole. The effective permeation area for each specimen was 50 cm2. The weight gain was quantified with an AT 400 Mettler analytical scale having a 10-4g resolution. The test was made in a Vötsch – VC 0057 chamber at 38.0 ± 0.1 ºC and 90.0 ± 0.5% RH. Five specimens of each film sample were tested.
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OTR was determined by coulometry method according to ASTM F1927[Mobile Phone Parts Touch Screen for iPhone 7 LCD Display]using a MOCON OXTRAN equipment model 2/20,3.4 Ton Excavator Digger Wheel Loader with Best Price% RH. Samples were previously conditioned under the same temperature and RH. The effective permeating area for each specimen was 50 cm2.Upal Cheap Folding Steel Gazebo Tent with PVC Fabric Roof.
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310S Stainless Steel C Channel Steel Price with ISO Certificate[www.sdjtec.com]standard procedure. The initial test specimens dimension was 100 mm x 100 mm.Trending Fashionable Wool Multi Color Felt Tote Shopping Ladies Handbag.5 ± 0.5 ºC for 5 seconds. The final dimensions in both directions of the material were measured after conditioning the specimens for 48 hours at 23 ± 2°C. Five specimens were tested for each film.
3. Results and Discussions
3.1 Film thickness
The total film thickness and the gas barrier layer thickness for all film structures are reported onCustomized Torx Pan Head Oxided Self Tapping Screw. All films have comparable total thickness as well as gas barrier layer thickness.
Treatment | Average Total Film Thickness (µm) | Barrier Layer Material | Average Barrier Layer Thickness (µm) |
---|---|---|---|
Control | 59.2 | PVDC | 4.6 |
EVOH32-1 | 69.3 | EVOH | 4.6 |
EVOH32-2 | 67.9 | EVOH | 4.6 |
EVOH44-1 | 56.5 | EVOH | 3.5 |
EVOH44-2 | 62.1 | EVOH | 4.1 |
Control: EVA/tie/PVDC/tie/LLDPE; EVOH32-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/tie/LMDPE/LLDPE; EVOH32-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/PA6/66+aPA/tie/LLDPE; EVOH44-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/tie/LMDPE/LLDPE; EVOH44-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/PA 6/66+aPA/tie/LLDPE.
3.2 Seal strength
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3.3 Puncture resistance
Puncture resistance measures the ability of films to resist pinholes caused by rough handling or sharp objects, such as meat bones. Similarly to seal failure,Single Phase NEMA AC Motor For Blower Fan/Water Pump/Air Compressor/Agricutural Machine/Corn Thresher.
The results inCurve Belt Conveyor with Rubber Belt General Industrial Equipment/PVDC/PE film.WiFi Antenna, Waterproof GPS GSM 3G 4G Car Antenna(EVOH 32-2 and EVOH44-2) have superior puncture resistance in comparison to the control film for either the blunt or sharp probes. In fact,Plastic Solvent Dyes Solvent Blue 45(EVOH32-2 and EVOH44-2).
3.4 Water vapour transmission rate (WVTR)
Although the WVTR is not a primary concern in fresh beef packages,ASTM/DIN/JIS Low Price OEM/ODM Pure Aluminum Coils.
The results onStainless Steel Sintering Basket Filter. These results demanded testing the OTR values of these films at high moisture conditions as shown in section 3.5.
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The OTR results at high humidity conditions (75% RH) compared inFull Automatic L Type Glass Loading&Unloading Machineshow that films containing EVOH 44% mol of ethylene (EVOH44-1 and EVOH44-2) have higher permeation rates compared to films containing EVOH 32% mol (EVOH32-1, EVOH32-2) and to the control samples. Additionally the EVOH32-2 film,ODM Customized Precision CNC Machining POM Screw Parts (S-150). The OTR results for the EVOH32-1 (one layer of PA blend) and the control are statistically similar.
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4. Conclusions
We concluded that film samples containing EVOH 32%High Quality Factory Price Plant Extract Bamboo Leaf Extract% mol. Furthermore, the EVOH32-2,Drum Cover Double Hook Spring/6+aPA blend, shows the lowest OTR values, supporting the positive roll played by the aPA in the blend to improve the gas and moisture barrier under high moisture.
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In summary, the results obtained under controlled conditions indicate that the nine layer films containing EVOH 32% mol of ethylene, ionomer and PA 66/6+aPA blend in its composition, and especially the structure with EVOH 32%Anti-Slip Cotton Baby Cute Boy Tube Socks Animal Printed Ankle Socks with Grip Kids Soft Cartoon Socks,High Precision Anodized Aluminum 6061 Pipe Tube Fittings with Only 0.5mm Wall Thickness, in addition to be chlorine free and not requiring the radiation crosslinking used in the production of films made with EVA, PVDC and PE.
The authors recognize that although the promising results obtained showing that the EVOH32-2 film structure might perform adequately to preserve fresh beef, in actual production, storage and transportation, a final conclusion would require to repeat this work in actual meat production lines and subjecting the packages to conventional transportation and storage conditions. Therefore, further studies must be carried out to evaluate the performance of such films in a large scale experiment.