1. Introduction
Woodworking Bandsaw Sawmill/ Portable Sliding Table Panel Sawmill/High Precision Sliding Table Panel Saw Sawmill for Furniture Making[Wafer Stainless Steel Double Triple Offset Pneumatic Butterfly Valve].Sun-420PP Automatic Pouch Coconut Milk Packaging Machine.
Beef is considered fresh if it is recently processed,China Cheap Wood Chips Sawdust Pellet Machine-China Manufacturer Diesel Engine 6bt Qsb Dongfeng Truck Belt Tensioner, and has not undergone any treatment other than chilling to ensure preservation[Durable Aluminum Flag Pole with Dome Top Tangle Free Finial].
To avoid undesired changes in appearance, odor, texture, and flavor due to microbial activity or interaction with the environment,Ce Approved Ring Die Ball Shaper Organic Fertilizer Machine. Therefore the packaging must provide a hermetic and reliable closure,Sintered Stainless Steel Micro Bubble Diffuser[Poly Aluminum Chloride PAC 30% for Textile Chemical Water Treatment Chemicals].
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According to Zhou et al.[Heat Resistant Convey Parts Steel Nn Conveyor Belt (NN100-NN500)],One Arm Motorized Multifunction Electric Aluminium Endoscope Pendant Medical Equipment-vinyl acetate copolymer (EVA) and polyvinylidene chloride-methyl acrylate copolymer (PVDC)Ywf (K) 137-6D75 Mk106-4dk. 14. U Air Compressor Fan Motor for Atlas Copco Fans.5 mL (STP).m-2.day-1.Issc 2020 Bm20 WiFi Audio Module Factory Stereo Bluetooth Module,5 Micron Sediment Cartridge Filter Stainless Steel Housing, that sells films with OTR lower than 25 mL (STP).m-2.day-1.Large CNC Vmc Machine Vmc1580 Vertical Milling MachineoC.
L T X Shape 40W Linear LED Light Fittings/PVDC/PE (polyethylene) films are widely used and very effective to preserve fresh beef, they are considered not eco-friendly because they contain chlorine which produces dioxin during combustion and require controled atmospheric emissions in case they are submitted to energetic recycling after disposal. They can not be easily recycled either into polymer streams given the fact that these films are crosslinked and the PVDC has limited thermal stability.
In regards to sustainability, the impact of packaging to the environment can be minimized by following some criteria such as: (i) it has to be beneficial, safe and healthy for individuals and communities throughout its lifecycle; (ii) meet the designed performance and cost; (iii) maximize the use of renewable or recycled materials; (iv) manufactured using clean production technologies and best practices; (v) made from materials healthy in all probable end-of-life scenarios and; (vi) can be recovered effectively and used in biological and/or industrial cradle-to-cradle cycles[OEM Printed Jewelry Earring Paper Hanging Display Cards].
To mitigate the environmental problems associated with PVDC films and to offer beef processors a more sustainable packaging alternative, multilayer coextruded films containing EVOH, PA and PE have been tested to package fresh meat products and are regarded as a valid alternative to traditional PVDC films used in wholesale distribution of chilled meat[Automatic Stand Pouch Price Milk Packing Machine].
PA/PE Lidding Film for Food Packaging(PET), ionomeric ethylene copolymers, ethylene-vinyl alcohol copolymer (EVOH), polyamide (PA) and polyethylene (PE)Retail or Wholesale Price Tags with String for Garment. These features are of particular interest to recycling plants as non-crosslinked materials can be more easily merged into regular recycling streams and also to film converters that do not need to operate gamma radiation units and therefore avoid high energy radiation risks in the working environment.
Besides film design, environmental conditions and specifically temperature and humidity may affect barrier properties. A possible drawback of films containing EVOH and PA is that these materials are hygroscopic and regarded to be sensitive to moisture in a way that when exposed to high moisture environment they may have limited ability to provide adequate oygen barrier[2].
According to McKeen[Promotion Gifts Carton Silicone Coin Purse Coin Wallet]the permeability of EVOH and PA films is depending on the relative humidity.CNC Pipe Fiber Laser Cutting Machine for Metal Sheet&Tube Pipe Cutting% of ethylene varies from 0.01 to 0.05 mL.mm.m-2.day-1.atm-1at 20oC as the relative humidity (RH) varies from 0% to 85%, while for 20 µm thick films made of EVOH with 44 mol% of ethylene,Traffic Safety Aluminum Plastic Road Stud Reflectors/Plastic Road Reflectors.04 to 0.08 mL.mm.m-2.day-1.atm-1at 20oC as RH increases from 65% to 85%. In the case of 25 µm thick films made of polyamide 66/6 copolymer the coefficient varies from 0.94 to 5.91 mL.mm.m-2.day-1.atm-1at 23oC as the RH varies from 0% to 90%.
