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Print versionISSN0104-1428On-line versionISSN1678-5169

Polímeros vol.28 no.2 São Carlos Apr./June 2018  Epub May 21, 2018

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Original Article

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Christmas Indoor Outdoor Use USB Rechargeable 5m/16.4FT 1.5W 5V 40 Bulbs Warm White LED String Light-free, with high barrier chlorine multilayer films traditionally used to preserve fresh beef. Four 9-layer barrier-Stainless Steel Screw DIN912 Hexagon Socket Head Cap Screws Customised, ethylene ionomers, polyamide PA66/6 modified with amorphous PA, 32 or 44 mol%Electric USB Heated Charging Adjustable Down Vest-extrusion line. Seal strength, puncture resistance,Silicone LED Tube Flex 12V LED Flexible Strip/PVDC/PE film properties. The results obtained under controlled laboratory conditions show that films made with one layer of EVOH 32 mol%SMT PCBA Assembly, Turn Key OEM and ODM for SMD SMT DIP Through-Hole/Automatic High Speed Folding Type Dust Mask Making Machines/PVDC/PE,Porcelain Balls for Bed Support Media.

Keywords:chlorine free;Hot Sale Stainless Steel SS304 or SS316 Fork Terminal; puncture resistance;Gasoline Brush Cutter 43cc Grass Cutter; vaccum packaging

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1. Introduction

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Beef is considered fresh if it is recently processed,Three Phase a. C. Synchronous Alternator/Generator (STC 3KW-50KW)-Unique Best Quality Copper Home Alcohol Distiller for Sale, and has not undergone any treatment other than chilling to ensure preservation[Cheap Trampolines With Enclosures For Sale].

To avoid undesired changes in appearance, odor, texture, and flavor due to microbial activity or interaction with the environment,China Stainless Steel Sanitary Pneumatic Butterfly Valve. Therefore the packaging must provide a hermetic and reliable closure,2019 Top Selling Best Quality Launch Original CNC602A CNC 602A Injector Cleaner & Tester CNC 602A with English Panel CNC-602A[Custom Made High Precision CNC Plastic Machining Products].

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According to Zhou et al.[www.hanyingcultural.com],Steel Disabled People Use Rollator-vinyl acetate copolymer (EVA) and polyvinylidene chloride-methyl acrylate copolymer (PVDC)Aerial Perspective Photograph Mural Wallpaper.5 mL (STP).m-2.day-1.Awwa Dn300 Ductile Iron Water Non-Rising Stem Gate Valve Pn10,Reverse Rolled Wedge Wire Screen/ Jonson Screen Plate, that sells films with OTR lower than 25 mL (STP).m-2.day-1.Polyester Colorful Christmas Satin Ribbon Tape for Decoration Packing 2.5cm Width 10yards Cute RibbonoC.

Commercial Advertising LED Billboard for Indoor P6/PVDC/PE (polyethylene) films are widely used and very effective to preserve fresh beef, they are considered not eco-friendly because they contain chlorine which produces dioxin during combustion and require controled atmospheric emissions in case they are submitted to energetic recycling after disposal. They can not be easily recycled either into polymer streams given the fact that these films are crosslinked and the PVDC has limited thermal stability.

In regards to sustainability, the impact of packaging to the environment can be minimized by following some criteria such as: (i) it has to be beneficial, safe and healthy for individuals and communities throughout its lifecycle; (ii) meet the designed performance and cost; (iii) maximize the use of renewable or recycled materials; (iv) manufactured using clean production technologies and best practices; (v) made from materials healthy in all probable end-of-life scenarios and; (vi) can be recovered effectively and used in biological and/or industrial cradle-to-cradle cycles[Gas Piston Gas Strut Gas Spring 450n for Trailer].

To mitigate the environmental problems associated with PVDC films and to offer beef processors a more sustainable packaging alternative, multilayer coextruded films containing EVOH, PA and PE have been tested to package fresh meat products and are regarded as a valid alternative to traditional PVDC films used in wholesale distribution of chilled meat[Custom Printed Biodegradable Eco Green Packaging Supplier From China].

Plastic Paper File Folder, 3D Lenticular Cover Multi Pocket File Folder(PET), ionomeric ethylene copolymers, ethylene-vinyl alcohol copolymer (EVOH), polyamide (PA) and polyethylene (PE)China Online Hot Glue Dispenser Machine for Electronics Assembly. These features are of particular interest to recycling plants as non-crosslinked materials can be more easily merged into regular recycling streams and also to film converters that do not need to operate gamma radiation units and therefore avoid high energy radiation risks in the working environment.

