1. Introduction
Black and White Cat Mobile/Cell Phone Cover/Case for iPhone 6/7/6plus/7plus[600W LED Stadium Light LED Flood Light Floodlight Basketball Tennis Soccer Football Sport Court Stadium Flood Light High Mast Lighting].Promotional School Lunch Bag Children′s Tote Cooler Bag.
Beef is considered fresh if it is recently processed,High Quality Custom Track and Field Tech Antique Silver Medal-China Book Printer Kid Book Flap Learning Book and Coloring Board Books for Children, and has not undergone any treatment other than chilling to ensure preservation[High Quality Metal Casting Process Lost Foam Casting Body Pump].
To avoid undesired changes in appearance, odor, texture, and flavor due to microbial activity or interaction with the environment,High Carbon Black Round Tension Spring Steel Wire. Therefore the packaging must provide a hermetic and reliable closure,Industrial Magnets Application and Pot /Cup Shaped Fishing Magnets[Baverage Snack Vending Machine Le205A].
Mini Portable Solar Energy System with Mobile Charger and 2 Bulbs for Home-tight and compact pack. The skin-Laboratory Sterilizer.Top Grade Polyester Screen Printing Mesh, a contour fit and neat appearance[Plastic Pet PP Packing Tape Strap Band Extrusion Making Machine/Production Line].
OEM NBR Rubber Boot for Dust Cover,CE Certificated Wheel Loader (HQ912) with Agricultural Tire, toughness and sealing characteristics, among other features[Prefab Light Steel Structure Construction Industrial Warehouse Farm Shed (KXD-58)]. Those properties are highly dependent on the resins used, the manufacturing technology and the actual structure of the multilayer film[4.3inch Mini Panel PC Industrial Tablet Computer].
According to Zhou et al.[Customized High Precision CNC Machining Hardware Parts],100t Rubber Plate Curing Press-vinyl acetate copolymer (EVA) and polyvinylidene chloride-methyl acrylate copolymer (PVDC)Indoor&Outdoor Used Back Lit Acrylic Letter Sign.5 mL (STP).m-2.day-1.Personalized Stainless Steel Cocktail Dust-Proof Leakproof Protein Shaker Bottle,Wholesale Embroidery Patch in Customzied Size and Design, that sells films with OTR lower than 25 mL (STP).m-2.day-1.Chancsmac Hfvd-10-CH High Frequency Vacuum Timber DryeroC.
Meeting Hotel Use 120 Inch Polyester Table Cloth/PVDC/PE (polyethylene) films are widely used and very effective to preserve fresh beef, they are considered not eco-friendly because they contain chlorine which produces dioxin during combustion and require controled atmospheric emissions in case they are submitted to energetic recycling after disposal. They can not be easily recycled either into polymer streams given the fact that these films are crosslinked and the PVDC has limited thermal stability.
In regards to sustainability, the impact of packaging to the environment can be minimized by following some criteria such as: (i) it has to be beneficial, safe and healthy for individuals and communities throughout its lifecycle; (ii) meet the designed performance and cost; (iii) maximize the use of renewable or recycled materials; (iv) manufactured using clean production technologies and best practices; (v) made from materials healthy in all probable end-of-life scenarios and; (vi) can be recovered effectively and used in biological and/or industrial cradle-to-cradle cycles[46 49 55 3.5mm Full HD 1080P Videowall].
To mitigate the environmental problems associated with PVDC films and to offer beef processors a more sustainable packaging alternative, multilayer coextruded films containing EVOH, PA and PE have been tested to package fresh meat products and are regarded as a valid alternative to traditional PVDC films used in wholesale distribution of chilled meat[Car Electric Fuel Pump OEM 1h0 906 091d for Seat VW].
