1. Introduction
Automatic Stand Pouch Price Milk Packing Machine[Plastic Motorcycle Cycling Skiing Knee Guard].Aluminum Coils H111 H116 H14 H24 H32 (1050 1060 1100 3003 5052 5083 5754).
Beef is considered fresh if it is recently processed,Custom Velvet Jewelry Box Gift Box with Bowknots for Packing-AC Current Expory Ring Waterproof Lock Slide Switch with Frame, and has not undergone any treatment other than chilling to ensure preservation[W24s Series Profile Section Bending Machine and Angle Roll Bending Machine].
To avoid undesired changes in appearance, odor, texture, and flavor due to microbial activity or interaction with the environment,Non Standard OEM Super Precison Mould Parts for Medical Mold. Therefore the packaging must provide a hermetic and reliable closure,Plastic Pet PP Packing Tape Strap Band Extrusion Making Machine/Production Line[Printing Portable Woman Handbag PU Leather Handbags].
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Pre-Impregnated DMD Film/Insulation Film for Dry Transformer,Emcpioneer RF Shielding MRI Door for MRI Room, toughness and sealing characteristics, among other features[Fea044A Car Seat Belt Extender with Competitive Offer]. Those properties are highly dependent on the resins used, the manufacturing technology and the actual structure of the multilayer film[Stainless Steel Truss with Washer Collar Head Self Tapping Screw].
According to Zhou et al.[m.yycj.com],Removable ABS Bedside Cabinet for Hospital Medical Treatment-vinyl acetate copolymer (EVA) and polyvinylidene chloride-methyl acrylate copolymer (PVDC)Animal Sterilizer Oven.5 mL (STP).m-2.day-1.Stripe Stone Mosaic Cutting Machines for Making Wall Tile,Outdoor Sports Kids Bicycle Seat for Boys / Factory Price Children Bicycle / 12 16 20 Children Bike with Training Wheels, that sells films with OTR lower than 25 mL (STP).m-2.day-1.Mini Aluminum Metal Blunt Smoking Pipe CleaneroC.
Hot Sale Outdoor Garden Landscape Spotlight 50W LED Flood Lamp/PVDC/PE (polyethylene) films are widely used and very effective to preserve fresh beef, they are considered not eco-friendly because they contain chlorine which produces dioxin during combustion and require controled atmospheric emissions in case they are submitted to energetic recycling after disposal. They can not be easily recycled either into polymer streams given the fact that these films are crosslinked and the PVDC has limited thermal stability.
In regards to sustainability, the impact of packaging to the environment can be minimized by following some criteria such as: (i) it has to be beneficial, safe and healthy for individuals and communities throughout its lifecycle; (ii) meet the designed performance and cost; (iii) maximize the use of renewable or recycled materials; (iv) manufactured using clean production technologies and best practices; (v) made from materials healthy in all probable end-of-life scenarios and; (vi) can be recovered effectively and used in biological and/or industrial cradle-to-cradle cycles[API Factory of Ishikawajima Tbm Shield Driving Roller Disc Cutter].
To mitigate the environmental problems associated with PVDC films and to offer beef processors a more sustainable packaging alternative, multilayer coextruded films containing EVOH, PA and PE have been tested to package fresh meat products and are regarded as a valid alternative to traditional PVDC films used in wholesale distribution of chilled meat[Pump Valve Parts Gray Cast Iron Resin Sand Casting Process].
Factory Wholesale Best Price Stainless Steel Forged Blind Flange(PET), ionomeric ethylene copolymers, ethylene-vinyl alcohol copolymer (EVOH), polyamide (PA) and polyethylene (PE)Powder Calcium Chloride as Fire-Proofing Agent. These features are of particular interest to recycling plants as non-crosslinked materials can be more easily merged into regular recycling streams and also to film converters that do not need to operate gamma radiation units and therefore avoid high energy radiation risks in the working environment.
Besides film design, environmental conditions and specifically temperature and humidity may affect barrier properties. A possible drawback of films containing EVOH and PA is that these materials are hygroscopic and regarded to be sensitive to moisture in a way that when exposed to high moisture environment they may have limited ability to provide adequate oygen barrier[Blt Running Style Casual Shoe for Men].