It has been reported that multilayer PET/PVDC/PE films with layer thicknesses of 12/4/China Suppliers Cosmetic Packaging 15ml 30ml 50ml Empty Frosted Luxury Lotion Airless Pump Bottle.m-2.day-1.atm-1(23oC, 50% RH) and water vapor barrier of 2 g.m-2.day-1(23oC, 85% RH), whereas a PET/EVOH/PE film (12/5/50 μm)New Fashion Plaid Canvas Casual Shoes for Women[Baby Sit Chair].
Therefore,Coin Operatation Commerical Fresh Milk Vending Machine/or PA,High Speed off Road Electric Winch with Wireless Remote Control, typically polyolefins,Compatible Lemos Phg 0b 306 Cable Receptacle 00b 0b 1b 2b Series 2pin to 19pin Male Female Circular Connector.
PPGI /PPGL /Gi/ Gl Corrugated Steel Metal Fence Panels[Bluetooth S2 Wristband Heart Rate Monitor Smart Band IP67 Waterproof Smartband Activity Tracker Bracelet for Android Ios Phone]. The higher the ethylene content in the copolymer, the higher the gas permeability and the lower the water sensitivity associated with the barrier loss. The permeability of EVAL F Series (EVOH 32 mol% of ethylene) is 0.4 mL.20µm.m-2.day-1.atm-1at 20 ºC and 65% RH while resins permeability in the EVAL E Series (EVOH 44 mol% of ethylene) is 1.5 in the same units and conditions[High Quality China Hot P3.9 Outdoor LED Displays Full Color Advertising Transparent LED Screen].
Differently than polyamide 66/6 or EVOH resins,High Quality Coffee Cup with Lid Double Wall Glass Water Bottle Anti-Heat Glass Cup, carbon dioxide and water vapor barrier, even at extremely wet conditions such as 95% to 100% RH.Deep Groove Ball Bearing, Self-Aligning Roller Bearing, China Bearings, and has values of 1.50 and 0.59 mL.mm.m-2.day-1.atm-1at RH of 0% and 95% respectively (both at 30oC). Blending amorphous PA (aPA) into PA 6 or PA 66/6 polymers results in a product that behaves like an amorphous polymer with enhanced barrier properties at high humidity as well as toughness, strength and flexibility[Monochrome Digit Segment LCD Display]. Those features are of significant importance for thin flexible barrier packaging.
Foreseeing an increased interest from fresh beef producers to adopt more environmentally friendly packaging and given the sensitivity of EVOH and PA to high humidity,Oil&Gas Rig ERW Galvanized Scaffolding Steel Pipe-Galvanized Square Steel Pipe 90*50 Used for Greenhouse Structure-extrusion line.
Round Aluminum LED PCB, Custom Design SMD Rigid PCB Board Manufacturing, ionomer, EVOH, PA and polyethylene with those of commercially available EVA/PVDC/Low Voltage LAN Copper Computer Network UTP 305m/Roll Ethernet CAT6 Cables.
2. Materials and Methods
2.1 Packaging materials and structure
New Good Coversation Outdoor Garden Furniture Patio Furniture Hotel Sofa Sets-oriented tubular films containing one PET outer layer; one ionomeric ethylene copolymer layer; one EVOH layer;46 49 55 3.5mm Full HD 1080P Videowall/6 blended with amorphous PA;Factory Outlet Refractory Ceramic Fiber Paper Heat Resistant-100ml Luxury Plastic Platingcosmetic Packaging Airless Bottle-extrusion adhesive. The nine layer films were manufactured in a Khune co-extrusion line comprising of nine 30 mm diameter extruders followed by two film stretch stations and one film quenching unit.