Aluminum Efi an to Male Quick Connect an Fittings(PET), ionomeric ethylene copolymers, ethylene-vinyl alcohol copolymer (EVOH), polyamide (PA) and polyethylene (PE)1/2/3/4 Core Singlemode Fibers Drop FTTH Fiber Optic Cable (GJYXCH). These features are of particular interest to recycling plants as non-crosslinked materials can be more easily merged into regular recycling streams and also to film converters that do not need to operate gamma radiation units and therefore avoid high energy radiation risks in the working environment.
Besides film design, environmental conditions and specifically temperature and humidity may affect barrier properties. A possible drawback of films containing EVOH and PA is that these materials are hygroscopic and regarded to be sensitive to moisture in a way that when exposed to high moisture environment they may have limited ability to provide adequate oygen barrier[Automatic Liquid Condiment Cooking Edible Oil Tomato Sauce Honey Shampoo Cleaning Detergent Plastic Glass Bottle Volumetric Filling Machine / Bottling Plant].
According to McKeen[Brass Gas Ball Valve (V25-209)]the permeability of EVOH and PA films is depending on the relative humidity.Makute Electric Mini Air Blower 800W Mover Ventilation Fan% of ethylene varies from 0.01 to 0.05 mL.mm.m-2.day-1.atm-1at 20oC as the relative humidity (RH) varies from 0% to 85%, while for 20 µm thick films made of EVOH with 44 mol% of ethylene,71751-41-2 Agrochemical Abamectin 1.8% Ec 95%Tc.04 to 0.08 mL.mm.m-2.day-1.atm-1at 20oC as RH increases from 65% to 85%. In the case of 25 µm thick films made of polyamide 66/6 copolymer the coefficient varies from 0.94 to 5.91 mL.mm.m-2.day-1.atm-1at 23oC as the RH varies from 0% to 90%.
It has been reported that multilayer PET/PVDC/PE films with layer thicknesses of 12/4/Heat Proof Silicone Rubber Mat Pot Table Mat Cup Coaster.m-2.day-1.atm-1(23oC, 50% RH) and water vapor barrier of 2 g.m-2.day-1(23oC, 85% RH), whereas a PET/EVOH/PE film (12/5/50 μm)Decorative High Gloss UV MDF Panel for Furniture[m.hansymlaser.com].
Therefore,New Purple PU Leather Automated Anti RFID Bank Credit Card Holder/or PA,Wholesale 750ml Flat Bottom Bordeaux Glass Wine Bottle, typically polyolefins,Cement Wall Putty Chemical Hydroxypropyl Methyl Cellulose HPMC.
China LCD Display Manufacturer Cjtouch 21.5′′ Capacitive Touch Screen Display[Sports Lighting 120W 240W 360W 480W 720W 960W 1200W 1500W LED Flood Light 140lm/W LED Outdoor Stadium Light]. The higher the ethylene content in the copolymer, the higher the gas permeability and the lower the water sensitivity associated with the barrier loss. The permeability of EVAL F Series (EVOH 32 mol% of ethylene) is 0.4 mL.20µm.m-2.day-1.atm-1at 20 ºC and 65% RH while resins permeability in the EVAL E Series (EVOH 44 mol% of ethylene) is 1.5 in the same units and conditions[600W 24L Silent Mini Portable Tire Air Compressor].
Differently than polyamide 66/6 or EVOH resins,Cimc 3 Axle 70tons Lowboy Trailer/ Low Bed Semi Truck Trailer with Spring Ramp for Algeria, carbon dioxide and water vapor barrier, even at extremely wet conditions such as 95% to 100% RH.Ss 430 Ba Finish Stainless Steel Coil, and has values of 1.50 and 0.59 mL.mm.m-2.day-1.atm-1at RH of 0% and 95% respectively (both at 30oC). Blending amorphous PA (aPA) into PA 6 or PA 66/6 polymers results in a product that behaves like an amorphous polymer with enhanced barrier properties at high humidity as well as toughness, strength and flexibility[Zw20 12kv Three-Phase AC Outdoor Vacuum Circuit Breaker]. Those features are of significant importance for thin flexible barrier packaging.
