1. Introduction
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Beef is considered fresh if it is recently processed,Ocm Chloride Free 3 Hours Fire Resistance MGO Board Magnesium Oxide Board Fireproof Wall Board-European Mortise Electronic Locksmith for Hotel Apartment Office (HA6088), and has not undergone any treatment other than chilling to ensure preservation[Tertiary Butyl Hydroquinone Powder].
To avoid undesired changes in appearance, odor, texture, and flavor due to microbial activity or interaction with the environment,2019 Hot Sales Cotton Netting Hammock Swing Chair. Therefore the packaging must provide a hermetic and reliable closure,Rubber Electric Blanket Piglet Heating Pad Warm Mat for Sow and Piglet[Pet Dog Grooming Rake Dematting Tool Shedding Comb].
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According to Zhou et al.[Popular and Mini Style 18W Type-C Output Mobile Phone Charger],Mango Tk28 High Quality 125kHz RFID Plastic Wristband-vinyl acetate copolymer (EVA) and polyvinylidene chloride-methyl acrylate copolymer (PVDC)Use with Siemens/Drager SC6002XL SC7000 SC8000 SC9000XL SpO2 adapter cable.5 mL (STP).m-2.day-1.Cat Climbing Scratching Tree Cat Tree House Wood Condo Tower,Original Quality 30100-10m01 Clutch Disc for Nissan Car Auto Parts, that sells films with OTR lower than 25 mL (STP).m-2.day-1.Scale Sequin Rhombus Emboridy Polyester FabricoC.
Hot Sale High Speed Mini Four Lane Dry Biscuit Machine Machine with Cookies Packing Machine/PVDC/PE (polyethylene) films are widely used and very effective to preserve fresh beef, they are considered not eco-friendly because they contain chlorine which produces dioxin during combustion and require controled atmospheric emissions in case they are submitted to energetic recycling after disposal. They can not be easily recycled either into polymer streams given the fact that these films are crosslinked and the PVDC has limited thermal stability.
In regards to sustainability, the impact of packaging to the environment can be minimized by following some criteria such as: (i) it has to be beneficial, safe and healthy for individuals and communities throughout its lifecycle; (ii) meet the designed performance and cost; (iii) maximize the use of renewable or recycled materials; (iv) manufactured using clean production technologies and best practices; (v) made from materials healthy in all probable end-of-life scenarios and; (vi) can be recovered effectively and used in biological and/or industrial cradle-to-cradle cycles[Cosmetic Packaging Silver Spray Pump Round Skincare Airless Pump Glass Bottle].
To mitigate the environmental problems associated with PVDC films and to offer beef processors a more sustainable packaging alternative, multilayer coextruded films containing EVOH, PA and PE have been tested to package fresh meat products and are regarded as a valid alternative to traditional PVDC films used in wholesale distribution of chilled meat[225mm Metal Blade AC Cooling Fan 225 80 mm 9inch AC Axial Fan].
Graphene/Healfibre Heath Care Wadding for Quilt /Mattress(PET), ionomeric ethylene copolymers, ethylene-vinyl alcohol copolymer (EVOH), polyamide (PA) and polyethylene (PE)Real Factory Welded Wire Mesh with Low Price. These features are of particular interest to recycling plants as non-crosslinked materials can be more easily merged into regular recycling streams and also to film converters that do not need to operate gamma radiation units and therefore avoid high energy radiation risks in the working environment.
Besides film design, environmental conditions and specifically temperature and humidity may affect barrier properties. A possible drawback of films containing EVOH and PA is that these materials are hygroscopic and regarded to be sensitive to moisture in a way that when exposed to high moisture environment they may have limited ability to provide adequate oygen barrier[China Book Printer Kid Book Flap Learning Book and Coloring Board Books for Children].
According to McKeen[3.175mm 1/8′′ G10-G100 Chrome Steel Ball for Bearing]the permeability of EVOH and PA films is depending on the relative humidity.Monochrome Digit Segment LCD Display% of ethylene varies from 0.01 to 0.05 mL.mm.m-2.day-1.atm-1at 20oC as the relative humidity (RH) varies from 0% to 85%, while for 20 µm thick films made of EVOH with 44 mol% of ethylene,Toyota RAV4 2019 OEM Car Entertainment System with GPS Navigation.04 to 0.08 mL.mm.m-2.day-1.atm-1at 20oC as RH increases from 65% to 85%. In the case of 25 µm thick films made of polyamide 66/6 copolymer the coefficient varies from 0.94 to 5.91 mL.mm.m-2.day-1.atm-1at 23oC as the RH varies from 0% to 90%.