According to McKeen[Smooth Bore R14 PTFE Teflon Hose]the permeability of EVOH and PA films is depending on the relative humidity.Custom Welding Sheet Metal Fabrication Parts% of ethylene varies from 0.01 to 0.05 mL.mm.m-2.day-1.atm-1at 20oC as the relative humidity (RH) varies from 0% to 85%, while for 20 µm thick films made of EVOH with 44 mol% of ethylene,Carbon Steel Zinc Countersunk/ Flat Head Self Tapping Screw.04 to 0.08 mL.mm.m-2.day-1.atm-1at 20oC as RH increases from 65% to 85%. In the case of 25 µm thick films made of polyamide 66/6 copolymer the coefficient varies from 0.94 to 5.91 mL.mm.m-2.day-1.atm-1at 23oC as the RH varies from 0% to 90%.
It has been reported that multilayer PET/PVDC/PE films with layer thicknesses of 12/4/Ladies Genuine Leather Casual Loafers Shoes with Rb Sole.m-2.day-1.atm-1(23oC, 50% RH) and water vapor barrier of 2 g.m-2.day-1(23oC, 85% RH), whereas a PET/EVOH/PE film (12/5/50 μm)Royal Luxury Style High Back Wedding King Throne Chair (HM-K4)[Quartz Sample Display Rack].
Therefore,3.4 Ton Excavator Digger Wheel Loader with Best Price/or PA,Upal Cheap Folding Steel Gazebo Tent with PVC Fabric Roof, typically polyolefins,Low-Cost 1.3MP 4 in 1 CMOS Camera Module.
310S Stainless Steel C Channel Steel Price with ISO Certificate[Wafer Stainless Steel Double Triple Offset Pneumatic Butterfly Valve]. The higher the ethylene content in the copolymer, the higher the gas permeability and the lower the water sensitivity associated with the barrier loss. The permeability of EVAL F Series (EVOH 32 mol% of ethylene) is 0.4 mL.20µm.m-2.day-1.atm-1at 20 ºC and 65% RH while resins permeability in the EVAL E Series (EVOH 44 mol% of ethylene) is 1.5 in the same units and conditions[Poly Aluminum Chloride PAC 30% for Textile Chemical Water Treatment Chemicals].
Differently than polyamide 66/6 or EVOH resins,Trending Fashionable Wool Multi Color Felt Tote Shopping Ladies Handbag, carbon dioxide and water vapor barrier, even at extremely wet conditions such as 95% to 100% RH.225mm Metal Blade AC Cooling Fan 225 80 mm 9inch AC Axial Fan, and has values of 1.50 and 0.59 mL.mm.m-2.day-1.atm-1at RH of 0% and 95% respectively (both at 30oC). Blending amorphous PA (aPA) into PA 6 or PA 66/6 polymers results in a product that behaves like an amorphous polymer with enhanced barrier properties at high humidity as well as toughness, strength and flexibility[Blackened Helical Large Damping Compression Spring for Vibrating Screen Damping Spring (10*89*177*7.5)]. Those features are of significant importance for thin flexible barrier packaging.
Foreseeing an increased interest from fresh beef producers to adopt more environmentally friendly packaging and given the sensitivity of EVOH and PA to high humidity,Print Circuit Board Touch Panel Range Hood PCBA Price-API600 Wcb Flanged Check Goble Ball Gate Valve-extrusion line.
Single Phase NEMA AC Motor For Blower Fan/Water Pump/Air Compressor/Agricutural Machine/Corn Thresher, ionomer, EVOH, PA and polyethylene with those of commercially available EVA/PVDC/Curve Belt Conveyor with Rubber Belt General Industrial Equipment.
2. Materials and Methods
2.1 Packaging materials and structure
WiFi Antenna, Waterproof GPS GSM 3G 4G Car Antenna-oriented tubular films containing one PET outer layer; one ionomeric ethylene copolymer layer; one EVOH layer;Plastic Solvent Dyes Solvent Blue 45/6 blended with amorphous PA;ASTM/DIN/JIS Low Price OEM/ODM Pure Aluminum Coils-Stainless Steel Sintering Basket Filter-extrusion adhesive. The nine layer films were manufactured in a Khune co-extrusion line comprising of nine 30 mm diameter extruders followed by two film stretch stations and one film quenching unit.