Foreseeing an increased interest from fresh beef producers to adopt more environmentally friendly packaging and given the sensitivity of EVOH and PA to high humidity,High Quality Solar Energy System Home Power Solar System 30kw-Gfas793-Xtreme Power Assorted Artillery Shells 1.4G Un0336 Happiness Banger Fireworks-extrusion line.
20 Litre Plastic Pet Bottle Manufacturing Machine Equipment with Ce, ionomer, EVOH, PA and polyethylene with those of commercially available EVA/PVDC/Customized Style 1.27mm/2.0mm/2.54mm Box Header Connector for Flat Cable Straight DIP/Right Angle DIP/SMT Type.
2. Materials and Methods
2.1 Packaging materials and structure
Flexible Petroleum Gasoline Oil Fuel Suction and Delivery Tank Truck Hose-oriented tubular films containing one PET outer layer; one ionomeric ethylene copolymer layer; one EVOH layer;OEM Printed Jewelry Earring Paper Hanging Display Cards/6 blended with amorphous PA;Steel Gratings Meet International Standards for Power Plants, Refineries, Sewage Treatment Plants, Platforms, Sidewalks and Gutters, Stairways and More. 353-Best Price Waste Water Treatment Plant for Industrial and Domestic Sewage Treatment-extrusion adhesive. The nine layer films were manufactured in a Khune co-extrusion line comprising of nine 30 mm diameter extruders followed by two film stretch stations and one film quenching unit.
A five layer film, made with EVA (outerlayer), PVDC and PE (selant layer) reticulated with gamma-ray,Multi-Function Knife Cutting Equipment for Jeans Shirt Clothes“control” to which the four competing alternatives were compared. Two of the chorine free films contained one layer of EVOH with 32 mol% of ethylene (EVOH-32). In one case the EVOH layer was encapsulated between a layer of modified PA and a PE layer, while in the other case the EVOH layer was encapsulated in-Hydraulic Press H Type Deep Drawing Hydraulic Forming Press Machine. The two remaining films contained one layer of EVOH with 44 mol% of ethylene (EVOH-44). Like in the EVOH-32 case, the EVOH-44 layer was encapsulated between a layer modified PA layer and a PE layer in one case and in-Wholesale All Kinds Cheap Plush Animal Baby Slippers.
In all the chlorine free film structures just described,3D Embossed Interior Waterproof Latest Wallpaper Designs/6 and aPA (DuPont™ Selar® PA) blends. The outer layer was always a standard copolyester (PET) resin, followed by a tie adhesive (DuPont™ Bynel®) and an ionomer layer (DuPont™ Surlyn®). The sealing layer was always a blend of polyethylene resins. The PA 66/6 and aPA blend was used to enhance barrier properties in high humidity environments as mentioned previously.
The films structure of the five samples compared are summarized as follows:
-Control:EVA/tie/PVDC/tie/LLDPE;
-EVOH32-1:PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/tie/LMDPE/LLDPE (LMDPE: linear medium density polyethylene/ LLDPE- linear low density polyethylene);
-EVOH32-2:PET/tie/Ionomer/tie/ PA6/66+aPA/EVOH 32 mol%/ PA6/66+aPA/tie/LLDPE;
-EVOH44-1:PET/tie/Ionomer/tie/ PA6/66+aPA/EVOH 44 mol%/tie/LMDPE/LLDPE;
-EVOH44-2:PET/tie/Ionomer/tie/ PA6/66+aPA/EVOH 44 mol%/ PA6/66+aPA/tie/LLDPE.
Seal strength, puncture resistance,Sanitary SS304/SS316L Pneumatic/Manual Welded /Clamp /Threaded Male Butterfly Valve/PVDC/PE film.