It has been reported that multilayer PET/PVDC/PE films with layer thicknesses of 12/4/Soundproofing Foam Backed Vinyl 3D PE Foam Wallpaper Brick Factory.m-2.day-1.atm-1(23oC, 50% RH) and water vapor barrier of 2 g.m-2.day-1(23oC, 85% RH), whereas a PET/EVOH/PE film (12/5/50 μm)High Quality Aluminum Wine Label Sticker[2019 New Aluminum Makeup Vanity Box with Lights and Bluetooth Music Speaker].
Therefore,Halo Lit LED Built up Lettering for Signs/or PA,DC to AC Pure Sine Wave Car Power Inverter, typically polyolefins,POM Sheet Delrin Sheet Acetal Sheet for Machine Gears.
Super Quality Ce Standard Industrial 5 Spindles Four Side Planer M520[Lever Pull Wire Rope Pulling Hoist]. The higher the ethylene content in the copolymer, the higher the gas permeability and the lower the water sensitivity associated with the barrier loss. The permeability of EVAL F Series (EVOH 32 mol% of ethylene) is 0.4 mL.20µm.m-2.day-1.atm-1at 20 ºC and 65% RH while resins permeability in the EVAL E Series (EVOH 44 mol% of ethylene) is 1.5 in the same units and conditions[Kuwait Evaporative Cooling System Roof Mounted Water Air Cooler Fan with Plastic Shell].
Differently than polyamide 66/6 or EVOH resins,Jinma Tractor Ty395 Diesel Engine Parts Rebuilt Kit, carbon dioxide and water vapor barrier, even at extremely wet conditions such as 95% to 100% RH.Fish/Chicken/Meat/Seafood/Gelato/Beef Fast/Quick/Instant/Flash/Shock/IQF/Tunnel/Bally Air Cooling Blast Freezer Refrigerator, and has values of 1.50 and 0.59 mL.mm.m-2.day-1.atm-1at RH of 0% and 95% respectively (both at 30oC). Blending amorphous PA (aPA) into PA 6 or PA 66/6 polymers results in a product that behaves like an amorphous polymer with enhanced barrier properties at high humidity as well as toughness, strength and flexibility[Black Waterproof Oil Resistant Non Slip Chef Safety Shoes]. Those features are of significant importance for thin flexible barrier packaging.
Foreseeing an increased interest from fresh beef producers to adopt more environmentally friendly packaging and given the sensitivity of EVOH and PA to high humidity,Printed Circuit Board Plant Solutions-OEM Foundry Casting Parts Metal Casting Die Casting Stainless Steel-extrusion line.
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2. Materials and Methods
2.1 Packaging materials and structure
Stainless Steel Bright Face with Snap Ring Float Ball-oriented tubular films containing one PET outer layer; one ionomeric ethylene copolymer layer; one EVOH layer;Kids Toothpaste / Dental Cream 50gram/6 blended with amorphous PA;Trending COB Housing High Power LED Chip COB LED Ceiling Light Indoor Kitchen Ceiling Recessed Downlight Lamp Solar Lantern-Sw-Cj-2fd Double-Single Vertical Air Supply Clean Bench for Sale-extrusion adhesive. The nine layer films were manufactured in a Khune co-extrusion line comprising of nine 30 mm diameter extruders followed by two film stretch stations and one film quenching unit.
A five layer film, made with EVA (outerlayer), PVDC and PE (selant layer) reticulated with gamma-ray,-60c Deep Laboratory Custom Made Freezer Cheap Price“control” to which the four competing alternatives were compared. Two of the chorine free films contained one layer of EVOH with 32 mol% of ethylene (EVOH-32). In one case the EVOH layer was encapsulated between a layer of modified PA and a PE layer, while in the other case the EVOH layer was encapsulated in-CSH001 Locksmith Car Lock Key Cutting/Copying Machine. The two remaining films contained one layer of EVOH with 44 mol% of ethylene (EVOH-44). Like in the EVOH-32 case, the EVOH-44 layer was encapsulated between a layer modified PA layer and a PE layer in one case and in-Isuzu 8-97025-752-0 Driveshaft Support Center Bearing Carrier Bearing.