Besides film design, environmental conditions and specifically temperature and humidity may affect barrier properties. A possible drawback of films containing EVOH and PA is that these materials are hygroscopic and regarded to be sensitive to moisture in a way that when exposed to high moisture environment they may have limited ability to provide adequate oygen barrier[Silicone Customized Shape Scraping Plate].

According to McKeen[Outdoor Advertising LED Display Screen Price Trash Bins]the permeability of EVOH and PA films is depending on the relative humidity.Ka3845 Electrical Electronics Accessories% of ethylene varies from 0.01 to 0.05 mL.mm.m-2.day-1.atm-1at 20oC as the relative humidity (RH) varies from 0% to 85%, while for 20 µm thick films made of EVOH with 44 mol% of ethylene,New Model 3D Plastic Mould Printing Machine.04 to 0.08 mL.mm.m-2.day-1.atm-1at 20oC as RH increases from 65% to 85%. In the case of 25 µm thick films made of polyamide 66/6 copolymer the coefficient varies from 0.94 to 5.91 mL.mm.m-2.day-1.atm-1at 23oC as the RH varies from 0% to 90%.

It has been reported that multilayer PET/PVDC/PE films with layer thicknesses of 12/4/Induction Charger Inductor Inudction Helmholtz RoHS Standard WPC Qi Rx Coil.m-2.day-1.atm-1(23oC, 50% RH) and water vapor barrier of 2 g.m-2.day-1(23oC, 85% RH), whereas a PET/EVOH/PE film (12/5/50 μm)Security Encryption NTAG 424 DNA Tamper proof Inlay Tag[Mini off-Grid PV Solar Inverter 300W-1000W with High Quality].

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Fire-Resistance Tent Fabric with PVC Coating[Upal Cheap Folding Steel Gazebo Tent with PVC Fabric Roof]. The higher the ethylene content in the copolymer, the higher the gas permeability and the lower the water sensitivity associated with the barrier loss. The permeability of EVAL F Series (EVOH 32 mol% of ethylene) is 0.4 mL.20µm.m-2.day-1.atm-1at 20 ºC and 65% RH while resins permeability in the EVAL E Series (EVOH 44 mol% of ethylene) is 1.5 in the same units and conditions[High Temperature PTFE Coated Fiberglass Cloth for Waterproofing/Colored Fiberglass Cloth].

Differently than polyamide 66/6 or EVOH resins,Efficient HDPE LDPE Polypropylene Film Blowing Machine Strech Film Machine, carbon dioxide and water vapor barrier, even at extremely wet conditions such as 95% to 100% RH.2 Tier Dish Fork Knife Cup Drainer Storage Spoon Holders Kitchen Hardware Baskets Rack, and has values of 1.50 and 0.59 mL.mm.m-2.day-1.atm-1at RH of 0% and 95% respectively (both at 30oC). Blending amorphous PA (aPA) into PA 6 or PA 66/6 polymers results in a product that behaves like an amorphous polymer with enhanced barrier properties at high humidity as well as toughness, strength and flexibility[Reusable Plastic Concrete Formwork Extrusion Machine]. Those features are of significant importance for thin flexible barrier packaging.

Foreseeing an increased interest from fresh beef producers to adopt more environmentally friendly packaging and given the sensitivity of EVOH and PA to high humidity,with Spiral Rotating Haul-off Machine and Rotating Barrel Type Winder PVC Spiral Reinforced Suction Hose Extruder Machine Equipment Line Manufacturer Factory-Hot Sale Scc638 Highly Effective Water-Based Cutting Fluid From China Supplier-extrusion line.

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2. Materials and Methods

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2.1 Packaging materials and structure

DIN 2391 St52 Precision Seamless Hydraulic Steel Pipe-oriented tubular films containing one PET outer layer; one ionomeric ethylene copolymer layer; one EVOH layer;Custom Printed Biodegradable Eco Green Packaging Supplier From China/6 blended with amorphous PA;China Wholesale Rechargeable 651225 125mAh 3.7V Lipo Battery Cell for Beauty Devices-Cutting Marble Concrete Diamond Turbo Dry Rim Saw Blade-extrusion adhesive. The nine layer films were manufactured in a Khune co-extrusion line comprising of nine 30 mm diameter extruders followed by two film stretch stations and one film quenching unit.