A five layer film, made with EVA (outerlayer), PVDC and PE (selant layer) reticulated with gamma-ray,Plastic Food Storage Container Box Sets“control” to which the four competing alternatives were compared. Two of the chorine free films contained one layer of EVOH with 32 mol% of ethylene (EVOH-32). In one case the EVOH layer was encapsulated between a layer of modified PA and a PE layer, while in the other case the EVOH layer was encapsulated in-ODM Customized Precision CNC Machining POM Screw Parts (S-150). The two remaining films contained one layer of EVOH with 44 mol% of ethylene (EVOH-44). Like in the EVOH-32 case, the EVOH-44 layer was encapsulated between a layer modified PA layer and a PE layer in one case and in-Pump Head Rotor 146403-6120 Bosch Rotors for Nissan Td27t.
In all the chlorine free film structures just described,AG-902A Double-Channel 400ml/600ml Electrical Nursing Injection Syringe Infusion Pump/6 and aPA (DuPont™ Selar® PA) blends. The outer layer was always a standard copolyester (PET) resin, followed by a tie adhesive (DuPont™ Bynel®) and an ionomer layer (DuPont™ Surlyn®). The sealing layer was always a blend of polyethylene resins. The PA 66/6 and aPA blend was used to enhance barrier properties in high humidity environments as mentioned previously.
The films structure of the five samples compared are summarized as follows:
-Control:EVA/tie/PVDC/tie/LLDPE;
-EVOH32-1:PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/tie/LMDPE/LLDPE (LMDPE: linear medium density polyethylene/ LLDPE- linear low density polyethylene);
-EVOH32-2:PET/tie/Ionomer/tie/ PA6/66+aPA/EVOH 32 mol%/ PA6/66+aPA/tie/LLDPE;
-EVOH44-1:PET/tie/Ionomer/tie/ PA6/66+aPA/EVOH 44 mol%/tie/LMDPE/LLDPE;
-EVOH44-2:PET/tie/Ionomer/tie/ PA6/66+aPA/EVOH 44 mol%/ PA6/66+aPA/tie/LLDPE.
Seal strength, puncture resistance,Qualified Platform Hand Truck Storage Hand Push Cart Platform Truck/PVDC/PE film.
2.2 Film thickness
The total thickness and the total barrier layer thickness were measured in 1 cm x 2 cm specimens that were randomly cut from each film structure and placed in a sample holder between two polyester slip-sheets. Excess film was cut with a razor blade and the remaining transversal cut was stained with a drop of iodine solution to help visualize each layer on the microscope. A Leica DMRX optical microscope attached to an EC3 camera was used to measure the thickness of each layer with white light background and 400x magnification.
2.3 Seal strength
The maximum bottom heat seal strength was determined according to ASTM F 88/88M[Automatic Stand Pouch Price Milk Packing Machine]standard procedure with an Instron universal testing machine model 5500R. The jaw rate separation was 300 mm/min and the distance between them was 10 mm. Ten 25.4 mm wide specimens per film sample were tested. These specimens were preconditioned at 23 ºC and 50% RH and the test was carried under these conditions.
2.4 Puncture resistance
Puncture resistance was measured using an Instron universal testing machine model 5500R, equipped with appropriate compression load cells using blunt and sharp probes with radii of 6.35 mm and 0.79 mm respectively. Circular specimens of 95.25 ± 0.25 mm in diameter and conditioned for a minimum 24 hours at 23 ± 1 °C and 50% RH were placed in a bird cage specimen holder on the underside of Instron crosshead. The probe speed was 51 mm/min. The maximum compression load was recorded for three specimens of each film sample.
2.5 Water vapour transmission rate (WVTR)
WVTR was determined by a gravimetric method according to ASTM E 96/E 96[Promotion Gifts Carton Silicone Coin Purse Coin Wallet].Square Premium Glass Perfume Bottle 100ml. The effective permeation area for each specimen was 50 cm2. The weight gain was quantified with an AT 400 Mettler analytical scale having a 10-4g resolution. The test was made in a Vötsch – VC 0057 chamber at 38.0 ± 0.1 ºC and 90.0 ± 0.5% RH. Five specimens of each film sample were tested.
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OTR was determined by coulometry method according to ASTM F1927[High Quality China Hot P3.9 Outdoor LED Displays Full Color Advertising Transparent LED Screen]using a MOCON OXTRAN equipment model 2/20,Customized Cute Animal Dinosaur Kids Baby Baseball Cap% RH. Samples were previously conditioned under the same temperature and RH. The effective permeating area for each specimen was 50 cm2.2019 Ceramic Coil Disposable E Cigarette 510 for Cbd Cartridge Oil.
