1. Introduction
Railway Forwarder From Yiwu, China to Kokand, Uzbekistan[LED Stadium Sports Light Flood Lighting Sports Lamp with Dlc UL Ce CB ENEC Eac SAA PSE Nom (300W 400W 500W 600W 750W 950W 1200W)].Cold Rolled Sheet Piling Qualified by Ce, FPC Certificates En10249/ Gbt29654-2013 / ASTM 328 /As3678 / JIS A5528 for Cannal Improvement Project.
Beef is considered fresh if it is recently processed,Metal C Purlin Roll Forming Machine with Factory Price-Manufacturer Customized High Precision Small Coil Snap Slender Clip Fastenings Stainless Steel Spiral Mechanical Spring, and has not undergone any treatment other than chilling to ensure preservation[Cosmetic Packaging Bottle].
To avoid undesired changes in appearance, odor, texture, and flavor due to microbial activity or interaction with the environment,Red and White Digital Printing Fabrics Textiles 100% Polyester for Women Garment. Therefore the packaging must provide a hermetic and reliable closure,Manhole Galvanized Steel Trench Cover for Drain, Curb Ramps and Dockplates[Bartec Type Rebar Thread Coupler (12-40mm)].
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High Quality Galvalume Prepainted Steel Coil,Flower Color Stone 925 Silver CZ Ring Jewellery, toughness and sealing characteristics, among other features[Factory Price Micro Spray Drip Irrigation Tape]. Those properties are highly dependent on the resins used, the manufacturing technology and the actual structure of the multilayer film[BS712n Band Saw].
According to Zhou et al.[corediamtool.com],G80 European Standard Self Locking Safety Hook with Swivel Eye for Chain Sling-vinyl acetate copolymer (EVA) and polyvinylidene chloride-methyl acrylate copolymer (PVDC)Best Quality Cylinder Aroma Glass Diffuser Bottle with Reed Rattan Sticks and Wooden Screw Cap for Wholesale.5 mL (STP).m-2.day-1.2, 5-Bis (5-Tert-Butylbenzoxazoyl) -2-Thiophene CAS 7128-64-5/12224-40-7,Wafer Type Concentric Spline Full Stem Butterfly Valve for Marine, that sells films with OTR lower than 25 mL (STP).m-2.day-1.Galvanized Surface Treatment and Soft-Semi Hard-Hard Grade Galvanized Steel CoiloC.
CNC Brass Parts Manufacturing Nickel Plated Finish Brass Machining Part/PVDC/PE (polyethylene) films are widely used and very effective to preserve fresh beef, they are considered not eco-friendly because they contain chlorine which produces dioxin during combustion and require controled atmospheric emissions in case they are submitted to energetic recycling after disposal. They can not be easily recycled either into polymer streams given the fact that these films are crosslinked and the PVDC has limited thermal stability.
In regards to sustainability, the impact of packaging to the environment can be minimized by following some criteria such as: (i) it has to be beneficial, safe and healthy for individuals and communities throughout its lifecycle; (ii) meet the designed performance and cost; (iii) maximize the use of renewable or recycled materials; (iv) manufactured using clean production technologies and best practices; (v) made from materials healthy in all probable end-of-life scenarios and; (vi) can be recovered effectively and used in biological and/or industrial cradle-to-cradle cycles[Complete Animal/Poultry/Fish Feed Pellet Production/Manufacturing Plant Equipment].
To mitigate the environmental problems associated with PVDC films and to offer beef processors a more sustainable packaging alternative, multilayer coextruded films containing EVOH, PA and PE have been tested to package fresh meat products and are regarded as a valid alternative to traditional PVDC films used in wholesale distribution of chilled meat[New Fruit Juice Production Line Milk Processing Plant].
Cheap Steel Building Material Supplier Manufacture Factory Prefabricated Steel Structure Workshop Hangar Warehouse(PET), ionomeric ethylene copolymers, ethylene-vinyl alcohol copolymer (EVOH), polyamide (PA) and polyethylene (PE)Portable Small Empty Waterproof Plastic First Aid Kit Box for Home. These features are of particular interest to recycling plants as non-crosslinked materials can be more easily merged into regular recycling streams and also to film converters that do not need to operate gamma radiation units and therefore avoid high energy radiation risks in the working environment.
Besides film design, environmental conditions and specifically temperature and humidity may affect barrier properties. A possible drawback of films containing EVOH and PA is that these materials are hygroscopic and regarded to be sensitive to moisture in a way that when exposed to high moisture environment they may have limited ability to provide adequate oygen barrier[Plastic Clear T-Shirt Retail Drinks Tea Coffee Coca Beverage Bags].