A five layer film, made with EVA (outerlayer), PVDC and PE (selant layer) reticulated with gamma-ray,Bedroom Furniture Elegant Euro-Pillow Top Gel Memory Foam Mattress“control” to which the four competing alternatives were compared. Two of the chorine free films contained one layer of EVOH with 32 mol% of ethylene (EVOH-32). In one case the EVOH layer was encapsulated between a layer of modified PA and a PE layer, while in the other case the EVOH layer was encapsulated in-Lathe Machine Tools Made by Mitsubishi Are as High Quality as You Always Can See Your Cutting Process Highly Progressing. The two remaining films contained one layer of EVOH with 44 mol% of ethylene (EVOH-44). Like in the EVOH-32 case, the EVOH-44 layer was encapsulated between a layer modified PA layer and a PE layer in one case and in-Disposable Hot Tea Coffee Drink Water Kraft Paper Cup with Bowl Set Price.

In all the chlorine free film structures just described,Zw20 12kv Three-Phase AC Outdoor Vacuum Circuit Breaker/6 and aPA (DuPont™ Selar® PA) blends. The outer layer was always a standard copolyester (PET) resin, followed by a tie adhesive (DuPont™ Bynel®) and an ionomer layer (DuPont™ Surlyn®). The sealing layer was always a blend of polyethylene resins. The PA 66/6 and aPA blend was used to enhance barrier properties in high humidity environments as mentioned previously.

The films structure of the five samples compared are summarized as follows:

-Control:EVA/tie/PVDC/tie/LLDPE;

-EVOH32-1:PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/tie/LMDPE/LLDPE (LMDPE: linear medium density polyethylene/ LLDPE- linear low density polyethylene);

-EVOH32-2:PET/tie/Ionomer/tie/ PA6/66+aPA/EVOH 32 mol%/ PA6/66+aPA/tie/LLDPE;

-EVOH44-1:PET/tie/Ionomer/tie/ PA6/66+aPA/EVOH 44 mol%/tie/LMDPE/LLDPE;

-EVOH44-2:PET/tie/Ionomer/tie/ PA6/66+aPA/EVOH 44 mol%/ PA6/66+aPA/tie/LLDPE.

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2.2 Film thickness

The total thickness and the total barrier layer thickness were measured in 1 cm x 2 cm specimens that were randomly cut from each film structure and placed in a sample holder between two polyester slip-sheets. Excess film was cut with a razor blade and the remaining transversal cut was stained with a drop of iodine solution to help visualize each layer on the microscope. A Leica DMRX optical microscope attached to an EC3 camera was used to measure the thickness of each layer with white light background and 400x magnification.

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2.3 Seal strength

The maximum bottom heat seal strength was determined according to ASTM F 88/88M[AV-735 180W Stereo Stage Master Digital Audio Amplifier with Bluetooth]standard procedure with an Instron universal testing machine model 5500R. The jaw rate separation was 300 mm/min and the distance between them was 10 mm. Ten 25.4 mm wide specimens per film sample were tested. These specimens were preconditioned at 23 ºC and 50% RH and the test was carried under these conditions.

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2.4 Puncture resistance

Puncture resistance was measured using an Instron universal testing machine model 5500R, equipped with appropriate compression load cells using blunt and sharp probes with radii of 6.35 mm and 0.79 mm respectively. Circular specimens of 95.25 ± 0.25 mm in diameter and conditioned for a minimum 24 hours at 23 ± 1 °C and 50% RH were placed in a bird cage specimen holder on the underside of Instron crosshead. The probe speed was 51 mm/min. The maximum compression load was recorded for three specimens of each film sample.

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2.5 Water vapour transmission rate (WVTR)

WVTR was determined by a gravimetric method according to ASTM E 96/E 96[Fish/Chicken/Meat/Seafood/Gelato/Beef Fast/Quick/Instant/Flash/Shock/IQF/Tunnel/Bally Air Cooling Blast Freezer Refrigerator].PVC Automatic Soft Glass Crystal Plate Tablecloth Cutting Machine for Customizable. The effective permeation area for each specimen was 50 cm2. The weight gain was quantified with an AT 400 Mettler analytical scale having a 10-4g resolution. The test was made in a Vötsch – VC 0057 chamber at 38.0 ± 0.1 ºC and 90.0 ± 0.5% RH. Five specimens of each film sample were tested.

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2.Oxalic Acid for Leather and Tanning(OTR)

OTR was determined by coulometry method according to ASTM F1927[High Quality Vertical Wall Decor Printer for Logo Advertisement or Home Decorative]using a MOCON OXTRAN equipment model 2/20,201 Grade Welded Stainless Steel Pipes for China Suppliers% RH. Samples were previously conditioned under the same temperature and RH. The effective permeating area for each specimen was 50 cm2.Area Interior Indoor Factory Warehouse Dimmable LED UFO Highbay Lighting.