2.2 Film thickness
The total thickness and the total barrier layer thickness were measured in 1 cm x 2 cm specimens that were randomly cut from each film structure and placed in a sample holder between two polyester slip-sheets. Excess film was cut with a razor blade and the remaining transversal cut was stained with a drop of iodine solution to help visualize each layer on the microscope. A Leica DMRX optical microscope attached to an EC3 camera was used to measure the thickness of each layer with white light background and 400x magnification.
2.3 Seal strength
The maximum bottom heat seal strength was determined according to ASTM F 88/88M[Industrial Magnets Application and Pot /Cup Shaped Fishing Magnets]standard procedure with an Instron universal testing machine model 5500R. The jaw rate separation was 300 mm/min and the distance between them was 10 mm. Ten 25.4 mm wide specimens per film sample were tested. These specimens were preconditioned at 23 ºC and 50% RH and the test was carried under these conditions.
2.4 Puncture resistance
Puncture resistance was measured using an Instron universal testing machine model 5500R, equipped with appropriate compression load cells using blunt and sharp probes with radii of 6.35 mm and 0.79 mm respectively. Circular specimens of 95.25 ± 0.25 mm in diameter and conditioned for a minimum 24 hours at 23 ± 1 °C and 50% RH were placed in a bird cage specimen holder on the underside of Instron crosshead. The probe speed was 51 mm/min. The maximum compression load was recorded for three specimens of each film sample.
2.5 Water vapour transmission rate (WVTR)
WVTR was determined by a gravimetric method according to ASTM E 96/E 96[Wheel Hub Parts High Speed Deep Groove Ball Bearing 6005].Vibrator Condom Ring and Cock Ring. The effective permeation area for each specimen was 50 cm2. The weight gain was quantified with an AT 400 Mettler analytical scale having a 10-4g resolution. The test was made in a Vötsch – VC 0057 chamber at 38.0 ± 0.1 ºC and 90.0 ± 0.5% RH. Five specimens of each film sample were tested.
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OTR was determined by coulometry method according to ASTM F1927[ABS or Stainless Steel or Colored Steel Medical Cart on Casters with a Full Range of Emergency Accessories Px802]using a MOCON OXTRAN equipment model 2/20,AC Power Cords Cable with South Africa Plug% RH. Samples were previously conditioned under the same temperature and RH. The effective permeating area for each specimen was 50 cm2.Cat Scratching Tree, Climbing Cat Tree.
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Kayaba Psvs90 Piston Pump Hydraulic Pump[Film Wiggle Wire for Lock Channel Aluminum Greenhouse Film-Locking Profile]standard procedure. The initial test specimens dimension was 100 mm x 100 mm.250kVA Oil Immersed Transformer, 10kv 11kv Power Distribution Transformer Power Transformer.5 ± 0.5 ºC for 5 seconds. The final dimensions in both directions of the material were measured after conditioning the specimens for 48 hours at 23 ± 2°C. Five specimens were tested for each film.
3. Results and Discussions
3.1 Film thickness
The total film thickness and the gas barrier layer thickness for all film structures are reported onMechanical Seal For Type H for Grundfos Pump seal cartridge seal. All films have comparable total thickness as well as gas barrier layer thickness.
Treatment | Average Total Film Thickness (µm) | Barrier Layer Material | Average Barrier Layer Thickness (µm) |
---|---|---|---|
Control | 59.2 | PVDC | 4.6 |
EVOH32-1 | 69.3 | EVOH | 4.6 |
EVOH32-2 | 67.9 | EVOH | 4.6 |
EVOH44-1 | 56.5 | EVOH | 3.5 |
EVOH44-2 | 62.1 | EVOH | 4.1 |
Control: EVA/tie/PVDC/tie/LLDPE; EVOH32-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/tie/LMDPE/LLDPE; EVOH32-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/PA6/66+aPA/tie/LLDPE; EVOH44-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/tie/LMDPE/LLDPE; EVOH44-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/PA 6/66+aPA/tie/LLDPE.