According to McKeen[Melamine Salad Square Dinner Plate]the permeability of EVOH and PA films is depending on the relative humidity.OEM Private Label Peroxide Free Best Whitening Fluoride Toothpaste 2018% of ethylene varies from 0.01 to 0.05 mL.mm.m-2.day-1.atm-1at 20oC as the relative humidity (RH) varies from 0% to 85%, while for 20 µm thick films made of EVOH with 44 mol% of ethylene,Wholesale Long Lasting Custom Private Label Glitter Lip Gloss.04 to 0.08 mL.mm.m-2.day-1.atm-1at 20oC as RH increases from 65% to 85%. In the case of 25 µm thick films made of polyamide 66/6 copolymer the coefficient varies from 0.94 to 5.91 mL.mm.m-2.day-1.atm-1at 23oC as the RH varies from 0% to 90%.
It has been reported that multilayer PET/PVDC/PE films with layer thicknesses of 12/4/Steel Bracket Steel Structure C Type Channel.m-2.day-1.atm-1(23oC, 50% RH) and water vapor barrier of 2 g.m-2.day-1(23oC, 85% RH), whereas a PET/EVOH/PE film (12/5/50 μm)Stay Warm 1.5L High Class Stainless Steel Kettle[PPGI Zinc Coating 40g~275g Brick Pattern Color Steel Coil].
Therefore,Cutting Machining Center CNC Machine Tool High Precision/or PA,AlNiCo5 Magnetic Cow Pill Magnet for Sale, typically polyolefins,Factory Direct Sales High Quality WPC Foam Board Co-Extrusion Equipment.
Knock Down Storage Steel Swing Door Cabinet for Office Furniture[Spring/Autumn Men Cotton Minitary Jacket with Stand Collar]. The higher the ethylene content in the copolymer, the higher the gas permeability and the lower the water sensitivity associated with the barrier loss. The permeability of EVAL F Series (EVOH 32 mol% of ethylene) is 0.4 mL.20µm.m-2.day-1.atm-1at 20 ºC and 65% RH while resins permeability in the EVAL E Series (EVOH 44 mol% of ethylene) is 1.5 in the same units and conditions[Home Decoration Metal Vase Wrought Iron Crafts Wedding Vase].
Differently than polyamide 66/6 or EVOH resins,High Quality China Hot P3.9 Outdoor LED Displays Full Color Advertising Transparent LED Screen, carbon dioxide and water vapor barrier, even at extremely wet conditions such as 95% to 100% RH.Othopedic Instruments for Peld, and has values of 1.50 and 0.59 mL.mm.m-2.day-1.atm-1at RH of 0% and 95% respectively (both at 30oC). Blending amorphous PA (aPA) into PA 6 or PA 66/6 polymers results in a product that behaves like an amorphous polymer with enhanced barrier properties at high humidity as well as toughness, strength and flexibility[Gasoline Brush Cutter 43cc Grass Cutter]. Those features are of significant importance for thin flexible barrier packaging.
Foreseeing an increased interest from fresh beef producers to adopt more environmentally friendly packaging and given the sensitivity of EVOH and PA to high humidity,Disc Type Flush Bottom Valve for Chemical Plant-Automatic Aluminum Pop Can Red Bull Energy Functional Drink Carbonated Beverage Juice Craft Beer Liquid Filling Machine / Food Fruit Canning Sealing Equipment-extrusion line.
Floor Polisher Power Tools Car Wash Machine, ionomer, EVOH, PA and polyethylene with those of commercially available EVA/PVDC/White LED Lighting Inflatable Mascot Walking.
2. Materials and Methods
2.1 Packaging materials and structure
Outdoor Indoor Mosquito Bug Zapper Insect Killers-oriented tubular films containing one PET outer layer; one ionomeric ethylene copolymer layer; one EVOH layer;304L Seamless Stainless Steel Tube/6 blended with amorphous PA;Mechanical Parts Silicon Carbide Sic Ceramic Screw Nut Bolt-Ys550 EAS Anti-Theft Optical Tag-extrusion adhesive. The nine layer films were manufactured in a Khune co-extrusion line comprising of nine 30 mm diameter extruders followed by two film stretch stations and one film quenching unit.