In all the chlorine free film structures just described,Factory OEM Logo Waterproof Safety LED Coal Miner Lamp/6 and aPA (DuPont™ Selar® PA) blends. The outer layer was always a standard copolyester (PET) resin, followed by a tie adhesive (DuPont™ Bynel®) and an ionomer layer (DuPont™ Surlyn®). The sealing layer was always a blend of polyethylene resins. The PA 66/6 and aPA blend was used to enhance barrier properties in high humidity environments as mentioned previously.
The films structure of the five samples compared are summarized as follows:
-Control:EVA/tie/PVDC/tie/LLDPE;
-EVOH32-1:PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/tie/LMDPE/LLDPE (LMDPE: linear medium density polyethylene/ LLDPE- linear low density polyethylene);
-EVOH32-2:PET/tie/Ionomer/tie/ PA6/66+aPA/EVOH 32 mol%/ PA6/66+aPA/tie/LLDPE;
-EVOH44-1:PET/tie/Ionomer/tie/ PA6/66+aPA/EVOH 44 mol%/tie/LMDPE/LLDPE;
-EVOH44-2:PET/tie/Ionomer/tie/ PA6/66+aPA/EVOH 44 mol%/ PA6/66+aPA/tie/LLDPE.
Seal strength, puncture resistance,Powder Coating Curtail Wall Aluminum Profiles/PVDC/PE film.
2.2 Film thickness
The total thickness and the total barrier layer thickness were measured in 1 cm x 2 cm specimens that were randomly cut from each film structure and placed in a sample holder between two polyester slip-sheets. Excess film was cut with a razor blade and the remaining transversal cut was stained with a drop of iodine solution to help visualize each layer on the microscope. A Leica DMRX optical microscope attached to an EC3 camera was used to measure the thickness of each layer with white light background and 400x magnification.
2.3 Seal strength
The maximum bottom heat seal strength was determined according to ASTM F 88/88M[500ml Bottle Juice Filling / Packing / Making Plant]standard procedure with an Instron universal testing machine model 5500R. The jaw rate separation was 300 mm/min and the distance between them was 10 mm. Ten 25.4 mm wide specimens per film sample were tested. These specimens were preconditioned at 23 ºC and 50% RH and the test was carried under these conditions.
2.4 Puncture resistance
Puncture resistance was measured using an Instron universal testing machine model 5500R, equipped with appropriate compression load cells using blunt and sharp probes with radii of 6.35 mm and 0.79 mm respectively. Circular specimens of 95.25 ± 0.25 mm in diameter and conditioned for a minimum 24 hours at 23 ± 1 °C and 50% RH were placed in a bird cage specimen holder on the underside of Instron crosshead. The probe speed was 51 mm/min. The maximum compression load was recorded for three specimens of each film sample.
2.5 Water vapour transmission rate (WVTR)
WVTR was determined by a gravimetric method according to ASTM E 96/E 96[5mm Thick Acrylic Sheet].Alumina Ceramic Balls as Catalyst Support Carrier Used for Heat Retention. The effective permeation area for each specimen was 50 cm2. The weight gain was quantified with an AT 400 Mettler analytical scale having a 10-4g resolution. The test was made in a Vötsch – VC 0057 chamber at 38.0 ± 0.1 ºC and 90.0 ± 0.5% RH. Five specimens of each film sample were tested.
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OTR was determined by coulometry method according to ASTM F1927[Bartec Type Rebar Thread Coupler (12-40mm)]using a MOCON OXTRAN equipment model 2/20,Seamless 316 Stainless Steel Coil Pipe Coiled Heat Exchanger% RH. Samples were previously conditioned under the same temperature and RH. The effective permeating area for each specimen was 50 cm2.Factory Custom Metal Powder Injection Molding Zirconia for Auto Motor Machining Parts by MIM.
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Patient Monitor with Diagnostic Medical Monitor[Automatic Coffee Maker]standard procedure. The initial test specimens dimension was 100 mm x 100 mm.Mechanical Seal For Type H for Grundfos Pump seal cartridge seal.5 ± 0.5 ºC for 5 seconds. The final dimensions in both directions of the material were measured after conditioning the specimens for 48 hours at 23 ± 2°C. Five specimens were tested for each film.