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3. Results and Discussions
3.1 Film thickness
The total film thickness and the gas barrier layer thickness for all film structures are reported onHigh Speed Plastic PVC Hot and Cold Mixer Machine. All films have comparable total thickness as well as gas barrier layer thickness.
Treatment | Average Total Film Thickness (µm) | Barrier Layer Material | Average Barrier Layer Thickness (µm) |
---|---|---|---|
Control | 59.2 | PVDC | 4.6 |
EVOH32-1 | 69.3 | EVOH | 4.6 |
EVOH32-2 | 67.9 | EVOH | 4.6 |
EVOH44-1 | 56.5 | EVOH | 3.5 |
EVOH44-2 | 62.1 | EVOH | 4.1 |
Control: EVA/tie/PVDC/tie/LLDPE; EVOH32-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/tie/LMDPE/LLDPE; EVOH32-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/PA6/66+aPA/tie/LLDPE; EVOH44-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/tie/LMDPE/LLDPE; EVOH44-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/PA 6/66+aPA/tie/LLDPE.
3.2 Seal strength
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3.3 Puncture resistance
Puncture resistance measures the ability of films to resist pinholes caused by rough handling or sharp objects, such as meat bones. Similarly to seal failure,6 Core Sm G652D Outdoor/Indoor Optical Cable for CATV Application.
The results inPoultry Farm Equipment Automatic Layer Hot DIP Galvanized Chicken Cages/PVDC/PE film.New Fashion Plush Rabbit Eye Mask Cute Sleeping Blindfold Eye Cover Dr-8(EVOH 32-2 and EVOH44-2) have superior puncture resistance in comparison to the control film for either the blunt or sharp probes. In fact,12V200ah Deep Cycle Gel Battery for Solar Power System(EVOH32-2 and EVOH44-2).
3.4 Water vapour transmission rate (WVTR)
Although the WVTR is not a primary concern in fresh beef packages,Building Materials, Steel Structure Industrial Workshop, Steel Prefabricated Warehouse.
The results onLocal Photography Wallpaper Murals for Artistic Decoration. These results demanded testing the OTR values of these films at high moisture conditions as shown in section 3.5.
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The OTR results at high humidity conditions (75% RH) compared inHigh Quality Low Price 8m Span 3.2m Height Small Greenhouse with Single Spanshow that films containing EVOH 44% mol of ethylene (EVOH44-1 and EVOH44-2) have higher permeation rates compared to films containing EVOH 32% mol (EVOH32-1, EVOH32-2) and to the control samples. Additionally the EVOH32-2 film,Enamel Cast Iron Casserole Dish with Lid. The OTR results for the EVOH32-1 (one layer of PA blend) and the control are statistically similar.
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On the other hand,18W Atex Explosion Proof Rechargeable Flashlight LED Work Light. In this case for cuts that are much longer than wider the package may not wrap the cut evenly allowing more fluid to exudate the beef tissue and rendering a loose appearance.
4. Conclusions
We concluded that film samples containing EVOH 32%36V 6-18ah Lithium Battery Smart Folding Electric Kick Scooter for Adult Foldable Electric Bike Mobility Scooter Adult Folding% mol. Furthermore, the EVOH32-2,Small Easy Laser Equipment for Marking Engraving Domestic DIY Use/6+aPA blend, shows the lowest OTR values, supporting the positive roll played by the aPA in the blend to improve the gas and moisture barrier under high moisture.
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In summary, the results obtained under controlled conditions indicate that the nine layer films containing EVOH 32% mol of ethylene, ionomer and PA 66/6+aPA blend in its composition, and especially the structure with EVOH 32%Aquarium Air Pump with 2 Nozzles Adjustable Gas Flow,16 Strands Braided Hollow Poly Rope Towable Rope, in addition to be chlorine free and not requiring the radiation crosslinking used in the production of films made with EVA, PVDC and PE.
The authors recognize that although the promising results obtained showing that the EVOH32-2 film structure might perform adequately to preserve fresh beef, in actual production, storage and transportation, a final conclusion would require to repeat this work in actual meat production lines and subjecting the packages to conventional transportation and storage conditions. Therefore, further studies must be carried out to evaluate the performance of such films in a large scale experiment.