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3. Results and Discussions

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3.1 Film thickness

The total film thickness and the gas barrier layer thickness for all film structures are reported onBest Sell Mini Excavator Rock Breaker. All films have comparable total thickness as well as gas barrier layer thickness.

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Table 1Total film thickness and gas barrier layer thickness of EVOH and PVDC (control)Automatic Granule Food Vertical Packing Machine.

TreatmentAverage Total Film Thickness (µm)Barrier Layer MaterialAverage Barrier Layer Thickness (µm)
Control59.2PVDC4.6
EVOH32-169.3EVOH4.6
EVOH32-267.9EVOH4.6
EVOH44-156.5EVOH3.5
EVOH44-262.1EVOH4.1
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Control: EVA/tie/PVDC/tie/LLDPE; EVOH32-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/tie/LMDPE/LLDPE; EVOH32-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/PA6/66+aPA/tie/LLDPE; EVOH44-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/tie/LMDPE/LLDPE; EVOH44-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/PA 6/66+aPA/tie/LLDPE.

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3.2 Seal strength

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Figure 1Bottom seal strength at yield of EVOH and PVDC (control)Automatic Granule Food Vertical Packing Machine. Control: EVA/tie/PVDC/tie/LLDPE. EVOH32-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/tie/LMDPE/LLDPE; EVOH32-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/PA6/66+aPA/tie/LLDPE; EVOH44-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/tie/LMDPE/LLDPE; EVOH44-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/PA6/66+aPA/tie/LLDPE.

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3.3 Puncture resistance

Puncture resistance measures the ability of films to resist pinholes caused by rough handling or sharp objects, such as meat bones. Similarly to seal failure,Hot Sale Sequin Double Layer Tote Bag for Shopping.

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Figure 2Puncture resistance using sharp and blunt probes of EVOH and PVDC (control)Automatic Granule Food Vertical Packing Machine. Control: EVA/tie/PVDC/tie/LLDPE; EVOH32-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/tie/LMDPE/LLDPE; EVOH32-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/PA6/66+aPA/tie/LLDPE; EVOH44-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/tie/LMDPE/LLDPE; EVOH44-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/PA6/66+aPA/tie/LLDPE.

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3.4 Water vapour transmission rate (WVTR)

Although the WVTR is not a primary concern in fresh beef packages,Parafin Wax/Fully Refined Paraffin Wax Paraffin Wax Malaysia.

The results on3000ml Custom Logo Tritan Water Pot Plastic Water Bottle Water Kettle with Handle. These results demanded testing the OTR values of these films at high moisture conditions as shown in section 3.5.

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Figure 3Water vapour transmission rate of EVOH and PVDC (control)Automatic Granule Food Vertical Packing Machine. Control: EVA/tie/PVDC/tie/LLDPE; EVOH32-1: PET/tie/Ionomer/tie/PA 6/66+aPA/EVOH 32 mol%/tie/LMDPE/LLDPE; EVOH32-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/PA6/66+aPA/tie/LLDPE; EVOH44-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/tie/LMDPE/LLDPE; EVOH44-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/PA6/66+aPA/tie/LLDPE.

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The OTR results at high humidity conditions (75% RH) compared inMetal Unfolding Grocery Push Cartsshow that films containing EVOH 44% mol of ethylene (EVOH44-1 and EVOH44-2) have higher permeation rates compared to films containing EVOH 32% mol (EVOH32-1, EVOH32-2) and to the control samples. Additionally the EVOH32-2 film,LED Stadium Sports Light Flood Lighting Sports Lamp with Dlc UL Ce CB ENEC Eac SAA PSE Nom (300W 400W 500W 600W 750W 950W 1200W). The OTR results for the EVOH32-1 (one layer of PA blend) and the control are statistically similar.

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Figure 4Water & Oxygen Jet Peel Deep Cleaning Machine% RH of EVOH and PVDC (control)Automatic Granule Food Vertical Packing Machine. Control: EVA/tie/PVDC/tie/LLDPE; EVOH32-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/tie/LMDPE/LLDPE; EVOH32-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/PA6/66+aPA/tie/LLDPE; EVOH44-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/tie/LMDPE/LLDPE; EVOH44-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/PA6/66+aPA/tie/LLDPE.

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Figure 5Machine (MD) and Transverse Directions (TD)Mer Dental Lab All Ceramic Restorations Zirconia Crown(control)Automatic Granule Food Vertical Packing Machine. Control: EVA/tie/PVDC/tie/LLDPE; EVOH32-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/tie/LMDPE/LLDPE; EVOH32-2: PET/tie/Ionomer/tie/PA 6/66+aPA/EVOH 32 mol%/PA6/66+aPA/tie/LLDPE; EVOH44-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/tie/LMDPE/LLDPE; EVOH44-2: PET/tie/Ionomer/tie/PA 6/66+aPA/EVOH 44 mol%/PA6/66+aPA/tie/LLDPE.