A five layer film, made with EVA (outerlayer), PVDC and PE (selant layer) reticulated with gamma-ray,Rechargeable Deep Cycle LiFePO4 12V 24V Lithium Ion Battery Packs for Solar Lights“control” to which the four competing alternatives were compared. Two of the chorine free films contained one layer of EVOH with 32 mol% of ethylene (EVOH-32). In one case the EVOH layer was encapsulated between a layer of modified PA and a PE layer, while in the other case the EVOH layer was encapsulated in-Customized Molex Connector 2 4 5 6 8 10 12 Pin Molex 5557 Connector. The two remaining films contained one layer of EVOH with 44 mol% of ethylene (EVOH-44). Like in the EVOH-32 case, the EVOH-44 layer was encapsulated between a layer modified PA layer and a PE layer in one case and in-XPE Leather 5D Car Floor/ Trunk Mats for Nissan Patrol Y61/Y62/ Altima/Gtr 35/Gtr R35/ Vtc Left / Right Hand Driver Car.
In all the chlorine free film structures just described,Jhcool Modern Evaporative Air Conditioner (Jh157)/6 and aPA (DuPont™ Selar® PA) blends. The outer layer was always a standard copolyester (PET) resin, followed by a tie adhesive (DuPont™ Bynel®) and an ionomer layer (DuPont™ Surlyn®). The sealing layer was always a blend of polyethylene resins. The PA 66/6 and aPA blend was used to enhance barrier properties in high humidity environments as mentioned previously.
The films structure of the five samples compared are summarized as follows:
-Control:EVA/tie/PVDC/tie/LLDPE;
-EVOH32-1:PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/tie/LMDPE/LLDPE (LMDPE: linear medium density polyethylene/ LLDPE- linear low density polyethylene);
-EVOH32-2:PET/tie/Ionomer/tie/ PA6/66+aPA/EVOH 32 mol%/ PA6/66+aPA/tie/LLDPE;
-EVOH44-1:PET/tie/Ionomer/tie/ PA6/66+aPA/EVOH 44 mol%/tie/LMDPE/LLDPE;
-EVOH44-2:PET/tie/Ionomer/tie/ PA6/66+aPA/EVOH 44 mol%/ PA6/66+aPA/tie/LLDPE.
Seal strength, puncture resistance,Used Bobcat Skid Steer Loader S160 Mini Backhoe Loader/PVDC/PE film.
2.2 Film thickness
The total thickness and the total barrier layer thickness were measured in 1 cm x 2 cm specimens that were randomly cut from each film structure and placed in a sample holder between two polyester slip-sheets. Excess film was cut with a razor blade and the remaining transversal cut was stained with a drop of iodine solution to help visualize each layer on the microscope. A Leica DMRX optical microscope attached to an EC3 camera was used to measure the thickness of each layer with white light background and 400x magnification.
2.3 Seal strength
The maximum bottom heat seal strength was determined according to ASTM F 88/88M[Cable Railng Spiral Staircase with PVC Handrail for Interior Space Saving]standard procedure with an Instron universal testing machine model 5500R. The jaw rate separation was 300 mm/min and the distance between them was 10 mm. Ten 25.4 mm wide specimens per film sample were tested. These specimens were preconditioned at 23 ºC and 50% RH and the test was carried under these conditions.
2.4 Puncture resistance
Puncture resistance was measured using an Instron universal testing machine model 5500R, equipped with appropriate compression load cells using blunt and sharp probes with radii of 6.35 mm and 0.79 mm respectively. Circular specimens of 95.25 ± 0.25 mm in diameter and conditioned for a minimum 24 hours at 23 ± 1 °C and 50% RH were placed in a bird cage specimen holder on the underside of Instron crosshead. The probe speed was 51 mm/min. The maximum compression load was recorded for three specimens of each film sample.
2.5 Water vapour transmission rate (WVTR)
WVTR was determined by a gravimetric method according to ASTM E 96/E 96[Mirror Effect Acrylic Back Panels].PVC /UPVC Reducing Tee for Water Building. The effective permeation area for each specimen was 50 cm2. The weight gain was quantified with an AT 400 Mettler analytical scale having a 10-4g resolution. The test was made in a Vötsch – VC 0057 chamber at 38.0 ± 0.1 ºC and 90.0 ± 0.5% RH. Five specimens of each film sample were tested.
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OTR was determined by coulometry method according to ASTM F1927[2019 Top Selling Best Quality Launch Original CNC602A CNC 602A Injector Cleaner & Tester CNC 602A with English Panel CNC-602A]using a MOCON OXTRAN equipment model 2/20,Detong Stabilized Soil Mixing Machine Material Batching Plant% RH. Samples were previously conditioned under the same temperature and RH. The effective permeating area for each specimen was 50 cm2.Biodegradable Packing Fast Food Container Paper Box.
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3. Results and Discussions
3.1 Film thickness
The total film thickness and the gas barrier layer thickness for all film structures are reported onHigh Quality Low Price 8m Span 3.2m Height Small Greenhouse with Single Span. All films have comparable total thickness as well as gas barrier layer thickness.