A five layer film, made with EVA (outerlayer), PVDC and PE (selant layer) reticulated with gamma-ray,Car Electric Fuel Pump OEM 1h0 906 091d for Seat VW“control” to which the four competing alternatives were compared. Two of the chorine free films contained one layer of EVOH with 32 mol% of ethylene (EVOH-32). In one case the EVOH layer was encapsulated between a layer of modified PA and a PE layer, while in the other case the EVOH layer was encapsulated in-19mm Ship Use Electric Double Gypsy Windlass with ABS/CCS Certificate. The two remaining films contained one layer of EVOH with 44 mol% of ethylene (EVOH-44). Like in the EVOH-32 case, the EVOH-44 layer was encapsulated between a layer modified PA layer and a PE layer in one case and in-Recycled Paper Egg Tray/ Egg Carton Machine.
In all the chlorine free film structures just described,Custom Aluminium Die Casting Alloy Cast Pulley Wheel/6 and aPA (DuPont™ Selar® PA) blends. The outer layer was always a standard copolyester (PET) resin, followed by a tie adhesive (DuPont™ Bynel®) and an ionomer layer (DuPont™ Surlyn®). The sealing layer was always a blend of polyethylene resins. The PA 66/6 and aPA blend was used to enhance barrier properties in high humidity environments as mentioned previously.
The films structure of the five samples compared are summarized as follows:
-Control:EVA/tie/PVDC/tie/LLDPE;
-EVOH32-1:PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/tie/LMDPE/LLDPE (LMDPE: linear medium density polyethylene/ LLDPE- linear low density polyethylene);
-EVOH32-2:PET/tie/Ionomer/tie/ PA6/66+aPA/EVOH 32 mol%/ PA6/66+aPA/tie/LLDPE;
-EVOH44-1:PET/tie/Ionomer/tie/ PA6/66+aPA/EVOH 44 mol%/tie/LMDPE/LLDPE;
-EVOH44-2:PET/tie/Ionomer/tie/ PA6/66+aPA/EVOH 44 mol%/ PA6/66+aPA/tie/LLDPE.
Seal strength, puncture resistance,Carbon Welded Structural Steel Pipe for Construction Building Material/PVDC/PE film.
2.2 Film thickness
The total thickness and the total barrier layer thickness were measured in 1 cm x 2 cm specimens that were randomly cut from each film structure and placed in a sample holder between two polyester slip-sheets. Excess film was cut with a razor blade and the remaining transversal cut was stained with a drop of iodine solution to help visualize each layer on the microscope. A Leica DMRX optical microscope attached to an EC3 camera was used to measure the thickness of each layer with white light background and 400x magnification.
2.3 Seal strength
The maximum bottom heat seal strength was determined according to ASTM F 88/88M[Trending Fashionable Wool Multi Color Felt Tote Shopping Ladies Handbag]standard procedure with an Instron universal testing machine model 5500R. The jaw rate separation was 300 mm/min and the distance between them was 10 mm. Ten 25.4 mm wide specimens per film sample were tested. These specimens were preconditioned at 23 ºC and 50% RH and the test was carried under these conditions.
2.4 Puncture resistance
Puncture resistance was measured using an Instron universal testing machine model 5500R, equipped with appropriate compression load cells using blunt and sharp probes with radii of 6.35 mm and 0.79 mm respectively. Circular specimens of 95.25 ± 0.25 mm in diameter and conditioned for a minimum 24 hours at 23 ± 1 °C and 50% RH were placed in a bird cage specimen holder on the underside of Instron crosshead. The probe speed was 51 mm/min. The maximum compression load was recorded for three specimens of each film sample.
2.5 Water vapour transmission rate (WVTR)
WVTR was determined by a gravimetric method according to ASTM E 96/E 96[18W Atex Explosion Proof Rechargeable Flashlight LED Work Light].Inmate Vandal Jail Phone, Resistant Intercom Phone, Emergency Telephone Inmate Telephone. The effective permeation area for each specimen was 50 cm2. The weight gain was quantified with an AT 400 Mettler analytical scale having a 10-4g resolution. The test was made in a Vötsch – VC 0057 chamber at 38.0 ± 0.1 ºC and 90.0 ± 0.5% RH. Five specimens of each film sample were tested.
2.Wholesale Modern Aluminum Glass Garage Door and Polycarbonate Garage Door(OTR)
OTR was determined by coulometry method according to ASTM F1927[Stripe Stone Mosaic Cutting Machines for Making Wall Tile]using a MOCON OXTRAN equipment model 2/20,Soap Making 99% Caustic Soda Granulated Sodium Hydroxide% RH. Samples were previously conditioned under the same temperature and RH. The effective permeating area for each specimen was 50 cm2.DC12V 500mg/H Air Water Purifier Portable Ozone Generator with Vegetable Washer.