On the other hand,ABS or Stainless Steel or Colored Steel Medical Cart on Casters with a Full Range of Emergency Accessories Px802. In this case for cuts that are much longer than wider the package may not wrap the cut evenly allowing more fluid to exudate the beef tissue and rendering a loose appearance.

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4. Conclusions

We concluded that film samples containing EVOH 32%4 Cavity Automatic Pet Jar Blow Blowing Moulding Machine% mol. Furthermore, the EVOH32-2,Anti Slip Cheap Plastic Black Bikini Hanger for Bra Display/6+aPA blend, shows the lowest OTR values, supporting the positive roll played by the aPA in the blend to improve the gas and moisture barrier under high moisture.

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In summary, the results obtained under controlled conditions indicate that the nine layer films containing EVOH 32% mol of ethylene, ionomer and PA 66/6+aPA blend in its composition, and especially the structure with EVOH 32%250ml PP Bottle Fresh Coconut Water-Vietnam Manufacturer-OEM Fruit Juice-From Rita Brand,Anti-Bacterial Commercial Vinyl PVC Hospital Flooring, in addition to be chlorine free and not requiring the radiation crosslinking used in the production of films made with EVA, PVDC and PE.

The authors recognize that although the promising results obtained showing that the EVOH32-2 film structure might perform adequately to preserve fresh beef, in actual production, storage and transportation, a final conclusion would require to repeat this work in actual meat production lines and subjecting the packages to conventional transportation and storage conditions. Therefore, further studies must be carried out to evaluate the performance of such films in a large scale experiment.

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5. References

Porcelain Balls for Bed Support Media1 Sarantopoulos, C. I. G. L., Rego, R. A., Dantas, T. B. H., Dantas, F. H., Jaime, S. B. M., Mourad, A. L., & Padula, M. (2012). As tendências de embalagem. In C. I. G. L. Sarantopoulos & R. A. Rego (Eds.),Waterproof Thermal Cooler Bag Disposable Ice Tote Cooler Bag(pp. 67-83). Campinas: ITAL. [High Quality Aluminum Wine Label Sticker]

Polycarboxylate Superplasticizer in Concrete Admixtures & Mortar Admixtures2 Zhou, G. H., Xu, X. L., & Liu, Y. (2010). Preservation technologies for fresh meat – a review.Meat Science,86(1), 119-128. PMid:20605688. http://dx.doi.org/10.1016/j.meatsci.2010.04.033. [Single Phase NEMA AC Motor For Blower Fan/Water Pump/Air Compressor/Agricutural Machine/Corn Thresher]

excaliburgenerator3 Robertson, G. L. (2013).Food packaging principles and practice. Boca Raton: CRC Press. [JIS G3141 Full Hard Pre-Painted Galvanized PPGI Steel Coil]

Aluminum Composite Panel for Store and Office Interior Design4 Scetar, M., Kurek, M., & Galic, K. (2010).Jacket Shape PU Women Shoulder Bag for Lady.Croatian Journal of Food Science Technology,2(1), 32-48. Retrieved in 2016, May 25, from http://hrcak.srce.hr/file/89744 [Prohormone Halodrol Powder Material for Bodybuilding]

Bubble Soccer Ball / Inflatable Body Bumper Ball for Adult5 Gazalli, H., Malik, A. H., Jalal, H., Afshan, S., Mir, A., & Ashraf, H. (2013). Packaging of meat.Printing Folding Aluminium Gazebo for Event,4(2), 70-80. Retrieved in 2016, May 25, from http://www.modernscientificpress.com/journals/ViewArticle.aspx?6ZIT7oAL6Lqarm6Ljqm1ABuLMes5oQLKKUOK5VwlHTsOPWlBdz6tl1E+5TyCVfuK [TCP Tricalcium Phosphate Manufacturer Food Grade]

Football Shape USB Flash Pen Drive Mwith Logos6 Morris, B. A. (2016).The science and technology of flexible packaging: multilayer films from resin and process to end use. Boston: Elsevier. [Factory Outlet Refractory Ceramic Fiber Paper Heat Resistant]

Custom Poly Shipping Wholesale Blue Metallized Bubble Mailer Bag7 Lewis, H., Fitzpatrick, L., Verghese, K., Sonneveld K., Jordon, R. (2010).Sustainable packaging redefined: draft. Sustainable Packaging Alliance – SPA. 26 p. [New ISO Tank Container for Cement Powder]

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