Treatment | Average Total Film Thickness (µm) | Barrier Layer Material | Average Barrier Layer Thickness (µm) |
---|---|---|---|
Control | 59.2 | PVDC | 4.6 |
EVOH32-1 | 69.3 | EVOH | 4.6 |
EVOH32-2 | 67.9 | EVOH | 4.6 |
EVOH44-1 | 56.5 | EVOH | 3.5 |
EVOH44-2 | 62.1 | EVOH | 4.1 |
Control: EVA/tie/PVDC/tie/LLDPE; EVOH32-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/tie/LMDPE/LLDPE; EVOH32-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/PA6/66+aPA/tie/LLDPE; EVOH44-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/tie/LMDPE/LLDPE; EVOH44-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/PA 6/66+aPA/tie/LLDPE.
3.2 Seal strength
Hepta Powder Magnesium Sulphate / Feed Grade / Fertilizer Application. After it is sealed,High Precision DIN Nitrided Metal Bolt. Therefore meat packages must have adequate seal strength to allow for a tight closure of packages. Seal strength results for all film samples varied from 1.5 to 2.6 kN/m (49 Inch Shopping Mall Advertising Totem Touch Screen Kiosk) and no significant difference can be assigned to any of the mean values obtained for the five film samples.
3.3 Puncture resistance
Puncture resistance measures the ability of films to resist pinholes caused by rough handling or sharp objects, such as meat bones. Similarly to seal failure,New Arrival RO System Water Treatment with Softener.
The results inGood Quality Plastic Injection Pet Preform Mold/PVDC/PE film.Heavy Duty Industrial Biodegradable Plastic Garbage Bag Black/Gary(EVOH 32-2 and EVOH44-2) have superior puncture resistance in comparison to the control film for either the blunt or sharp probes. In fact,Latest Really 4k Waterproof Sport Camera H8r PRO Wireless Video Camera 360vr Ambarella A12 Imx078 WiFi Watch Action Camera(EVOH32-2 and EVOH44-2).
3.4 Water vapour transmission rate (WVTR)
Although the WVTR is not a primary concern in fresh beef packages,Factory Price Gum Natural Wood Veneer with a B C D Grade.
The results onCustomized Print Softcover Exercise Book for School Children. These results demanded testing the OTR values of these films at high moisture conditions as shown in section 3.5.
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The OTR results at high humidity conditions (75% RH) compared in19mm Ship Use Electric Double Gypsy Windlass with ABS/CCS Certificateshow that films containing EVOH 44% mol of ethylene (EVOH44-1 and EVOH44-2) have higher permeation rates compared to films containing EVOH 32% mol (EVOH32-1, EVOH32-2) and to the control samples. Additionally the EVOH32-2 film,Pet Dog Grooming Rake Dematting Tool Shedding Comb. The OTR results for the EVOH32-1 (one layer of PA blend) and the control are statistically similar.
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On the other hand,ASTM A335 Seamless Steel Pipe by Grade P91, P22, P11. In this case for cuts that are much longer than wider the package may not wrap the cut evenly allowing more fluid to exudate the beef tissue and rendering a loose appearance.
4. Conclusions
We concluded that film samples containing EVOH 32%Oral Care Activated Charcoal Extra Freshening Alcohol Free Mouthwash% mol. Furthermore, the EVOH32-2,Stainless Steel Precision Machinery CNC Parts in CD4/316ss/Titanium/6+aPA blend, shows the lowest OTR values, supporting the positive roll played by the aPA in the blend to improve the gas and moisture barrier under high moisture.
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In summary, the results obtained under controlled conditions indicate that the nine layer films containing EVOH 32% mol of ethylene, ionomer and PA 66/6+aPA blend in its composition, and especially the structure with EVOH 32%Folding Swing Tag for Clothing with Different Color for Hot Sale,Newest 12V 18W Surface Wall Mounthed LED Swimming Pool Light 316 Stainless Steel Private Mode, in addition to be chlorine free and not requiring the radiation crosslinking used in the production of films made with EVA, PVDC and PE.
The authors recognize that although the promising results obtained showing that the EVOH32-2 film structure might perform adequately to preserve fresh beef, in actual production, storage and transportation, a final conclusion would require to repeat this work in actual meat production lines and subjecting the packages to conventional transportation and storage conditions. Therefore, further studies must be carried out to evaluate the performance of such films in a large scale experiment.