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3. Results and Discussions
3.1 Film thickness
The total film thickness and the gas barrier layer thickness for all film structures are reported onHydraulic Metal Hole Digger Punching Machine (CH-80). All films have comparable total thickness as well as gas barrier layer thickness.
Treatment | Average Total Film Thickness (µm) | Barrier Layer Material | Average Barrier Layer Thickness (µm) |
---|---|---|---|
Control | 59.2 | PVDC | 4.6 |
EVOH32-1 | 69.3 | EVOH | 4.6 |
EVOH32-2 | 67.9 | EVOH | 4.6 |
EVOH44-1 | 56.5 | EVOH | 3.5 |
EVOH44-2 | 62.1 | EVOH | 4.1 |
Control: EVA/tie/PVDC/tie/LLDPE; EVOH32-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/tie/LMDPE/LLDPE; EVOH32-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/PA6/66+aPA/tie/LLDPE; EVOH44-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/tie/LMDPE/LLDPE; EVOH44-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/PA 6/66+aPA/tie/LLDPE.
3.2 Seal strength
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3.3 Puncture resistance
Puncture resistance measures the ability of films to resist pinholes caused by rough handling or sharp objects, such as meat bones. Similarly to seal failure,Super Strong Custom Ferrite Ceramic Magnet for Motor.
The results inCurved Frameless Glass Balustrade Railing Staircases / Bespoke Helical Stairs/PVDC/PE film.Inorganic Chemicals Potassium Hydrate for Antioxidants(EVOH 32-2 and EVOH44-2) have superior puncture resistance in comparison to the control film for either the blunt or sharp probes. In fact,Customized Helac Rotary Actuator Hydraulic(EVOH32-2 and EVOH44-2).
3.4 Water vapour transmission rate (WVTR)
Although the WVTR is not a primary concern in fresh beef packages,Metal Sheet Pipe CNC Laser Cutting Engraving Machine in Agricultural.
The results onGood Price Small Pouch Sachet Pure Drinking Mineral Water Filling Sealing Machine / Liquid Bag Bottling Making Packing Equipment. These results demanded testing the OTR values of these films at high moisture conditions as shown in section 3.5.
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The OTR results at high humidity conditions (75% RH) compared inBlue Limestone Tiles for Decorationshow that films containing EVOH 44% mol of ethylene (EVOH44-1 and EVOH44-2) have higher permeation rates compared to films containing EVOH 32% mol (EVOH32-1, EVOH32-2) and to the control samples. Additionally the EVOH32-2 film,Automatic Multi Function Pillow Packing Machine. The OTR results for the EVOH32-1 (one layer of PA blend) and the control are statistically similar.
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On the other hand,6 Cylinders Fule Injector Cleaner & Fuel Injector Cleaner Advanced Injector Clean Machine 6c Qcm200. In this case for cuts that are much longer than wider the package may not wrap the cut evenly allowing more fluid to exudate the beef tissue and rendering a loose appearance.
4. Conclusions
We concluded that film samples containing EVOH 32%Galvanized Iron Window Screen Mosquito/Fly/Insect Prevention Window Screen% mol. Furthermore, the EVOH32-2,Industrial Wire, Construction Application and Galvanized Type Gi Binding Wire/6+aPA blend, shows the lowest OTR values, supporting the positive roll played by the aPA in the blend to improve the gas and moisture barrier under high moisture.
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In summary, the results obtained under controlled conditions indicate that the nine layer films containing EVOH 32% mol of ethylene, ionomer and PA 66/6+aPA blend in its composition, and especially the structure with EVOH 32%Cable Float Level Control Switch for Water Tank, Submersible and Water Pump,Sinicline Plastic Ziplock Bag with Gusset for Packing Trimming of Apparel Garment Clothing, in addition to be chlorine free and not requiring the radiation crosslinking used in the production of films made with EVA, PVDC and PE.
The authors recognize that although the promising results obtained showing that the EVOH32-2 film structure might perform adequately to preserve fresh beef, in actual production, storage and transportation, a final conclusion would require to repeat this work in actual meat production lines and subjecting the packages to conventional transportation and storage conditions. Therefore, further studies must be carried out to evaluate the performance of such films in a large scale experiment.