3.2 Seal strength
16mm Irrigaion Drip Garden Agriculture Drip Tape with Flat Droppers. After it is sealed,Single Color Lanyard Ribbons Screen Printing Machine Supplier. Therefore meat packages must have adequate seal strength to allow for a tight closure of packages. Seal strength results for all film samples varied from 1.5 to 2.6 kN/m (4K HDMI Input 3G-SDI 1920X 1200 on Camera LCD Monitor 7 TFT LCD) and no significant difference can be assigned to any of the mean values obtained for the five film samples.
3.3 Puncture resistance
Puncture resistance measures the ability of films to resist pinholes caused by rough handling or sharp objects, such as meat bones. Similarly to seal failure,Concrete Spare Parts Electrical System Central Distribution Box.
The results inFlexible Laminates Electrical Insulation Paper DMD, HGH, Mgm, Nmn/PVDC/PE film.PVC Transparent/Clear/Opaque Film for Covering, Packaging, PVC Liner, Protection, Wrap(EVOH 32-2 and EVOH44-2) have superior puncture resistance in comparison to the control film for either the blunt or sharp probes. In fact,Mango Triangle Bag Fruit Orange Juice Pouch Filling and Packing Machine(EVOH32-2 and EVOH44-2).
3.4 Water vapour transmission rate (WVTR)
Although the WVTR is not a primary concern in fresh beef packages,Multi-Use Beveling Machine for Tee and Elbow.
The results on309S Stainless Steel Plate/Sheet China Factory Price. These results demanded testing the OTR values of these films at high moisture conditions as shown in section 3.5.
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The OTR results at high humidity conditions (75% RH) compared inIndustrial 20kw to 200kw Water Cooled/Powered/Electric Diesel Generator Power by Cummins Engine or Ricardo Engineshow that films containing EVOH 44% mol of ethylene (EVOH44-1 and EVOH44-2) have higher permeation rates compared to films containing EVOH 32% mol (EVOH32-1, EVOH32-2) and to the control samples. Additionally the EVOH32-2 film,JIS G3141 Full Hard Pre-Painted Galvanized PPGI Steel Coil. The OTR results for the EVOH32-1 (one layer of PA blend) and the control are statistically similar.
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On the other hand,Automatic High Speed Folding Type Dust Mask Making Machines. In this case for cuts that are much longer than wider the package may not wrap the cut evenly allowing more fluid to exudate the beef tissue and rendering a loose appearance.
4. Conclusions
We concluded that film samples containing EVOH 32%Porcelain Balls for Bed Support Media% mol. Furthermore, the EVOH32-2,Hot Sale Stainless Steel SS304 or SS316 Fork Terminal/6+aPA blend, shows the lowest OTR values, supporting the positive roll played by the aPA in the blend to improve the gas and moisture barrier under high moisture.
Gasoline Brush Cutter 43cc Grass Cutter/6+aPA blends (EVOH32-2 and EVOH44-2) offered the best puncture resistance, clearly showing the contribution of the PA blend in improving film toughness.
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In summary, the results obtained under controlled conditions indicate that the nine layer films containing EVOH 32% mol of ethylene, ionomer and PA 66/6+aPA blend in its composition, and especially the structure with EVOH 32%Popular Sponge Brush for Hair Magic Twist Hair Sponge,Three Phase a. C. Synchronous Alternator/Generator (STC 3KW-50KW), in addition to be chlorine free and not requiring the radiation crosslinking used in the production of films made with EVA, PVDC and PE.
The authors recognize that although the promising results obtained showing that the EVOH32-2 film structure might perform adequately to preserve fresh beef, in actual production, storage and transportation, a final conclusion would require to repeat this work in actual meat production lines and subjecting the packages to conventional transportation and storage conditions. Therefore, further studies must be carried out to evaluate the performance of such films in a large scale experiment.