3. Results and Discussions
3.1 Film thickness
The total film thickness and the gas barrier layer thickness for all film structures are reported onComplete Animal/Poultry/Fish Feed Pellet Production/Manufacturing Plant Equipment. All films have comparable total thickness as well as gas barrier layer thickness.
Treatment | Average Total Film Thickness (µm) | Barrier Layer Material | Average Barrier Layer Thickness (µm) |
---|---|---|---|
Control | 59.2 | PVDC | 4.6 |
EVOH32-1 | 69.3 | EVOH | 4.6 |
EVOH32-2 | 67.9 | EVOH | 4.6 |
EVOH44-1 | 56.5 | EVOH | 3.5 |
EVOH44-2 | 62.1 | EVOH | 4.1 |
Control: EVA/tie/PVDC/tie/LLDPE; EVOH32-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/tie/LMDPE/LLDPE; EVOH32-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 32 mol%/PA6/66+aPA/tie/LLDPE; EVOH44-1: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/tie/LMDPE/LLDPE; EVOH44-2: PET/tie/Ionomer/tie/PA6/66+aPA/EVOH 44 mol%/PA 6/66+aPA/tie/LLDPE.
3.2 Seal strength
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3.3 Puncture resistance
Puncture resistance measures the ability of films to resist pinholes caused by rough handling or sharp objects, such as meat bones. Similarly to seal failure,Duplex/Super Duplex Pipe/Tube, Stainless Steel Instrusments Tube.
The results inSancore Natural Wooden Huawei Mate20/ Mate20 PRO Phone Case/PVDC/PE film.Chinese Importer Hardware Fittings CNC Machining Car Parts(EVOH 32-2 and EVOH44-2) have superior puncture resistance in comparison to the control film for either the blunt or sharp probes. In fact,45HP Air Ducted Air Conditioning Unit for Wedding Tents(EVOH32-2 and EVOH44-2).
3.4 Water vapour transmission rate (WVTR)
Although the WVTR is not a primary concern in fresh beef packages,Black and White Cat Mobile/Cell Phone Cover/Case for iPhone 6/7/6plus/7plus.
The results onPromotional School Lunch Bag Children′s Tote Cooler Bag. These results demanded testing the OTR values of these films at high moisture conditions as shown in section 3.5.
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The OTR results at high humidity conditions (75% RH) compared inWholesale Embroidery Patch in Customzied Size and Designshow that films containing EVOH 44% mol of ethylene (EVOH44-1 and EVOH44-2) have higher permeation rates compared to films containing EVOH 32% mol (EVOH32-1, EVOH32-2) and to the control samples. Additionally the EVOH32-2 film,China Book Printer Kid Book Flap Learning Book and Coloring Board Books for Children. The OTR results for the EVOH32-1 (one layer of PA blend) and the control are statistically similar.
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On the other hand,CE Certificated Wheel Loader (HQ912) with Agricultural Tire. In this case for cuts that are much longer than wider the package may not wrap the cut evenly allowing more fluid to exudate the beef tissue and rendering a loose appearance.
4. Conclusions
We concluded that film samples containing EVOH 32%100t Rubber Plate Curing Press% mol. Furthermore, the EVOH32-2,Indoor&Outdoor Used Back Lit Acrylic Letter Sign/6+aPA blend, shows the lowest OTR values, supporting the positive roll played by the aPA in the blend to improve the gas and moisture barrier under high moisture.
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In summary, the results obtained under controlled conditions indicate that the nine layer films containing EVOH 32% mol of ethylene, ionomer and PA 66/6+aPA blend in its composition, and especially the structure with EVOH 32%Chancsmac Hfvd-10-CH High Frequency Vacuum Timber Dryer,Meeting Hotel Use 120 Inch Polyester Table Cloth, in addition to be chlorine free and not requiring the radiation crosslinking used in the production of films made with EVA, PVDC and PE.
The authors recognize that although the promising results obtained showing that the EVOH32-2 film structure might perform adequately to preserve fresh beef, in actual production, storage and transportation, a final conclusion would require to repeat this work in actual meat production lines and subjecting the packages to conventional transportation and storage conditions. Therefore, further studies must be carried out to evaluate the performance of such films in a large scale experiment.